2015 Fiscal Year Final Research Report
Development of molecular transformation using bichromophoric metal complexes
| Project/Area Number |
26893221
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Chemical pharmacy
|
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| Research Institution | Gifu Pharmaceutical University |
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Principal Investigator |
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| Project Period (FY) |
2014-08-29 – 2016-03-31
|
| Keywords | 遷移金属触媒 / 光駆動性錯体 / カップリング反応 / 不活性結合の活性化 |
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| Outline of Final Research Achievements |
In this study, we have developed organic reaction especially C-C bond forming reaction using a series of novel visible light sensitizing dinuclear metal complexes. Variety of Ru-Pd dinuclear complexes bearing Ru bipyridyl as a photo sensitizing moiety were synthesized and applied them for the Suzuki-Miyaura coupling reaction. One of the complex show the highest catalytic activity compared to the reported complexes and produced coupling product in high yield under visible light irradiation condition. This result support that this complex works as a converter the photo energy into the chemical energy which we envisioned.
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| Free Research Field |
有機合成化学
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