2015 Fiscal Year Final Research Report
Development of functional carbon materials based on two-dimensional organic frameworks
Project/Area Number |
26886011
|
Research Category |
Grant-in-Aid for Research Activity Start-up
|
Allocation Type | Single-year Grants |
Research Field |
Nanomaterials chemistry
|
Research Institution | Kyushu University |
Principal Investigator |
SHIRAKI Tomohiro 九州大学, 工学(系)研究科(研究院), 助教 (10508089)
|
Project Period (FY) |
2014-08-29 – 2016-03-31
|
Keywords | 共有結合性有機構造体 / 結晶性 / 炭化 / 窒素ドープカーボン |
Outline of Final Research Achievements |
In this study, development of functional carbon materials was examined through carbonization of covalent organic frameworks (COFs) that are constructed by crystalline molecular networks composed of covalently-linked organic molecules. At first, we succeeded in development of a room temperature synthesis method that provided highly-crystalline COFs compared to the reported ones prepared by solvothermal methods. The nitrogen atom-containing COFs were carbonized to synthesize graphitic carbon materials. Importantly, we found that crystallinity of COFs strongly effects on the resulting graphitic carbon structures and nitrogen-doped conditions that are related to functionalities as fuel cell catalysts and super capacitors.
|
Free Research Field |
ナノカーボン科学、超分子化学、高分子化学
|