Development of Polymer-Supported Ubiquitous Metal Catalysts for Aqueous Flow-Aerobic Oxidation

2015 Fiscal Year Final Research Report

• Project/Area Number: 26810099
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Green/Environmental chemistry
• Research Institution: Institute for Molecular Science
• Principal Investigator: OSAKO Takao 分子科学研究所, 生命・錯体分子科学研究領域, 助教 (90500984)
• Project Period (FY): 2014-04-01 – 2016-03-31
• Keywords: ポリマー担持触媒 / フロー反応 / 酸素酸化反応 / ユビキタス金属

Outline of Final Research Achievements

Development of heterogeneous polymer-supported ubiquitous metal catalysts was investigated to realize the aqueous flow aerobic oxidation reactions using oxygen under highly green-sustainable conditions. As the results, new polystyrene and polystyrene poly(ethylene glycol)-supported alkylamine and pyridylamine copper catalysts were successfully developed and applied to a series of oxidation reactions with oxygen such as the oxidative homocoupling of terminal alkynes and aerobic oxidation and azide-alkyne cycloaddition under batch and flow conditions.

Free Research Field

触媒化学