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1987 Fiscal Year Final Research Report Summary

Mono- and Multicomponent Porous Oxide Glasses Prepared by the Sol-Gel Process

Research Project

Project/Area Number 61470074
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 無機工業化学
Research InstitutionOkayama University

Principal Investigator

TAKAHASHI Katsuaki  President Okayama University, 学長 (90032911)

Co-Investigator(Kenkyū-buntansha) ODA Kiichi  Faculty of Engineering, Okayama University, 工学部, 助手 (50033410)
OSAKA Akiyoshi  Faculty of Engineering, Okayama University, 工学部, 助教授 (20033409)
MIURA Yoshinari  Faculty of Engineering, Okayama University, 工学部, 教授 (80032952)
Project Period (FY) 1986 – 1987
KeywordsSol-Gel process / silica glass / borosilicate / solvent / catalyst / organometallic compounds / crystallization / 結晶化
Research Abstract

Mono- and multicomponent porous glasses have been prepared by the sol-gel process using organometallic compounds, and their pore characteristics have been investigated as a function of the starting material, catalyst, solvent and their mixing ratio.
1. Gel derived silica glass. Gelation time was dependent on the solvent and its concentration in the solution. Granular gels and glass were easily obtained by using HF as the catalyst. HC1-catalysis of tetraethoxysilane (Si(OEt)^4:TEOS) with 1-hexanol takes three times as long for gelation as that with ethanol as the solvent. H^3PO^4 catalysis gave a pore characteristic similar to the HC1 catalysis though more water and organics (mainly ethanol) were trapped in the gels with H^3PO^4 Gel-derived silica glass containing smaller amount of Na^2O precipitated cristobalite at about 650゜C, indicating that the heat treatment should be done at temperatures lower than 600゜C for fixing useful oxides like calcium apatite on the surface of the pores.
2. Sodium borosilicate glasses. The glass of composition 5Na^2O.15B^2O.^3.80SiO^2(wt%) has been.prepared from NaOCH^3, B(OCH^3)^3 and TEOS with HCl as the catalyst and ethanol nol as the solvent. Porosity and specific surface area increased with heat-treatment temperature and reached a maximum value at 450゜C, and decreased to null (pores collapsed). Slight phase separation was observed as well as in the melt-quenched borosilicate glass of the same composition. Cristobalite was precipitated by the treatment at 800゜C from the gel-derived borosilicate glasses. It was concluded that the sodium ions are interacted with Si atoms forming Si-ONa bonds in the gels but not with boron atoms, and that the del-derived glass has no BO^4 units and is different from the melt-quenched glass.

  • Research Products

    (8 results)

All Other

All Publications (8 results)

  • [Publications] Akiyoshi Osaka: Journal of Non-Cuystalline solede.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Akiyoshi Osaka: Journal of Non-Crystalline Solids.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Akiyoshi Osaka: Memoirs of the Faculty of Engineering, Okayama University.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Akiyoshi Osaka: Memoirs of the Faculty Engineering, Okayama University.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Akiyoshi Osaka: "Sodium Borosilicate Glasses Prepared by the Sol-Gel Process" Journal of Non-Crystalline Solids,.

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Akiyoshi Osaka: "Thermal Stability of So-Gel Derived Silica Glass with Impurity Cations" Journal of Non-Crystalline solids,.

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Akiyoshi Osaka: "Preparation of Sodium Borosilicate Gels from Metal Alkoxides" Memoirs of the Faculty of Engineering, Okayama University.

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Akiyoshi Osaka: "Structure Evolution in Sodium Borosilicate Glasses Prepared by the Sol-Gel Process" Memoirs of the Faculty of Engineering, Okayama University.

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1989-03-30  

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