2015 Fiscal Year Final Research Report
Reversible control of spin and charge via electrochemical operation based on single-molecule magnet.
| Project/Area Number |
26888017
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Fukuoka University |
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Principal Investigator |
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| Project Period (FY) |
2014-08-29 – 2016-03-31
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| Keywords | 単分子磁石 / 単一分子素子 / 磁性変換 / 多段階酸化還元 / 電気化学 |
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| Outline of Final Research Achievements |
The chloranilate is one of anilate derivatives, which shows the multi-step redox property. Thus, both dinuclear dysprosium(III) and mononuclear cobalt (II) complexes with the chloranilate as the bridged were synthesized. Both complexes can reversibly control spin and/or electronic state by the electrochemical procedure, which is confirmed by the cyclic voltammetry measurement.
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| Free Research Field |
錯体化学
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