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1987 Fiscal Year Final Research Report Summary

Construction of Surface Plasmon Spectrometer for Studies of Adsorption and Organic Films.

Research Project

Project/Area Number 61850156
Research Category

Grant-in-Aid for Developmental Scientific Research

Allocation TypeSingle-year Grants
Research Field 高分子物性
Research InstitutionMie University

Principal Investigator

AKIRA TAKAHASHI  Mie University, Faculty of Engineering, Prof., 工学部, 教授 (70023009)

Co-Investigator(Kenkyū-buntansha) TADAYA KATO  Mie University, Faculty of Engineering, Prof., 工学部, 教授 (80023133)
Project Period (FY) 1986 – 1987
KeywordsSurface Plasmon / Surface Polarition / Layer Thickness / Adsorption / Polymer Adsorption
Research Abstract

A surface plasmon spectrometer, which is suitable for studies of polymer adsorption as well as layer thickness measurement of deposited layers of organic matters, was designed and constructed. Both the He-Ne laser light source arm and the detector photodiode arm are independently rotatable by stepping motors with the precision of 0.01゜ per pulse. The sensitivity of thickness measurement was <plus-minus> 0.1 nm. To determine the thcikness and the refractive index of layers on a metalic films (e. g. Ag), expressions for reflectivity and surface polariton dispersion equation are solved by curve fitting method, and a computor program was offered. Using the method, adsorption of polyethylene oxide from aqueous solutions onto a silver surface was examined and both adsorbance and adsorbed layer thickness were obtained preciselof

  • Research Products

    (16 results)

All Other

All Publications (16 results)

  • [Publications] 久保 宏記: 第37回高分子年次大会 Polymer Preprint, Japan.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 高橋 彰: 表面. 24. 574-581 (1986)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 高橋 彰: 日本接着協会誌. 22. 646-651 (1986)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 高橋 彰: 色材. 59. 168-175 (1986)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 川口 正美: 表面. 25. 601-611 (1987)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 高橋 彰: 日本ゴム協会誌. 60. 231-239 (1987)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 高橋 彰: "新素材プロセス綜合技術,19章「無機物質表面への高分子の吸着」" R&Dプランニング, 13 (1986)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Mitsru Nagasawa: "Molecular Conformation and Dynamics of Macromolecules in Condensed Systems" Elsevier Science Publisher, 20 (1988)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H. Kubo: "Surface Plasmon Spectroscopy and Its Application for Study of Plymer Adsorption" Polymer Preprint, Japan. (1988)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Takahashi: "Adsorption of Polyelectrolytes onto Electrods Surfaces" Hyomen (Surfaces). 24. 574-581 (1986)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Takahashi: "Adsorption of Polymers on Powders and its Application" The Japan Society of Colour Material. 59. 168-175 (1986)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Takahashi: "Conformation of Macromolecules Adsorbed on Surfaces" Nippon Gomu Kyokai. 60. 231-239 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kawaguchi: "Adsorption of Polyelectrolyte and Steric Stabilization" Hyomen (Surfaces). 25. 601-611 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Akira Takahashi: "Adsorption of Macromolecules on Soild Surfaces" J. Adhesion Soc. Japan. 22. 646-651 (1986)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Takahashi (M. Nagasawa Ed.): Elsevier Science Publisher. Molecular Conformation and Bynamics of Macromolecules in Condensed Systems, 20 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Akira Takahashi: R & D Planning. "Adsorption of Polymers on Inorganic Surfaces" in "Technology in processing of New Materials", Chaptor 19., 13 (1986)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1989-03-30  

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