2015 Fiscal Year Final Research Report
Synthesis, Structure and Function of Stereoregular Poly(beta-amino acid) Derivatives with Carbon-Carbon Backbone
| Project/Area Number |
26810069
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Shinshu University (2015)
Osaka University (2014) |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Keywords | 立体規則性ポリマー / 刺激応答性ポリマー / アニオン重合 / ラジカル重合 / α-機能化アクリル酸エステル / 環化重合 / α-機能化アクリルアミド |
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| Outline of Final Research Achievements |
Polymerizations of esters, amides and their analogues of α-(aminomethyl)acrylic acid, that is, a β-amino acid ester carrying a polymerizable vinyl group on the side group, were investigated, particularly focusing on the control of stereoregularity. The resulting polymers exhibited thermo-/pH-responsiveness in aqueous media, and the relationships between the functions and the chemical structures of the monomers and the polymers were evaluated. Moreover, stereospecific cyclopolymerization of the similar divinyl monomer, i.e. bis(amino acid ester) was also achieved.
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| Free Research Field |
高分子化学
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