Development of High Performance Molecular Catalysts for Extremely Difficult Selective Oxidation Reactions

• Project Area: Precise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions
• Project/Area Number: 15H05797
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: The University of Tokyo
• Principal Investigator: Mizuno Noritaka 東京大学, 大学院工学系研究科(工学部), 教授 (50181904)
• Co-Investigator(Kenkyū-buntansha): 山口 和也 東京大学, 大学院工学系研究科(工学部), 教授 (50334313)
• Project Period (FY): 2015-06-29 – 2020-03-31
• Project Status: Completed (Fiscal Year 2019)
• Budget Amount: ¥43,160,000 (Direct Cost: ¥33,200,000、Indirect Cost: ¥9,960,000); Fiscal Year 2019: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000); Fiscal Year 2018: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000); Fiscal Year 2017: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000); Fiscal Year 2016: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000); Fiscal Year 2015: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
• Keywords: ポリオキソメタレート / 分子触媒 / 固体触媒 / 酸化反応 / 新反応開発 / 高難度選択酸化反応 / ナノ構造体

Outline of Final Research Achievements

In this study, we have precisely designed high-performance heterogeneous catalysts based on polyoxometalates and metal nanoparticles, and have successfully developed extremely difficult selective oxidation reactions such as (1) oxidative amidation of alcohols and oxygenation of amines using O2 as the oxidant, and (2) phenol synthesis and arylamine synthesis using acceptorless dehydrogenative aromatization.

Academic Significance and Societal Importance of the Research Achievements

本研究では、ナノ構造触媒ならびに固体表面の精密設計・機能集積化によって初めて実現した固体触媒ならではの反応をいくつか開発した。これまでの固体触媒研究は、単に均一系触媒を固定化したものを既存の反応に適用するだけの研究が数多くを占めていた。一方，本研究では、均一系触媒を用いてもこれまでに実現されていなかった新反応開発のための固体触媒ならではの活性点構造の創出や機能の集積化を独自の視点・手法で行ったという点で新しい固体触媒設計概念や反応開発手法の学理を提供するものになると考えられる。さらに，環境調和型の含窒素化合物の新合成・新変換手法を開発したため、工業的観点からのインパクトも大である。

Research Products

• [Journal Article] Synthesis of unsymmetrically substituted triarylamines via acceptorless dehydrogenative aromatization using a Pd/C and p-toluenesulfonic acid hybrid relay catalyst (2020)
  • Author(s): S. Takayama, T. Yatabe, Y. Koizumi, X. Jin, K. Nozaki, N. Mizuno, K. Yamaguchi
  • Journal Title: Chem. Sci. Volume: 11 Issue: 16 Pages: 4074-4084
  • DOI: 10.1039/c9sc06442g
  • Peer Reviewed
• [Journal Article] Methyl Selective α-Oxygenation of Tertiary N-Methylamines to Formamides by Employing Copper/Moderately Hindered Nitroxyl Radical (DMN-AZADO or 1-Me-AZADO) (2019)
  • Author(s): S. Nakai, T. Yatabe, K. Suzuki, Y. Sasano, Y. Iwabuchi, J. Hasegawa, N. Mizuno, K. Yamaguchi
  • Journal Title: Angew. Chem. Int. Ed. Volume: 58 Issue: 46 Pages: 16651-16659
  • DOI: 10.1002/anie.201909005
  • Peer Reviewed
• [Journal Article] Selective Synthesis of Primary Anilines from NH 3 and Cyclohexanones by Utilizing Preferential Adsorption of Styrene on the Pd Nanoparticle Surface (2019)
  • Author(s): Koizumi Yu、Jin Xiongjie、Yatabe Takafumi、Miyazaki Ray、Hasegawa Jun‐ya、Nozaki Kyoko、Mizuno Noritaka、Yamaguchi Kazuya
  • Journal Title: Angewandte Chemie International Edition Volume: 58 Issue: 32 Pages: 10893-10897
  • DOI: 10.1002/anie.201903841
  • Peer Reviewed
• [Journal Article] アンモニアを直接窒素源とした含窒素有機化合物の合成 (2019)
  • Author(s): 山口 和也, 谷田部 孝文, 金 雄傑, 水野 哲孝
