Budget Amount *help |
¥35,880,000 (Direct Cost: ¥27,600,000、Indirect Cost: ¥8,280,000)
Fiscal Year 2019: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2018: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2017: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2016: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2015: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
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Outline of Final Research Achievements |
We have developed catalytic nitrogen fixation under mild reaction conditions using transition metal complexes as catalysts. Typically, we have found that iron, cobalt, and vanadium-dinitrogen complexes bearing pyrrole-based anionic PNP-type pincer ligands and molybdenum complexes bearing pyridine-based PNP-type pincer ligands and N-heterocyclic carbene-based PCP-type pincer ligands worked as effective catalysts toward formation of ammonia and hydrazine from dinitrogen.
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