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1988 Fiscal Year Final Research Report Summary

DESIGN AND APPLICATION OF CAGE MOLECULES

Research Project

Project/Area Number 62303004
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 有機化学一般
Research InstitutionTHE INSTITUTE OF SCIENTIFIC AND INDUSTRIAL RESEARCH OSAKA UNIVERSITY

Principal Investigator

PROF. MISUMI SOICHI  ISIR-SANKEN, OSAKA UNIVERSITY, 産研, 教授 (40029830)

Co-Investigator(Kenkyū-buntansha) 伊東 椒  徳島文理大学, 薬, 教授 (00004242)
米光 宰  北海道大学, 薬, 教授 (60001038)
大木 道則  岡山大学, 理, 教授 (40011407)
PROF. ITO SHO  FACULTY OF PHARMACEUTICAL SCIENCES TOKUSHIMA BUNRI UNIVERSITY (40029830)
PROF. OKI MICHINORI  OKAYAMA UNIVERSITY OF SCIENCE (40029830)
PROF. YONEMITSU OSAMU  FACULTY OF PHARMACEUTICAL SCIENCES HOKKAIDO UNIVERSITY (40029830)
Project Period (FY) 1987 – 1988
KeywordsCAGE MOLECULES / CYCLOPHANES / PHOTOCHROMISM / TRIPTYCENES / FERROCENOPHANES / TROPONOPHANES / HOST-GUEST COMPLEXATION / CARBON CLUSTER
Research Abstract

This research group has studied with three divided sub-projects as follows:
I. Alicyclic and Aromatic cage Molecules.
The project of this sub-group has been focused on the chemistry of highly strained, highly symmetrical cage molecules and their application to develop new fuctional systems; e.g., 1) synthesis of paracyclophanes with marginal stability, 2) solar energy storage material, 3) photochromism of multilayered cyclophanes, 4) stereochemistry of dynamic gearing with polymeric triptycenes, 5) structural study of multi-bridged ferrocenophanes, 6) chemistry of troponophanes, 7) cationic cyclocodimerization to synthesize [3.n]cyclophanes, etc.
II. Structural Studies and Host-Guest chemistry of Hetero-Cage Molecules.
This project was carried out with two sub-projects, i) design-synthesis of new highly strained hetero-cage molecules and ii) guest selective inclusion with O,N-cage molecules; e.g., 1) chemistry of ethylene polysilane cage molecules, 2) transannular interaction of azastibocines, 3) complexation of fluorescent spherands, 4) pottasium selective complexation with photochromic crowns and hexametaxylylenetetramine, etc.
III. Theoretical Design for New Novel Cage Molecules.
1) Computation study of carbon cluster, C_<40>-C_<90>, 2) molecular mechanic study ofcompact cage molecules with high symmetry and strain energy, etc.

  • Research Products

    (11 results)

All Other

All Publications (11 results)

  • [Publications] T.ASOH;K.TANI;H.HIGUCHI;T.KANEDA;T.TANAKA;M.SAWADA;S.MISUMI: CHEMISTRY LETTERS. 417-420 (1988)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.OKI;N.TAKIGUCHI;S.TOYOTA;G.YAMAMOTO;S.MURATA: BULL.CHEM.SOC.JAPAN. 61. 4295-4303 (1988)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.HIRAO;A.YAMASHITA;O.YONEMITSU: TETRAHEDRON LETTERS. 29. 4109-4112 (1988)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.TOBE;K.UEDA;T.KANEDA;K.KAKIUCHI;Y.ODAIRA;Y.KAI;N.KASAI: J.AM.CHEM.SOC.109. 1136-1144 (1987)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.MIKI;K.MATSUO;M.YOSHIDA;Z.YOSHIDA: TETRAHEDRON LETTERS. 29. 2211-2214 (1988)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.IWAMURA;K.MISLOW: ACC.CHEM.RES.21. 175-182 (1988)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.ASOH,;K.TANI,;H.HIGUCHI,;T.KANEDA.;T.TANAKA,;M.SAWADA,; S.MISUMI.: "SYNTHESIS AND MOLECULAR STRUCTURE OF TETRATHIA[3^4] (1,2,4,5) CYCLOPHANE" CHEMISTRY LETTERS. 417-420 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.OKI,;N.TAKIGUGHI,;S.TOYOTA,;G.YAMAMOTO,; S.MURATA.: "ROTAMER POPURATIONS AND MOLECULAR STRUCTURE OF 9-ISOBUTYL-1,4-DIMETHOXYTRIPTYCENE: FURTHER EVIDENCE FOR THE PRESENCE OF CH_3...O HYDROGEN BOND" BULL. CHEM. SOC. JAPAN. 61. 4295-4303 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.HIRAO,;A.YAMASHITA,; O.YONEMITSU.: "CYCLOREVERSION OF ACYLQUADRICYCLANE TO ACYLNORBORNADIENE PROMOTED BY METAL OXIDES" TETRAHEDRON LETTERS. 29. 4109-4112 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.TOBE,;K.UEDA,;T.KANEDA,;K.KAKIUCHI,;Y.ODAIRA,;Y.KAI,; N.KASAI: "SYNTHESIS AND MOLECULAR STRUCTURE OF (Z)-[6]PARACYCLOPH-3-ENES" J. AM. CHEM. SOC.109. 1136-1144 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.MIKI,;K.MATSUO,;M.YOSHIDA,; Z.YOSHIDA.: "NOVEL ANTHRAQUINONE DERIVATIVES UNDERGOING PHOTOCHEMICAL VALENCE ISOMERIZATION" TETRAHEDRON LETTERS. 29. 2211-2214 (1988)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1990-03-20  

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