  • Journal Title: 触媒 Volume: 61 Pages: 248-254
  • Peer Reviewed
• [Journal Article] 担持PdあるいはAu-Pd合金ナノ粒子触媒による脱水素芳香環形成反応 (2019)
  • Author(s): 金 雄傑, 野崎 京子, 水野 哲孝, 山口 和也
  • Journal Title: 有機合成協会誌 Volume: 77 Pages: 566-575
  • NAID: 130007662289
  • Peer Reviewed
• [Journal Article] Heterogeneously Palladium-catalyzed Acceptorless Dehydrogenative Aromatization of Cyclic Amines (2019)
  • Author(s): Oyama Takashi、Yatabe Takafumi、Jin Xiongjie、Mizuno Noritaka、Yamaguchi Kazuya
  • Journal Title: Chemistry Letters Volume: 印刷中 Issue: 6 Pages: 517-520
  • DOI: 10.1246/cl.190080
  • NAID: 130007659794
  • Peer Reviewed
• [Journal Article] Unusual Olefinic C-H Functionalization of Simple Chalcones Toward Aurones Enabled by the Rational Design of a Function-Integrated Heterogeneous Catalyst (2018)
  • Author(s): Takafumi Yatabe, Xiongjie Jin, Noritaka Mizuno, Kazuya Yamaguchi
  • Journal Title: ACS Catalysis Volume: 印刷中 Issue: 6 Pages: 4969-4978
  • DOI: 10.1021/acscatal.8b00727
  • Peer Reviewed
• [Journal Article] CuCl/TMEDA/nor-AZADO-catalyzed aerobic oxidative acylation of amides with alcohols to produce imides (2018)
  • Author(s): Kataoka Kengo、Wachi Keiju、Jin Xiongjie、Suzuki Kosuke、Sasano Yusuke、Iwabuchi Yoshiharu、Hasegawa Jun-ya、Mizuno Noritaka、Yamaguchi Kazuya
  • Journal Title: Chemical Science Volume: 9 Issue: 21 Pages: 4756-4768
  • DOI: 10.1039/c8sc01410h
  • Peer Reviewed / Open Access
• [Journal Article] Transition-Metal-Free Catalytic Formal Hydroacylation of Terminal Alkynes (2018)
  • Author(s): Yatabe Takafumi、Mizuno Noritaka、Yamaguchi Kazuya
  • Journal Title: ACS Catalysis Volume: 8 Issue: 12 Pages: 11564-11569
  • DOI: 10.1021/acscatal.8b02832
  • Peer Reviewed
• [Journal Article] Aerobic Oxygenation of Alkylarenes over Ultrafine Transition-Metal-Containing Manganese-Based Oxides (2018)
  • Author(s): S. Nakai, T. Uematsu, Y. Ogasawara, K. Suzuki, K. Yamaguchi, N. Mizuno
  • Journal Title: ChemCatChem Volume: 10 Issue: 5 Pages: 1096-1106
  • DOI: 10.1002/cctc.201701587
  • Peer Reviewed
• [Journal Article] Selective Synthesis of Primary Anilines from Cyclohexanone Oximes by the Concerted Catalysis of a Mg-Al Layered Double Hydroxide Supported Pd Catalyst (2017)
  • Author(s): X. Jin, Y. Koizumi, K. Yamaguchi, K. Nozaki, N. Mizuno
  • Journal Title: J. Am. Chem. Soc. Volume: 139 Issue: 39 Pages: 13821-13829
  • DOI: 10.1021/jacs.7b07347
  • Peer Reviewed
• [Journal Article] Formal Arylation of NH3 to Produce Diphenylamines over Supported Pd Catalysts (2017)
  • Author(s): Y. Koizumi, K. Taniguchi, X. Jin, K. Yamaguchi, K. Nozaki, N. Mizuno
  • Journal Title: Chem. Commun. Volume: 53 Issue: 78 Pages: 10827-10830
  • DOI: 10.1039/c7cc06737b
  • Peer Reviewed
• [Journal Article] Platinum-supporting hollandite-type vanadium-chromium mixed oxides as efficient heterogeneous catalysts for deoxygenation of sulfoxides under atmospheric H2 pressure (2017)
  • Author(s): T. Uematsu, Y. Ogasawara, K. Suzuki, K. Yamaguchi, N. Mizuno
  • Journal Title: Catal. Sci. Technol. Volume: 7 Issue: 9 Pages: 1912-1920
  • DOI: 10.1039/c7cy00547d
  • Peer Reviewed
• [Journal Article] A Ni-Mg-Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromatization (2017)
  • Author(s): Jin, X.; Taniguchi, K.; Yamaguchi, K.; Nozaki, K.; Mizuno, N.
  • Journal Title: Chem. Commun. Volume: 53 Issue: 38 Pages: 5267-5270
  • DOI: 10.1039/c7cc01182b
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] “Release and catch” catalysis by tungstate species for the oxidative cleavage of olefins (2017)
  • Author(s): Yoshimura, Y.; Ogasawara, Y.; Suzuki, K.; Yamaguchi, K.; Mizuno, N.
  • Journal Title: Catal. Sci. Technol. Volume: 7 Issue: 8 Pages: 1662-1670
  • DOI: 10.1039/c7cy00062f
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Phosphovanadomolybdic acid catalyzed direct C-H trifluoromethylation of (hetero)arenes using NaSO2CF3 as the CF3 source and O2 as the terminal oxidant (2017)
  • Author(s): Li, C.; Suzuki, K.; Yamaguchi, K.; Mizuno, N.
  • Journal Title: New J. Chem. Volume: 41 Issue: 4 Pages: 1417-1420
  • DOI: 10.1039/c6nj03654f
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold-palladium bimetallic nanoparticles (2017)
  • Author(s): Taniguchi, K.; Jin, X.; Yamaguchi, K.; Nozaki, K.; Mizuno, N.
  • Journal Title: Chem. Sci. Volume: 8 Issue: 3 Pages: 2131-2142
  • DOI: 10.1039/c6sc04455g
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Gold nanoparticles on OMS-2 for heterogeneously catalyzed aerobic oxidative α,β-dehydrogenation of β-heteroatom-substituted ketones (2016)
  • Author(s): Yoshii, D.; Jin, X.; Yatabe, T.; Hasegawa, J.; Yamaguchi, K.; Mizuno, N.
  • Journal Title: Chem. Commun. Volume: 52 Issue: 99 Pages: 14314-14317
  • DOI: 10.1039/c6cc07846j
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Au-Pd alloy nanoparticles supported on layered double hydroxide for heterogeneously catalyzed aerobic oxidative dehydrogenation of cyclohexanols and cyclohexanones to phenols (2016)
  • Author(s): Jin, X.; Taniguchi, K.; Yamaguchi, K.; Mizuno, N.
  • Journal Title: Chem. Sci. Volume: 7 Issue: 8 Pages: 5371-5383
  • DOI: 10.1039/c6sc00874g
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Supported Gold Nanoparticles for Efficient α-Oxygenation of Secondary and Tertiary Amines into Amides (2016)
  • Author(s): Jin, X.; Kataoka, K.; Yatabe, T.; Yamaguchi, K.; Mizuno, N.
  • Journal Title: Angew. Chem. Int. Ed. Volume: 55 Issue: 25 Pages: 7212-7217
  • DOI: 10.1002/anie.201602695
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Phosphovanadomolybdic acids catalyzed desulfurization-oxygenation of secondary and tertiary thioamides into amides using molecular oxygen as the terminal oxidant (2016)
  • Author(s): Xu, N.; Jin, X.; Suzuki, K.; Yamaguchi, K.; Mizuno, N.
  • Journal Title: New. J. Chem. Volume: 40 Issue: 6 Pages: 4865-4869
  • DOI: 10.1039/c5nj03579a
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Rational Low-Temperature Synthesis of Ultrasmall Nanocrystalline Manganese Binary Oxide Catalysts under Controlled Metal Cation Hydration in Organic Media (2016)
  • Author(s): Miyamoto, Y.; Kuroda, Y.; Uematsu, T.; Oshikawa, H.; Shibata, N.; Ikuhara, Y.; Suzuki, K.; Hibino, M. ; Yamaguchi, K.; Mizuno, N.
