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Development of New Reactions Based on the Construction of Precisely Designed Multidentate Ligands

Planned Research

Project AreaPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions
Project/Area Number 15H05800
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

Iwasawa Nobuharu  東京工業大学, 理学院, 教授 (40168563)

Project Period (FY) 2015-06-29 – 2020-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥115,830,000 (Direct Cost: ¥89,100,000、Indirect Cost: ¥26,730,000)
Fiscal Year 2019: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2018: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2017: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2016: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2015: ¥52,910,000 (Direct Cost: ¥40,700,000、Indirect Cost: ¥12,210,000)
Keywords有機合成化学 / 遷移金属錯体 / 金属ー金属結合 / 有機化学 / 有機金属化学 / 触媒反応 / 異種二核金属錯体 / 合成化学 / 錯体化学
Outline of Final Research Achievements

By using 6,6 ”-bisphosphinoterpyridine ligands, we have successfully realized a general method for the synthesis of hetero-dinuclear metal complexes containing metal-metal bonds by sequentially introducing two different metals to the scaffold. In addition, we were able to accumulate a lot of knowledge about the structure and bonding of these complexes based on single crystal X-ray structure analysis and theoretical methods. Furthermore, by utilizing the characteristic properties of the prepared complexes, we have developed a highly efficient hydrosilylation of carbon dioxide and a selective reduction of aromatic nitriles. In the former reaction, the highest turnover frequency was achieved.

Academic Significance and Societal Importance of the Research Achievements

従来の遷移金属触媒を用いる反応開発ではもっぱら金属を一つ持つ錯体が用いられてきた。本研究では、新しい配位子PNNNP型配位子を用いて順次金属を導入するという手法により、金属-金属結合を持つ異種二核金属錯体の汎用的な合成法を確立し、異種金属-金属間の結合に関し系統的に知見を得ることができた。これらの成果は金属-金属結合を持つ異種二核金属錯体の化学という新しい研究分野の発展に大きく寄与するものである。また、これによりこれまで困難とされていた反応や高効率的な反応を実現することができ、遷移金属錯体触媒を用いて有用な物質を合成する際に新たな可能性を提供することができた。

Report

(6 results)
  • 2020 Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report

Research Products

(135 results)

All 2021 2020 2019 2018 2017 2016 2015 Other

All Int'l Joint Research (8 results) Journal Article (27 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 27 results,  Acknowledgement Compliant: 4 results) Presentation (100 results) (of which Int'l Joint Research: 17 results,  Invited: 13 results)

  • [Int'l Joint Research] ICIQ(スペイン)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] University of Alberta(カナダ)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Xi'an Jiaotong University(中国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] ICIQ(スペイン)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] University of Alberta(カナダ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Xi’an Jiaotong University(中国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] ICIQ(Spain)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] University of Alberta(Canada)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Mechanistic Investigations of the Ruthenium-Catalyzed Synthesis of Acrylate Salt from Ethylene and CO22020

    • Author(s)
      Takahashi Kohei、Hirataka Yo、Ito Tatsuyoshi、Iwasawa Nobuharu
    • Journal Title

      Organometallics

      Volume: 39 Issue: 9 Pages: 1561-1572

    • DOI

      10.1021/acs.organomet.9b00659

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rh‐Catalyzed Direct Carboxylation of Alkenyl C-H Bonds of Alkenylpyrazoles2020

    • Author(s)
      Saitou Takanobu、Jin Yushu、Isobe Kotaro、Suga Takuya、Takaya Jun、Iwasawa Nobuharu
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 15 Issue: 13 Pages: 1941-1944

    • DOI

      10.1002/asia.202000476

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Chemoselective Hydrosilylation of Nitriles to an Imine Oxidation Level Enabled by a Pincer-type Group 13 Metallylene Ligand2020

    • Author(s)
      Takaya Jun、Ogawa Koki、Nakaya Ryota、Iwasawa Nobuharu
    • Journal Title

      ACS Catalysis

      Volume: 10 Issue: 20 Pages: 12223-12228

    • DOI

      10.1021/acscatal.0c02779

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Photocatalysis by Utilizing the Host-Guest Charge‐Transfer Interaction: Visible‐Light‐Induced Generation of Triplet Anthracenes for [4+2] Cycloaddition Reactions2020

