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Stimuli-responsive Chemical Species for the Creation of Functional Molecules

Organizer

Project AreaStimuli-responsive Chemical Species for the Creation of Functional Molecules
Project/Area Number 24109001
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionHiroshima University

Principal Investigator

Yamamoto Yohsuke  広島大学, 理学研究科, 教授 (50158317)

Co-Investigator(Renkei-kenkyūsha) MATSUO TSUKASA  近畿大学, 理工学部, 准教授 (90312800)
IWAMOTO TAKEAKI  東北大学, 大学院理学研究科, 教授 (70302081)
YAMAGO SHIGERU  京都大学, 化学研究所, 教授 (30222368)
SEKIGUCHI AKIRA  筑波大学, 数理物質系, 特命教授 (90143164)
YAMAGUCHI SHIGEHIRO  名古屋大学, 大学院理学研究科, 教授 (60260618)
ABE MANABU  広島大学, 大学院理学研究科, 教授 (30273577)
IKEDA HIROSHI  大阪府立大学, 大学院工学研究科, 教授 (30211717)
OZAWA FUMIYUKI  京都大学, 化学研究所, 教授 (40134837)
HASHIMOTO HISAKO  東北大学, 大学院理学研究科, 准教授 (60291085)
YAMASHITA MAKOTO  名古屋大学, 大学院工学研究科, 教授 (10376486)
TOKITOH NORIHIRO  京都大学, 化学研究所, 教授 (90197864)
YOSHIZAWA KAZUNARI  九州大学, 先導物質化学研究所, 教授 (30273486)
SUGIMOTO HIDEKI  大阪大学, 大学院工学研究科, 准教授 (00315970)
OGO SEIJI  九州大学, 大学院工学研究院, 教授 (60290904)
INOUE TSUYOSHI  大阪大学, 大学院工学研究科, 教授 (20263204)
NAKAI HIDETAKA  近畿大学, 理工学部, 准教授 (70377399)
Project Period (FY) 2012-06-28 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥36,530,000 (Direct Cost: ¥28,100,000、Indirect Cost: ¥8,430,000)
Fiscal Year 2016: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2015: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2014: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2013: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2012: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Keywords典型元素 / 遷移金属 / 不安定中間体 / 触媒 / 機能性化学種 / 不安定化学種 / 機能 / 構造
Outline of Final Research Achievements

In this area, we have promoted truly original and fusion-type fundamental chemical researches. A clear research concept called "Stimuli-responsive Chemical Species" and a variety of research perspectives brought by the collaboration of leading researchers are twin engines of our research. As a result, new material science was created, which is not reached without collaboration. And it has a great ripple effect not only in the specific field but also in related fields.
For example, they are (1) creation of organic radical batteries based on the stabilization of the radical atom of the hypervalent group 16 element, (2) discovery of intermediate diradical state and development to nonlinear optical material based on its favorable electronic state, (3) Development of a novel nickel-iron catalyst that reduces oxygen molecules to water, (4) creation of a time-resolved X-ray structural analysis device to clarify the mechanism of enzymatic reactions, etc.

Report

(6 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report

Research Products

(24 results)

All 2017 2016 2013 2012 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (7 results) (of which Invited: 2 results) Remarks (5 results) Funded Workshop (3 results)

  • [Journal Article] Substituent Effects on the Structure of Hexacoordinate Carbon Bearing Two Thioxanthene Ligands2013

    • Author(s)
      T. Yamaguchi
    • Journal Title

      Pure and Applied Chemistry

      Volume: 85(4) Pages: 671-682

    • DOI

      10.1351/pac-con-12-11-05

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Novel 7-6-7 Ring Based PCP Pincer Rhodium Complexes2013

    • Author(s)
      Y. Shi , S. Kojima, Y. Yamamoto
    • Journal Title

      Phosphorus, Sulfur and Silicon and the Related Elements

      Volume: 188(1-3) Pages: 116-120

    • DOI

      10.1080/10426507.2012.743137

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Impact of Diradical Character on Two-Photon Absorption : Bis(acridine) Dimers Synthesized from an Allenic Precursor2013

    • Author(s)
      Kenji Kamada, Shin-ichi Fuku-en. Shu Minamide, Koji Ohta, Ryohei Kishi, Masayoshi Nakano, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hiroyuki Higashikawa, Katsuya Inoue, Satoshi Kojima, Yohsuke Yamamoto
    • Journal Title

      J. Am. Chem. Soc.,

      Volume: 135(1) Pages: 232-241

    • DOI

      10.1021/ja308396a

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Counter-Cation Effect on Reactivity of o-(Fluorodimethylsilyl)phenyl Anion2013

    • Author(s)
      Atsushi Kawachi
    • Journal Title

      Heteroatom Chem.

      Volume: 24 Pages: 53-57

    • DOI

      10.1002/hc.21062

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Anti-apicophilic Arsoranes and Related compounds.2012

    • Author(s)
      X.-D. Jiang, S. Matsukawa, S. Kojima, and Y. Yamamoto.
    • Journal Title

      Inorg. Chem.

      Volume: 51 Pages: 10996-11006

    • DOI

      10.1021/ic3014893

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of new cyclic aromatic carbene ligands bearing remote amino groups and their palladium(II) complexes2012

    • Author(s)
      Shun Sugawara, Satoshi Kojima, Yohsuke Yamamoto
    • Journal Title

      Chem. Commun.