  • Journal Title: ChemNanoMat Volume: 2 Issue: 4 Pages: 297-306
  • DOI: 10.1002/cnma.201600114
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis of ultrasmall Li-Mn spinel oxides exhibiting unusual ion exchange, electrochemical, and catalytic properties (2015)
  • Author(s): Y. Miyamoto, Y. Kuroda, T. Uematsu, H. Oshikawa, N. Shibata, Y. Ikuhara, K. Suzuki, M. Hibino, K. Yamaguchi, N. Mizuno
  • Journal Title: Sci. Rep. Volume: 5 Issue: 1 Pages: 15011-15011
  • DOI: 10.1038/srep15011
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Gold Nanoparticles Supported on a Layered Double Hydroxide as Efficient Catalysts for the One-Pot Synthesis of Flavones (2015)
  • Author(s): T. Yatabe, X. Jin, K. Yamaguchi, N. Mizuno
  • Journal Title: Angew. Chem. Int. Ed. Volume: 54 Issue: 45 Pages: 13302-13306
  • DOI: 10.1002/anie.201507134
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Supported gold-palladium alloy nanoparticles catalyzed tandem oxidation routes to N-substituted anilines from non-aromatic compounds (2015)
  • Author(s): K. Taniguchi, X. Jin, K. Yamaguchi, N. Mizuno
  • Journal Title: Chem. Commun. Volume: 51 Issue: 81 Pages: 14969-14972
  • DOI: 10.1039/c5cc06514c
  • Peer Reviewed / Acknowledgement Compliant
• [Presentation] 銅/ニトロキシルラジカル触媒を用いた第三級アミンのホルムアミドへのメチル選択的酸素化 (2019)
  • Author(s): 中井諭，谷田部孝文，鈴木康介，笹野裕介，岩渕好治，長谷川淳也，水野哲孝，山口和也
  • Organizer: 第５２回酸化反応討論会
• [Presentation] パラジウムナノ粒子触媒を用いた脱水素芳香環形成反応によるトリアリールアミンの合成", ポスター発表 (2019)
  • Author(s): 高山聡，小泉悠，谷田部孝文，水野哲孝，山口和也
  • Organizer: 第9回CSJ化学フェスタ2019
• [Presentation] チオールのC-S結合開裂を経るカップリング反応の開発 (2019)
  • Author(s): 三田村侃樹・山本喜大・谷田部孝文・水野哲孝・山口和也
  • Organizer: 第9回CSJ化学フェスタ2019
• [Presentation] 担持Au-Pd合金ナノ粒子触媒を用いた飽和カルボニル化合物からα,β-不飽和カルボニル化合物への酸化的脱水素反応 (2019)
  • Author(s): 竹井大輔, 谷田部孝文, 金雄傑, 矢部智宏, 山口和也, 水野哲孝
  • Organizer: 第124回触媒討論会
• [Presentation] 担持Pd ナノ粒子触媒を用いた脱水素芳香環形成反応によるトリアリールアミン合成 (2019)
  • Author(s): 高山聡，小泉悠，谷田部孝文，水野哲孝，山口和也
  • Organizer: 第124回触媒討論会
• [Presentation] 担持金属ナノ粒子触媒による第二級アミンの単純脱水素型α位酸素化反応 (2019)
  • Author(s): 大山貴史，谷田部孝文，矢部智宏，水野哲孝，山口和也
  • Organizer: 第124回触媒討論会
• [Presentation] GREEN AMIDE PRODUCTION THROUGH CATALYTIC FORMAL OXYGENATION OF AMINES (2019)
  • Author(s): K. Yamaguchi, T. Yatabe, X. Jin, N. Mizuno
  • Organizer: The 8th Asia Pacific Congress on Catalysis
  • Int'l Joint Research
• [Presentation] Dehydrogenative Aromatization to Produce Arylamines over Supported Palladium Catalysts (2019)
  • Author(s): K. Yamaguchi, Y. Koizumi, X. Jin, N. Mizuno
  • Organizer: 17th Korea-Japan Symposium on Catalysis
  • Int'l Joint Research
• [Presentation] Dehydrogenative Mono- or Diborylation of Styrenes by Supported Copper Catalysts (2019)
  • Author(s): D. Yoshii, X. Jin, N. Mizuno, K. Yamaguchi
  • Organizer: 17th Korea-Japan Symposium on Catalysis
  • Int'l Joint Research
• [Presentation] Development of Novel Transformations by Utilizing Gold-Catalyzed Heterogeneous Aerobic Dehydrogenation (2019)
  • Author(s): Kazuya Yamaguchi
  • Organizer: RSC Journal symposium: Frontiers of catalysis and photocatalysis for energy chemistry
  • Invited
• [Presentation] Synthesis of phenols and anilines via heterogeneously Pd-catalyzed acceptorless dehydrogenative aromatization of six-membered carbocyclic compounds (2018)
  • Author(s): Kazuya Yamaguchi
  • Organizer: 2018 International Symposium on Advancement and Prospect of Catalysis Science & Technology
  • Invited
• [Presentation] Synthesis of phenols and anilines through acceptorless dehydrogenative aromatization catalysis over supported Pd nanoparticles (2018)
  • Author(s): Kazuya Yamaguchi
  • Organizer: The 8th Tokyo Conference on Advanced Catalytic Science and Technology
  • Invited
• [Presentation] Development of Novel Transformations by Utilizing Gold-Catalyzed Heterogeneous Aerobic Dehydrogenation (2018)
  • Author(s): Kazuya Yamaguchi
  • Organizer: The International Symposium on Catalysis and Fine Chemicals 2018
  • Invited
• [Presentation] Dehydrogenative Aromatization Strategy for Synthesis of Phenols, Anilines, and Diarylamines (2018)
  • Author(s): Kazuya Yamaguchi
  • Organizer: 16th Japan-Taiwan Joint Symposium on Catalysis-New Horizon of Catalytic Science and Technology-
  • Int'l Joint Research / Invited
• [Presentation] Layered Double Hydroxide Supported Palladium Nanoparticles for Efficient Heterogeneous Acceptorless Dehydrogenative Aromatization Reactions (2018)
  • Author(s): 金雄傑
  • Organizer: 日本化学会第98春季年会
  • Invited
• [Presentation] 層状複水酸化物担持パラジウム触媒によるアクセプターレス脱水素芳香環形成反応 (2018)
  • Author(s): 金雄傑，山口和也，野崎京子，水野哲孝
  • Organizer: 第121回触媒討論会
• [Presentation] Visible-Light-Induced Aerobic Oxidation of Sulfides by a Phosphovanadotungstate (2018)
  • Author(s): Chifeng Li, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno
  • Organizer: 日本化学会第98春季年会
• [Presentation] nprecedented Catalytic Aurone Synthesis Enabled by Design of a Pd-on-Au Bimetallic Nanoparticle Catalyst Supported on CeO2 (2018)
  • Author(s): Takafumi Yatabe, Xiongjie Jin, Kazuya Yamaguchi, Noritaka Mizuno
  • Organizer: 日本化学会第98春季年会
• [Presentation] 担持銅触媒によるスチレン誘導体の脱水素ボリル化反応 (2018)
  • Author(s): 吉井大地，金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第98春季年会
• [Presentation] 担持金-パラジウム合金ナノ粒子触媒によるアンモニアの選択的モノアリール化反応 (2018)
  • Author(s): 小泉悠，金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第98春季年会
• [Presentation] 担持パラジウムナノ粒子触媒によるピペリジン類のアクセプターレス脱水素反応 (2018)
  • Author(s): 大山貴史，金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第98春季年会
• [Presentation] 担持Au-Pdナノ粒子触媒によるアルデヒドおよびケトンの酸化的脱水素反応 (2018)
  • Author(s): 竹井 大輔, 谷田部 孝文, 金 雄傑, 山口 和也, 水野 哲孝
  • Organizer: 日本化学会第98春季年会
• [Presentation] Cu/N-oxyl触媒酸化系によるビシナルジオールからのα-ケトカルボニル化合物合成 (2018)
  • Author(s): 和知慶樹，片岡憲吾，金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第98春季年会
• [Presentation] Heterogeneously Catalyzed New Green Amide Synthesis (2017)
  • Author(s): Kazuya Yamaguchi
  • Organizer: The Tenth International Conference on the Science and Technology for Advanced Ceramics (STAC-10)
  • Int'l Joint Research / Invited
