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1987 Fiscal Year Final Research Report Summary

Systematic Studies of Electron Transport in Amorphous Alloys

Research Project

Project/Area Number 60460191
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field Physical properties of metals
Research InstitutionNagoya University

Principal Investigator

MIZUTANI Uichiro  School of Engineering, Nagoya University, 工学部, 助教授 (00072679)

Co-Investigator(Kenkyū-buntansha) INAGAKI Matsumi  School of Engineering, Nagoya University, 工学部, 助手 (40023098)
NISHIO Takayuki  School of Engineering, Nagoya University, 工学部, 助手 (50164538)
IWAMA Yoshiro  School of Engineering, Nagoya University, 工学部, 教授 (40022975)
Project Period (FY) 1985 – 1987
KeywordsAmorphous alloys / Electron transport / sp-electrons / d-電子 / 伝導電子
Research Abstract

We have proposed to classify amorphous alloys in five groups in terms of magnetic states, to facilitate the discussion of the electron transport mechanism in a disordered system. Among them, non-magnetic alloys are grouped into groups (5) and (4), depending on the location of the Fermi level in the sp-band and d-band, respectively. They are considered to be of fundamental importance in understanding the scattering mechanism.
Major conclusions are summarized here.
(1) The electron transport in group (5) is found to be dominated by sp-electrons at the Fermi level, whereas that in group (4) by d-electrons. We found that the difference in the character of the carriers at the Fermi level yields unique electron transport features in the respective group alloys.
(2) The scattering mechanism in group (5),where only sp-electrons are reaponsible for the transport, changes with increasing resistivity. In the low-resistivity regime of less than 200 <mu><omega> -cm, where the electron mean free path is longer than the average atomic distance, the normal scattering mechanism described by the Boltzmann equation, is found to be valid. The mobility of conduction electrons is greatly lowered as the resistivity exceeds about 500 <mu><omega>-cm. In such high- resistivity regime, the electron-electron correlation and quantum interference effect becomes substantial and yield unique temperature dependence of resistivity over a wide temperature range below 300 K. (3) We demonstrated that the electron transport mechanism in group (4),where d-electron
conduction is significant, is essintially the same as that in high-resistivity group (5) having resistivities above about 500 <mu><omega>-cm. From this we concluded that the electron transport in non-magnetic amorphous alloys including both group (4) and (5) can be understood on the same footing, regardless of the difference in the electronic structure at the Fermi level.

  • Research Products

    (11 results)

All Other

All Publications (11 results)

  • [Publications] U. Mizutani: Matrials Science and Engineering Proceedings of 6th International Conference on Rapidly Ouenched Metals(Montreal, Canada 1987). (1988)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] U. Mizutani: Journal of Non-Crystalline Solids. 94. 345-352 (1987)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] U. Mizutani: Proceedings of International Symposium on Non-Equilibrium Solid Phases of Metals Alloys(Kyoto, Japan 1988). (1988)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] U. Mizutani: Journal of Physics F:Metal Physics. 17. 667-678 (1987)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] U. Mizutani: Journal of Physics F:Metal Physics. 17. 131-141 (1987)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y. Yamada: Journal of Physics F:Metal Physics. 17. 2313-2322

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] U,Mizutani: "Electron Transport Properties of Non-Magnetic Metallic Glasses" Materials Science and Engineering Proceedings of 6th International Conference on Rapidly Quenched Metals (Montreal, Canada 1987). (1988)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] U,Mizutani: "Resistivity, Hall Coefficient and Thermopower in Mg_<70>Cu_<30-x>Zn_x (O<less than or equal>x <less than or equal>30) Metallic Glasses" Journal of Non-Crystalline Solids. 94. 345-352 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] U,Mizutani: "A Unified Picture of Electron Transport Mechanism in Non-Magnetic Metallic Glasses" Proceeding of International Symposium on Non-Equilibrium Solid Phases of Metals and Alloys (Kyoto, Japha 1988). (1988)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] U,Mizutani: "Electronic structure and Electron Transport of Ca-Mg-Al Metallic Glasses" Journal of Physics F: Metal Physics. 17. 667-678 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] U,Mizutani: "Studies of Negative TCR and Electronic Structure of Non-Magnetic Metallic Glasses Based on Y and La" Jounal of Physics F: Metal Physics. 17. 131-141 (1987)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1989-03-30  

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