| Budget Amount *help |
¥34,840,000 (Direct Cost: ¥26,800,000、Indirect Cost: ¥8,040,000)
Fiscal Year 2019: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2018: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2017: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2016: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2015: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
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| Outline of Final Research Achievements |
Catalytic direct functionalization of unreactive C-H, C-C, C-N, and C-O bonds, which are ubiquitous in organic molecules, is highly useful in organic synthesis in terms of atom- and step-economy. Much attention has been paid to these transformations and many research groups have reported various methods using different metal catalysts. Nevertheless, many of known protocols rely on the use of substrates having coordinating functional groups to direct metal catalysts and/or strains to be relieved to cleave such unreactive bonds. In this project, we have developed the synthetic organic transformations involving activation of these bonds in readily available conventional organic molecules, without using substrates specially prepared.
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