Concise Synthesis of Deformylflustrabromine, a Marine Indole Alkaloid, through a 2-Propynyl Dicobalt Hexacarbonyl Complex
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- Isaji Hisaaki
- Graduate School of Bioagricultural Sciences, Nagoya University
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- Nakazaki Atsuo
- Graduate School of Bioagricultural Sciences, Nagoya University
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- Isobe Minoru
- Graduate School of Bioagricultural Sciences, Nagoya University
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- Nishikawa Toshio
- Graduate School of Bioagricultural Sciences, Nagoya University
Abstract
Deformylflustrabromine, a marine indole alkaloid, was synthesized from 6-bromotryptamine, a plausible biosynthetic precursor, without protection of the amino group by a two-step reverse prenylation involving the Nicholas reaction and reductive decomplexation of the resulting acetylene dicobalt hexacarbonyl complex.
Journal
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- Chemistry Letters
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Chemistry Letters 40 (10), 1079-1081, 2011
The Chemical Society of Japan
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Keywords
Details
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- CRID
- 1390282679566734592
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- NII Article ID
- 130004426050
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- ISSN
- 13480715
- 03667022
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed