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1989 Fiscal Year Final Research Report Summary

Chronological application of Re-Os system to sulfide ores

Research Project

Project/Area Number 62430009
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field 分析・地球化学
Research InstitutionUniversity of Tokyo

Principal Investigator

MASUDA Akimasa  Univ. Tokyo, Fac. Sci., Professor, 理学部, 教授 (40030788)

Co-Investigator(Kenkyū-buntansha) NAKAI Shun-ichi  Univ. Tokyo, Fac. Sci., Res. Associate, 理学部, 助手 (50188869)
SHIMIZU Hiroshi  Univ. Tokyo, Fac. Sci., Associate Prof., 理学部, 助教授 (60090544)
Project Period (FY) 1987 – 1989
KeywordsRe-Os geochronometer / sulfide ore minerals / ICP mass spectrometer / isotopic equilibrium / mass discrimination / gas-mist merging introduction / molybdenite
Research Abstract

For the studies of sulfide ore deposits, chronological studies of them are of much significance. However, such studies of formation ages of sulfides have been retarded, since there remain some problems concerning Re-Os dating which has been expected to be a promising geochronometer. In the present work, we tried to examine the problems underlying the practical and wide application of Re-Os clock to the sulfide ore minerals, from basic points of view involving the technical improvement, where the mass spectrometer with inductively coupled plasma (ICP) ion source was employed. Our results are summarized below:
(1) A new method has been developed to make a correction about the effect of mass discrimination which takes place in ICP mass spectrometer. By combination of this correction method with isotope dilution employing highly enriched Os-192, we succeeded in simultaneous determination of (Os-187)/(Os-186) ratio and Os abundance. In this connection, an apparatus was devise to treat Os as … More tetroxide which has very high volatility.
(2) Also we succeeded in enhancing the sensitivities of Os and Re. In this method, the vapor of OsO_4"or Re_2O_7 generated from a specially designed small furnace merges into the "pure" mist produced by a conventional nebulizer. Thus, Os or Re is introduced into the plasma torch without substantial loss or discard. In use of the customary introduction employing the simple nebulization of aqueous solution of element(s), 50-100 ng Os was required, whereas -10 ng Os is sufficient amount according to our system.
(3) We recognized that the Re content in molybdenite is different from portion to portion. This problem is solved by careful pulverization. Besides, it was found out that it is difficult for us to attain the isotopic equilibrium between the radiogenic Os and the Os spike added. This isotopic problem can be solved by distillation for 5 hours, in which the distillate is collected separately for each hour and isotopic measurement of Os distilled is made for each fraction. As a result, we could obtain the correct age. Less

  • Research Products

    (8 results)

All Other

All Publications (8 results)

  • [Publications] Takafumi Hirata: "Simultaneous determination of isotopic ratio and abundances and abundances of osmium by ICP-MS: fundamental studies for the application to rhenium-osmium systematics" ICP Inf.Newslett.13. 731-735 (1988)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Takafumi Hirata: "Determination of osmium and osmium isotope ratios by microelectrothermal vaporization by inductively coupled plasma mass spectrometry" Analytical Chemistry. 61. 2263-2266 (1989)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Takafumi Hirata: "Direct introduction of powder samples into inductively coupled plasma mass spectrometry with spark dispersion/merging introduction technique" Analyst(submitted).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Takafumi Hirata: "Determination of rhenium with enhanced sensitivity by inductively coupled plasma mass spectrometry" Journal of Analytical Atomic Spectrometry(submitted).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Takafumi Hirata: "Simultaneous determination of isotopic ratio and abundances and abundances of osmium by ICP-MS: fundamental studies for the application to rhenium-osmium systematics" ICP Inf. Newslett.13. 731-735 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Takafumi Hirata: "Determination of osmium and osmium isotope ratios by microelectrothermal vaporization by inductively coupled plasma mass spectrometry" Anal. Chemistry, 61 2263-2266, 1989.

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Takafumi Hirata: "Direct introduction of powder samples into inductively coupled plasma mass spectrometry with spark dispersion/merging introduction technique" Analyst.

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Takafumi Hirata: "Determination of rhenium with enhanced sensitivity by inductively coupled plasma mass spectrometry" J. Anal. Atomic Spectrometry.

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1993-03-26  

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