• [Presentation] Au-Pd Bimetallic Nanoparticles-Catalyzed Dehydrogenative Aromatization Reactions for Synthesis of Arylamines (2017)
  • Author(s): Kento Taniguchi, Xiongjie Jin, Kazuya Yamaguchi, Noritaka Mizuno
  • Organizer: Interdisciplinary Symposium for Up-and-coming Material Scientists 2017 (ISUMS 2017)
  • Int'l Joint Research
• [Presentation] Aerobic Oxidative Trifluoromethylation of Arenes Catalyzed by Phosphovanadomolybdic Acids (2017)
  • Author(s): Chifeng Li, Kosuke Suzuki, Kazuya Yamaguchi, Noritaka Mizuno
  • Organizer: 16th Korea-Japan Symposium on Catalysis & 3rd International Symposium on Institute for Catalysis
  • Int'l Joint Research
• [Presentation] One-pot Green Synthesis of Flavones Using Gold Nanoparticles Supported on Layered Double Hydroxides (2017)
  • Author(s): 5.Takafumi Yatabe, Xiongjie Jin, Kazuya Yamaguchi, Noritaka Mizuno
  • Organizer: The 16th Korea-Japan Symposium on Catalysis (KJSC16)
  • Int'l Joint Research
• [Presentation] 担持パラジウムナノ粒子触媒によるアンモニアの形式的アリール化反応 (2017)
  • Author(s): 小泉悠，谷口健人，金雄傑，山口和也，水野哲孝
  • Organizer: 第50回酸化反応討論会
• [Presentation] 異種遷移金属を導入したナノマンガン酸化物触媒によるアルキルアレーンの酸素酸化 (2017)
  • Author(s): 中井諭, 山口和也, 水野哲孝
  • Organizer: 第50回酸化反応討論会
• [Presentation] 銅触媒によるアルコールを用いたアミドの酸化的アシル化反応 (2017)
  • Author(s): 片岡憲吾，金雄傑，山口和也，水野哲孝
  • Organizer: 第50回酸化反応討論会
• [Presentation] CeO2担持Pd-on-Auナノ粒子触媒による選択性逆転を利用したオーロン合成 (2017)
  • Author(s): 谷田部孝文，金雄傑，山口和也，水野哲孝
  • Organizer: 第50回酸化反応討論会
• [Presentation] 担持パラジウムナノ粒子触媒によるアンモニアの形式的アリール化反応 (2017)
  • Author(s): 小泉悠，谷口健人，金雄傑，山口和也，水野哲孝
  • Organizer: 第7回CSJ化学フェスタ2017
• [Presentation] 異種遷移金属導入ナノマンガン酸化物触媒によるアルキルアレーンの酸素酸化 (2017)
  • Author(s): 中井諭, 山口和也, 水野哲孝
  • Organizer: 第7回CSJ化学フェスタ2017
• [Presentation] 銅触媒を用いたアルコールによるアミドの酸化的アシル化反応 (2017)
  • Author(s): 片岡憲吾，金雄傑，山口和也，水野哲孝
  • Organizer: 第7回CSJ化学フェスタ2017
• [Presentation] Photocatalytic Aerobic Oxidation of Sulfides by a Visible-Light-Responsive Phosphovanadotungstate (2017)
  • Author(s): 李赤峰，鈴木康介，山口和也，水野哲孝
  • Organizer: 第7回CSJ化学フェスタ2017
• [Presentation] CeO2担持Au-;Pd ナノ粒子触媒による選択性逆転を利用したオーロン合成 (2017)
  • Author(s): 谷田部孝文，金雄傑，山口和也，水野哲孝
  • Organizer: 第120回触媒討論会
• [Presentation] Mg-Al LDH担持パラジウム触媒によるシクロヘキサノンオキシムのアニリンへのアクセプターレス脱水素酸化反応 (2017)
  • Author(s): 金雄傑，山口和也，水野哲孝
  • Organizer: 第120回触媒討論会
• [Presentation] 過酸化水素を用いたオレフィンの酸化開裂反応を指向した担持タングステート触媒の開発 (2017)
  • Author(s): 吉村悠，小笠原義之，鈴木康介，山口和也，水野哲孝
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応義塾大学（神奈川県・横浜市）
• [Presentation] Phosphovanadomolybdic Acid Catalyzed Trifluoromethylation of Arenes (2017)
  • Author(s): Li, C.; Suzuki, K.; Yamaguchi, K.; Mizuno, N.
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応義塾大学（神奈川県・横浜市）
• [Presentation] 担持パラジウムナノ粒子触媒によるアンモニアのアリール化反応 (2017)
  • Author(s): 小泉悠，谷口健人，金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応義塾大学（神奈川県・横浜市）
• [Presentation] Synthesis of Diarylamines through Supported Gold-Palladium Nanoparticles-Catalyzed Acceptorless Dehydrogenative Aromatization (2017)
  • Author(s): Taniguchi, K.; Jin, X.; Yamaguchi, K.; Mizuno, N.
