2015 Fiscal Year Final Research Report
Development of Polymer-Supported Ubiquitous Metal Catalysts for Aqueous Flow-Aerobic Oxidation
Project/Area Number |
26810099
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Green/Environmental chemistry
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Research Institution | Institute for Molecular Science |
Principal Investigator |
OSAKO Takao 分子科学研究所, 生命・錯体分子科学研究領域, 助教 (90500984)
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Project Period (FY) |
2014-04-01 – 2016-03-31
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Keywords | ポリマー担持触媒 / フロー反応 / 酸素酸化反応 / ユビキタス金属 |
Outline of Final Research Achievements |
Development of heterogeneous polymer-supported ubiquitous metal catalysts was investigated to realize the aqueous flow aerobic oxidation reactions using oxygen under highly green-sustainable conditions. As the results, new polystyrene and polystyrene poly(ethylene glycol)-supported alkylamine and pyridylamine copper catalysts were successfully developed and applied to a series of oxidation reactions with oxygen such as the oxidative homocoupling of terminal alkynes and aerobic oxidation and azide-alkyne cycloaddition under batch and flow conditions.
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Free Research Field |
触媒化学
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