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1987 Fiscal Year Final Research Report Summary

Synthesis of Surface-Active Crown Ethers and Aminimides, and Their Functions

Research Project

Project/Area Number 61470084
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 有機工業化学
Research InstitutionGunma University

Principal Investigator

KUWAMURA Tsunehiko  Faculty of Technology, Gunma University, 工学部, 教授 (60008399)

Co-Investigator(Kenkyū-buntansha) TAKAHASHI Hideo  Faculty of Technology, Gunma University, 工学部, 助手 (80008458)
FURUSAWA Kunio  Institute of Chemistry, Tukuba University, 化学系, 助教授 (90015561)
YANO Yumihiko  Faculty of Technology, Gunma University, 工学部, 教授 (30008510)
KAMEYAMA Eiichi  Faculty of Technology, Gunma University, 工学部, 助教授 (40008438)
Project Period (FY) 1986 – 1987
KeywordsAmphiphilic crown ethers / Monolayers of crown ethers / Colloid particles exhibiting selective ion-binding ability / Amphiphilic aminimides / phase-transfer catalyst / Carriers for liquid membrane transport / Bilayer assemblies / 二分子膜会合体
Research Abstract

A mumber of the title compounds varied in the structural feature have been synthesized and exanined for the following basic properties and functions.
1) Molecular assemblies of higher alkoxymethyl-18-crown-6 in aqueous KCl solution. 2) Binding behavior of metal ions to the monolayers of octadecyloxymethyl-18-corwn-6 in air/water and oil/water interface.
3) Electric field effects on the adsorption and desorption of alkoxymethyl-18-crown-6 compounds varying in alkyl chain length.
4) Preparation of vesicles with phospholipid containing octadecyloxymethyl-18-crown-6, and the variation in zeta potential and coaguration velocity of the combined vesicles with addition of salt.
5) Aggregation behavior (stability of bilayer) in water for aminimides involving two long alkyl chains and for 18-crown-6 compounds having a double-chain hydrocarbon group and an amino acid residue in the side arm.
6) Structural effects of the side chains of amphiphilic crown and azacrown ethers on the aqueous solution properties, cation complexation, phase-transfer catalysis and ability of ion-transport through liquid membrane.
7) Micellar hydrolysis of PNPP by amphiphilic aminimides having a metal binding site and a hydroxyl or thiol group in the presence of Zu++.

  • Research Products

    (9 results)

All Other

All Publications (9 results)

  • [Publications] Hideo Matsumura: Bulletin of The Chemical Society of Japan. 60. 2747-2750 (1987)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Seichi Inokuma: J. of The Japan Oil Chemists′ Society(Yukagaku). 36. 602-604 (1987)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Sumio Ozeki: Submitted to Langmuir.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Tunehiko Kuwamira: Bulletin of The Chemical Society of Japan.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hideo Matsumura: "%electrical Double layer Formed on The Monolayer of Crown Ether Compounds" Bulletin of The Chemical Society of Japan. 60. 2747-2750 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Seiichi Inokuma: "Synthesis and Cation Complexing Ability of Crown Ethers with Glycerol-skeleton" J. of The Japan Oil Chemists' Society (Yukagaku). 36. 602-604 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Sumio Ozeki: "Molecular Assemblies of An Amphipatic Crown Compound in Aqueous KCl Solution" Submitted to Langmuir.

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Tsunehiko Kuwamura: "Metal Ion-Catalysed Hydrolysis os p-Nitrophenyl Picolinate in The Presence of N-Aminimides Having Metal Binding Site and Hydroxy Groups" Bulletin of The Chemical Society of Japan.

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Tsunehiko Kuwamura: "Structural Effects of The Side-Chain on The Cation Binding and Aggregation properties of Amphiphilic Crown Ethers"

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1989-03-30  

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