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応義塾大学（神奈川県・横浜市）
• [Presentation] ホランダイト型バナジウム酸化物を用いたスルホキシドの触媒的還元 (2017)
  • Author(s): 植松翼，宮本唯未，山口和也，水野哲孝
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応義塾大学（神奈川県・横浜市）
• [Presentation] 異種遷移金属を導入したナノマンガン酸化物触媒によるアルキルアレーンの酸素酸化 (2017)
  • Author(s): 中井諭，植松翼，宮本唯未，山口和也，水野哲孝
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応義塾大学（神奈川県・横浜
• [Presentation] 銅触媒によるアルコールを用いたアミドの酸化的アシル化反応 (2017)
  • Author(s): 片岡憲吾，金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応義塾大学（神奈川県・横浜
• [Presentation] OMS-2担持金ナノ粒子触媒による酸素を酸化剤としたβ-ヘテロ原子置換飽和ケトンのα,β-脱水素反応 (2017)
  • Author(s): 吉井大地，谷田部孝文，金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応義塾大学（神奈川県・横浜
• [Presentation] Ni-Mg-Al層状複合水酸化物担持Pd触媒による高効率アクセプターレス脱水素芳香環形成反応 (2017)
  • Author(s): 金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第97春季年会
  • Place of Presentation: 慶応義塾大学（神奈川県・横浜
• [Presentation] 有機溶媒中でのLi+の水和状態制御に基づく極微Li-Mnスピネルナノ粒子の合成 (2016)
  • Author(s): 宮本唯未，黒田義之，植松翼，押川浩之，柴田直哉，幾原雄一，鈴木康介，日比野光宏，山口和也，水野哲孝
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学，京田辺市，京都府
  • Year and Date: 2016-03-24
• [Presentation] Au-Pd合金ナノ粒子触媒による空気を酸化剤としたシクロヘキサノールのフェノールへの脱水素型酸化反応 (2016)
  • Author(s): 金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学，京田辺市，京都府
  • Year and Date: 2016-03-24
• [Presentation] 担持金-パラジウムナノ粒子触媒を用いたタンデム型脱水素芳香環形成反応によるN-置換アニリン合成 (2016)
  • Author(s): 谷口健人，金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学，京田辺市，京都府
  • Year and Date: 2016-03-24
• [Presentation] 酸化的脱水素反応を鍵反応とした環境調和型フラボン類One-Pot合成の開発 (2016)
  • Author(s): 谷田部孝文，金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学，京田辺市，京都府
  • Year and Date: 2016-03-24
• [Presentation] 担持金ナノ粒子触媒による酸素を酸化剤とした飽和ケトンのα,β-不飽和ケトンへの酸化的脱水素反応 (2016)
  • Author(s): 吉井大地，谷田部孝文，金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学，京田辺市，京都府
  • Year and Date: 2016-03-24
• [Presentation] 担持金ナノ粒子触媒による酸素を酸化剤としたアミンの形式的α-酸素化反応 (2016)
  • Author(s): 片岡憲吾，金雄傑，山口和也，水野哲孝
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学，京田辺市，京都府
  • Year and Date: 2016-03-24
• [Presentation] ENVIRONMENTALLY-FRIENDLY HETEROGENEOUS ONE-POT SYNTHESIS OF FLAVONES THROUGH THE CONCERTED CATALYSIS OF GOLD NANOPARTICLES SUPPORTED ON LAYERED DOUBLE HYDROXIDES (2016)
  • Author(s): Yatabe, T.; Jin, X.; Yamaguchi, K.; Mizuno, N.
  • Organizer: 6th Asia-Oceania Conference on Sustainable and Green Chemistry
  • Place of Presentation: Hong Kong (China)
  • Int'l Joint Research
• [Presentation] Supported Au-Pd alloy nanoparticles catalyzed tandem oxidative aromatization for synthesis of N-substituted anilines", Oral Presentation (2016)
  • Author(s): Taniguchi, K.; Jin, X.; Yamaguchi, K.; Mizuno, N.
  • Organizer: 16th International Congress on Catalysis
  • Place of Presentation: Beijing (China
  • Int'l Joint Research
• [Presentation] Aerobic oxidative dehydrogenation of cyclohexanols to phenols by layered double hydroxide supported Au-Pd alloy nanoparticles”, 16th International Congress on Catalysis", Poster Presentation (2016)
  • Author(s): Jin, X.; Yamaguchi, K.; Mizuno, N.