      Volume: 48 Pages: 9735-9737

    • DOI

      10.1039/c2cc33510g

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Optical Properties of Dithienostiboles2012

    • Author(s)
      J. Ohshita
    • Journal Title

      Chem. Lett.

      Volume: 41 Issue: 9 Pages: 1002-1003

    • DOI

      10.1246/cl.2012.1002

    • NAID

      130004426695

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intramolecular H-Ar Ligand Exchange between Silicon and Boron : Functionality Transfer of Si-H to B-H2012

    • Author(s)
      A. Kawachi, H. Morisaki, N. Nishioka, Y. Yamamoto
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 7(3) Pages: 3566-3581

    • DOI

      10.1002/asia.201100678

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Characterization and Spectroscopic Analysis of Antiaromatic Benzofused Metalloporphyrin Species2012

    • Author(s)
      S. Sugawara, Y. Hirata, S. Kojima, Y, Yamamoto, E. Miyazaki, K. Takimiya, S. Matsukawa, D. Hashizume, J. Mack, N. Kobayashi, Z. Fu, K. M. Kadish, Y. M. Sung, K. S. Kim, D. Kim
    • Journal Title

      Chemistry - A European Journal

      Volume: 18(12) Pages: 3566-3581

    • DOI

      10.1002/chem.201101846

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Development of a New Tridentate Ligand and Application to the Synthesis of an Isolable Hypervalent Sulfur Radicals (9-S-3)2013

    • Author(s)
      Yohsuke Yamamoto
    • Organizer
      The 1st International Symposium on Stimuli-responsive Chemical Species for the Creation of Functional Molecules
    • Place of Presentation
      広島
    • Year and Date
      2013-03-26
    • Related Report
      2012 Annual Research Report
  • [Presentation] 典型元素化学・有機金属化学の研究動向と将来展望2013

    • Author(s)
      山本 陽介
    • Organizer
      分子研研究会 「無機化学の現状と未来:若い世代が切り開く新しいサイエンス」
    • Place of Presentation
      岡崎
    • Year and Date
      2013-01-17
    • Related Report
      2012 Annual Research Report
  • [Presentation] 感応性化学種が拓く新物質科学2013

    • Author(s)
      山本陽介
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      タワーホール船堀東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高配位および低配位典型元素の実験研究と計算化学2012

    • Author(s)
      山本陽介
    • Organizer
      計算分子科学研究拠点 第2回実験科学との交流シンポジウム
    • Place of Presentation
      京都
    • Year and Date
      2012-11-16
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Synthesis and properties of 16 π-Electron Porphyrins2012

    • Author(s)
      Yohsuke Yamamoto
    • Organizer
      17th Malaysian Chemical Congress
    • Place of Presentation
      クアラルンプール(マレーシア)
    • Year and Date
      2012-10-15
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Preparation of alcohols bearing two identical perfluoroalkyl groups by a Cannizzaro-type reaction and application of the alcohols as a bulky Martin ligand variant for new anti-apicophilic phosphoranes2012

    • Author(s)
      Yohsuke Yamamoto
    • Organizer
      20th International Symposium on Fluorine Chemistry
    • Place of Presentation
      京都
    • Year and Date
      2012-07-22
    • Related Report
      2012 Annual Research Report
  • [Presentation] Highly Active Catalysts for the Transfer Dehydrogenation of Alkanes; Synthesis and Application of Novel 7-6-7 Rings Based Pincer Iridium Complexes2012

    • Author(s)
      Yohsuke Yamamoto
    • Organizer
      The 19th International Congress on Phosphorus Chemistry (ICPC-19)
    • Place of Presentation
      ロッテルダム(オランダ)
    • Year and Date
      2012-07-08
    • Related Report
      2012 Annual Research Report
  • [Remarks] 感応性化学種が拓く新物質科学ホームページ

    • URL

      http://www.strecs.jp/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 「感応性化学種」HP

    • URL

      http://www.strecs.jp/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 文部科学省科学研究費補助金「新学術領域研究」感応性化学種が拓く新物質科学HP

    • URL

      http://www.strecs.jp/

    • Related Report
      2014 Annual Research Report
  • [Remarks] 文部科学省科学研究費補助金「新学術領域研究」 感応性化学種が拓く新物質科学HP

    • URL

      http://www.strecs.jp/

    • Related Report
      2013 Annual Research Report
  • [Remarks] http://www.strecs.jp/

    • Related Report
      2012 Annual Research Report
  • [Funded Workshop] 感応性化学種が拓く新物質科学 第2回国際シンポジウム2017

    • Place of Presentation
      広島大学東広島キャンパス(広島県東広島市)
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Funded Workshop] 感応性化学種が拓く新物質科学 第4回若手国際シンポジウム2016

    • Place of Presentation
      大阪大学吹田キャンパス(大阪府吹田市)
    • Year and Date
      2016-12-12
    • Related Report
      2016 Annual Research Report
  • [Funded Workshop] 感応性化学種が拓く新物質科学 第3回若手国際シンポジウム2016

    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2016-03-09
    • Related Report
      2015 Annual Research Report

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Published: 2012-11-27   Modified: 2019-07-29  

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