1987 Fiscal Year Final Research Report Summary
PREPARATION OF NEW TYPES OF ORGANOMETALLIC AND INORGANIC MATERIALS
| Project/Area Number |
61550570
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| Research Category |
Grant-in-Aid for General Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Research Field |
無機工業化学
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| Research Institution | SHIZUOKA UNIVERSITY |
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Principal Investigator |
SAKAI Shizoyosi Shizuoka University (Professor), 工学部, 教授 (80023042)
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| Co-Investigator(Kenkyū-buntansha) |
FUKUZAWA Shin-ichi Shizuoka University (Research Associate), 工学部, 助手 (50173331)
FUJINAMI Tatuo Shizuoka University (Associate Professor), 工学部, 助教授 (80022010)
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| Project Period (FY) |
1986 – 1987
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| Keywords | Surface-active organometallic complex / Surface-active trialkyltelluronium halide / Cyclopentadienyl(long-chain alkyl substituted benzene)iron(1+)complex / トリカルボニル(長鎖アルキル置換ベンゼン)マンガン(1+)錯体 / 有機金属のLB膜 |
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| Research Abstract |
A new type of redox-sensitive and surface-active organotransition-metal cationic complexes ,long chain alkyl mono-substituted (benzene)cyclopentadienyliron(1+)(A), (benzene)tricarbonylmanganese(1+)(B), and cobaltocenium(1+) complexes(C) were prepeared, and their critical micelle concentrations were 10^<-2>-10^<-5> mol/dm^3, these values beeing strongly affected by their structures and in the copresence of a reductant. Long-chain substituted (benzene)tricarbonylchrom(0)(D) , trialkyltelluronium halides(E),and organostannyl-substituted polyether(F) were also synthesized. Thin films of these organometallics were prepared on glass plates by Langmuir-Blodgetts' method or by a dipping method, and were thermally decomposed under air to form thin metal oxide films. Finally, trimethylsilyl-substituted ferrocene, tricarbonylchrom , and related complexes were decomposed in Au-tube at 600゜C under pressure of 1250 kg/cm ^2 for 3 h, to afford fine powders containing <alpha>-Fe and Fe_3Si.
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Research Products
(8 results)
