| Project Area | Stimuli-responsive Chemical Species for the Creation of Functional Molecules |
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| Project/Area Number | 24109001 |
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| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Hiroshima University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
MATSUO TSUKASA 近畿大学, 理工学部, 准教授 (90312800)
IWAMOTO TAKEAKI 東北大学, 大学院理学研究科, 教授 (70302081)
YAMAGO SHIGERU 京都大学, 化学研究所, 教授 (30222368)
SEKIGUCHI AKIRA 筑波大学, 数理物質系, 特命教授 (90143164)
YAMAGUCHI SHIGEHIRO 名古屋大学, 大学院理学研究科, 教授 (60260618)
ABE MANABU 広島大学, 大学院理学研究科, 教授 (30273577)
IKEDA HIROSHI 大阪府立大学, 大学院工学研究科, 教授 (30211717)
OZAWA FUMIYUKI 京都大学, 化学研究所, 教授 (40134837)
HASHIMOTO HISAKO 東北大学, 大学院理学研究科, 准教授 (60291085)
YAMASHITA MAKOTO 名古屋大学, 大学院工学研究科, 教授 (10376486)
TOKITOH NORIHIRO 京都大学, 化学研究所, 教授 (90197864)
YOSHIZAWA KAZUNARI 九州大学, 先導物質科学研究所, 教授 (30273486)
SUGIMOTO HIDEKI 大阪大学, 大学院工学研究科, 准教授 (00315970)
OGO SEIJI 九州大学, 大学院工学研究院, 教授 (60290904)
INOUE TSUYOSHI 大阪大学, 大学院工学研究科, 教授 (20263204)
NAKAI HIDETAKA 近畿大学, 理工学部, 准教授 (70377399)
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| Project Period (FY) |
2012-06-28 – 2017-03-31
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| Project Status |
Completed(Fiscal Year 2016)
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| Budget Amount *help |
¥36,530,000 (Direct Cost : ¥28,100,000、Indirect Cost : ¥8,430,000)
Fiscal Year 2016 : ¥7,410,000 (Direct Cost : ¥5,700,000、Indirect Cost : ¥1,710,000)
Fiscal Year 2015 : ¥7,410,000 (Direct Cost : ¥5,700,000、Indirect Cost : ¥1,710,000)
Fiscal Year 2014 : ¥7,540,000 (Direct Cost : ¥5,800,000、Indirect Cost : ¥1,740,000)
Fiscal Year 2013 : ¥7,410,000 (Direct Cost : ¥5,700,000、Indirect Cost : ¥1,710,000)
Fiscal Year 2012 : ¥6,760,000 (Direct Cost : ¥5,200,000、Indirect Cost : ¥1,560,000)
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| Keywords | 典型元素 / 遷移金属 / 不安定中間体 / 触媒 / 機能性化学種 / 不安定化学種 / 機能 / 構造 |
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| Outline of Final Research Achievements |
In this area, we have promoted truly original and fusion-type fundamental chemical researches. A clear research concept called "Stimuli-responsive Chemical Species" and a variety of research perspectives brought by the collaboration of leading researchers are twin engines of our research. As a result, new material science was created, which is not reached without collaboration. And it has a great ripple effect not only in the specific field but also in related fields.
For example, they are (1) creation of organic radical batteries based on the stabilization of the radical atom of the hypervalent group 16 element, (2) discovery of intermediate diradical state and development to nonlinear optical material based on its favorable electronic state, (3) Development of a novel nickel-iron catalyst that reduces oxygen molecules to water, (4) creation of a time-resolved X-ray structural analysis device to clarify the mechanism of enzymatic reactions, etc.
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