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1986 Fiscal Year Final Research Report Summary

Carrier-Mediated Transport Membranes for Gas Separation Processes

Research Project

Project/Area Number 59850136
Research Category

Grant-in-Aid for Developmental Scientific Research

Allocation TypeSingle-year Grants
Research Field 工業物理化学
Research InstitutionNagasaki University

Principal Investigator

KAGAWA Shuichi  Nagasaki University, Faculty of Engineering, Prof., 工学部, 教授 (80037746)

Co-Investigator(Kenkyū-buntansha) MATSUMOTO Hideyuki  JGC Corporation, R & D Division, 技術開発部, 主任研究員
FUCHITA Yoshio  Nagasaki University, Faculty of Engineering, Res. Assist., 工学部, 助手 (00100884)
Project Period (FY) 1984 – 1986
KeywordsCarrier-mediated transport / Membrane separation / Gas separation / Liquid membrane / Oxygen / Carbon monoxide / Carbon dioxide
Research Abstract

With a view of developing a high efficient membrane for gas separation processes, a carrier-mediated transport of gases was investigated for some metal ion-liquid oligomer systems. In this system, a liquid oligomer acts as a metal complex ligand and, at the same time, as a liquid membrane matrix substance. Employing a low volatile solvent such as liquid oligomer can result in stabilizing the form of the membrane. The results obtained are as follows.
1. The permselectivity of <CO_2> through liquid polyethylene glycol (PEG) membrane was enhanced by the addition of alkali metal salts to PEG. It was suggested that the enhancement is attributable to the increase in sulubilities of <CO_2> resulting from the acid-base interaction between <CO_2> molecules and naked counter anions.
2. The transport of <O_2> was facilitated by a <Cu^+> -tetraethylenepentamine (tetren) system which absorbs <O_2> reversibly with a stoicheiometry of Cu : <O_2> = 1 : 1 accompanied by a <Cu^+> <<-!->> <Cu^(2+)> cycle.
3. The <Cu^+> -tetren system facilitated also the transportation of CO accompanied by the reversible formation of a <Cu^+> -carbonyl complex.
4. The permselectivities of ethylene and propylene were improved in the <Rh^(3+)> -added PEC membrane. Addition of <KNO_3> to the <Rh^(3+)> -PEG system resulted in further enhancement of permselectivity. Sorption and permeation measurements demonstrated that the olefin transport mediated by <Rh^(3+)> becomes more predominant as a result of the salting-out effect induced by the added salt.

  • Research Products

    (8 results)

All Other

All Publications (8 results)

  • [Publications] M.Kawakami: Journal of Membrane Science. 30. 105-110 (1987)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Kagawa: "Synthetic Polymeric Membranes",ed.by B.Sedlacek,Walter du Gruyter & Co.,Berlin.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M. Kawakami: "Transport of Carbon Monoxide Facilitated by a <Cu^I> -Tetraethylenepentamine System" Chemistry Letters. 1984. 109-112 (1984)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kawakami: "Modification of Gas Permeabilities of Polymer Membranes by Plasma Coating" Journal of Membrane Science. 19. 249-258 (1984)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kawakami: "Selective Permeation of Ethylene and Propylene through <Rh^(3+)> -Polyethylene Glycol Liquid Membranes" Journal of Membrane Science. 30. 105-110 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Kagawa: "Gas Permeability and Permselectivity of Polyvinylacetal Membranes" Synthetic Polymeric Membranes , ed. by B. Sedlacek, Walter de Gruyter & Co., Berlin.

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Matsumoto: "Modern Aspect of Applications of Membranes to Gas Separation Processes" PETROTECH. 7. 19-24 (1984)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Kagawa: "Separation of Gases with Facilitated Transport Membranes" Energy and Resources. 6. 286-291 (1985)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1988-11-09  

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