  • Organizer: 16th International Congress on Catalysis
  • Place of Presentation: Beijing, China)
  • Int'l Joint Research
• [Presentation] Aerobic Oxidative Trifluoromethylation of Aromatic Compounds Catalyzed by Vanadium-Containing Phosphomolybdic Acids (2016)
  • Author(s): 李赤峰，鈴木康介，山口和也，水野哲孝
  • Organizer: 第6回CSJ化学フェスタ2016
  • Place of Presentation: タワーホール船堀（東京都・江戸川）
• [Presentation] 担持金ナノ粒子触媒による酸素を酸化剤とした飽和ケトンのα,β-不飽和ケトンへの酸化的脱水素反応", ポスター発表 (2016)
  • Author(s): 吉井大地，谷田部孝文，金雄傑，山口和也，水野哲孝
  • Organizer: 第6回CSJ化学フェスタ2016
  • Place of Presentation: タワーホール船堀（東京都・江戸川）
• [Presentation] 担持金ナノ粒子触媒による酸素を酸化剤としたアミンのα-酸素化反応 (2016)
  • Author(s): 片岡憲吾，金雄傑，山口和也，水野哲孝
  • Organizer: 第6回CSJ化学フェスタ2016
  • Place of Presentation: タワーホール船堀（東京都・江戸川）
• [Presentation] 過酸化水素によるオレフィンの酸化開裂反応を目指した release and catch 触媒システムの開発 (2016)
  • Author(s): 吉村悠，小笠原義之，山口和也，水野哲孝
  • Organizer: 第6回CSJ化学フェスタ2016
  • Place of Presentation: タワーホール船堀（東京都・江戸川）
• [Presentation] 担持Au-Pd合金ナノ粒子触媒によるシクロヘキサノール及びシクロヘキサノンのフェノールへの脱水素型酸化反応" (2016)
  • Author(s): 金雄傑，山口和也，水野哲孝
  • Organizer: 第49回酸化反応討論会
  • Place of Presentation: 徳島大学（徳島県・徳島市）
• [Presentation] 担持金ナノ粒子触媒による酸素を酸化剤としたアミンのα-酸素化反応 (2016)
  • Author(s): 片岡憲吾，金雄傑，山口和也，水野哲孝
  • Organizer: 第118回触媒討論会
  • Place of Presentation: 岩手大学（岩手県・盛岡市）
• [Presentation] モリブドバナドリン酸を触媒としたチオアミドの脱硫－酸素化反応 (2016)
  • Author(s): 山口和也，徐寧，金雄傑，鈴木康介，水野哲孝
  • Organizer: 第118回触媒討論会
  • Place of Presentation: 岩手大学（岩手県・盛岡市）
• [Presentation] 有機溶媒中でのカチオンの水和状態制御に基づくMn系複酸化物ナノ粒子の合成と触媒特性 (2016)
  • Author(s): 宮本唯未，黒田義之，植松翼，押川浩之，柴田直哉，幾原雄一，鈴木康介，日比野光宏，山口和也，水野哲孝
  • Organizer: 第118回触媒討論会
  • Place of Presentation: 岩手大学（岩手県・盛岡市）
• [Presentation] Au/LDH触媒の協奏的触媒作用を利用した環境調和型フラボン類One-Pot合成 (2016)
  • Author(s): 谷田部孝文，金雄傑，山口和也，水野哲孝
  • Organizer: 第5回JACI/GSCシンポジウム
  • Place of Presentation: ANAクラウンプラザホテル神戸（兵庫県・神戸市）
• [Presentation] 金ナノ粒子担持LDH触媒によるMultiple Relay Catalysisを利用した液相不均一系フラボン類One-Pot合成 (2015)
  • Author(s): 谷田部孝文，金雄傑，山口和也，水野哲孝
  • Organizer: 第5回CSJ化学フェスタ2015
  • Place of Presentation: 船堀タワーホール，江戸川区，東京都
  • Year and Date: 2015-10-13
• [Presentation] Multiple Relay Catalysisを利用したAu/LDH触媒による液相不均一系フラボン類One-Pot合成 (2015)
  • Author(s): 谷田部孝文，金雄傑，山口和也，水野哲孝
  • Organizer: 第116回触媒討論会
  • Place of Presentation: 三重大学，津市，三重県
  • Year and Date: 2015-09-16
• [Presentation] 担持金ーパラジウム合金触媒を用いたタンデム型脱水素芳香環形成反応 (2015)
  • Author(s): 谷口健人，金雄傑，山口和也，水野哲孝
  • Organizer: 第116回触媒討論会
  • Place of Presentation: 三重大学，津市，三重県
  • Year and Date: 2015-09-16