    • Author(s)
      Uchikura Tatsuhiro、Oshima Mari、Kawasaki Minami、Takahashi Kohei、Iwasawa Nobuharu
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 59 Issue: 19 Pages: 7403-7408

    • DOI

      10.1002/anie.201916732

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Controlled release of the guest molecule via borate formation of a fluorinated boronic ester cage2020

    • Author(s)
      Takata Hisatsugu、Ono Kosuke、Iwasawa Nobuharu
    • Journal Title

      Chemical Communications

      Volume: 56 Issue: 42 Pages: 5613-5616

    • DOI

      10.1039/d0cc01441a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, structure, and reactivity of pincer-type iridium complexes having gallyl- and indyl-metalloligands utilizing 2,5-bis(6-phosphino-2-pyridyl)pyrrolide as a new scaffold for metal-metal bonds2019

    • Author(s)
      Takaya Jun、Hoshino Mayuko、Ueki Kanako、Saito Narumasa、Iwasawa Nobuharu
    • Journal Title

      Dalton Transactions

      Volume: 48 Issue: 39 Pages: 14606-14610

    • DOI

      10.1039/c9dt03443a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rhodium‐Catalyzed C-H Activation Enabled by an Indium Metalloligand2019

    • Author(s)
      Yamada Ryosuke、Iwasawa Nobuharu、Takaya Jun
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 58 Issue: 48 Pages: 17251-17254

    • DOI

      10.1002/anie.201910197

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reactivity of Ruthenium(0) Complex Bearing a Tetradentate Phosphine Ligand: Applications to Catalytic Acrylate Salt Synthesis from Ethylene and CO22019

    • Author(s)
      T. Ito, K. Takahashi, N. Iwasawa
    • Journal Title

      Organometallics

      Volume: 38 Issue: 2 Pages: 205-209

    • DOI

      10.1021/acs.organomet.8b00789

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ruthenium-catalyzed ortho C-H Borylation of Arylphosphines: A Powerful Tool for Late-Stage Modification of Phosphorus Compounds2019

    • Author(s)
      K. Fukuda, N. Iwasawa, J. Takaya
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 58 Issue: 9 Pages: 2850-2853

    • DOI

      10.1002/anie.201813278

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 1,2-Dihydro-1-hydroxy-2,3,1-benzodiazaborine Bearing an Acridine Moiety as a CD Probe for Determination of Absolute Configuration of Mono-alcohols2019

    • Author(s)
      S. Shimo, K. Takahashi, N. Iwasawa
    • Journal Title

      Chem. Eur. J.

      Volume: 25 Issue: 15 Pages: 3790-3794

    • DOI

      10.1002/chem.201900350

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Re(I)-Catalyzed Hydropropargylation of Enamides: A Useful Method for the Preparation of 4-Pentynylamine Derivatives2019

    • Author(s)
      S. Watanabe, A. Ario, N. Iwasawa
    • Journal Title

      J. Antibiotics

      Volume: 72 Issue: 6 Pages: 490-493

    • DOI

      10.1038/s41429-019-0162-3

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-assembly of macrocyclic boronic esters bearing tellurophene moieties and their guest responsive phosphorescence2019

    • Author(s)
      K. Takahashi, S. Shimo, E. Hupf, J. Ochiai, C. A. Braun, W. T. Delgado, L. Xu, G. He, E. Rivard, N. Iwasawa
    • Journal Title

      Chem. Eur. J.

      Volume: 25 Issue: 36 Pages: 8479-8483

    • DOI

      10.1002/chem.201901319

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Re(I)-Catalyzed Hydropropargylation of Silyl Enol Ethers Utilizing Dynamic Interconversion of Vinylidene-Alkenylmetal Intermediates via 1,5-Hydride Transfer2018

    • Author(s)
      N. Iwasawa, S. Watanabe, A. Ario, H. Sogo
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 140 Issue: 25 Pages: 7769-7772

    • DOI

      10.1021/jacs.8b02903

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structure, and Reactivity of a Mononuclear η2-(Ge-H)palladium(0) Complex Bearing a PGeP-Pincer Type Ligand: Reactivity Differences Between Silicon and Germanium2018

    • Author(s)
      J. Takaya, N. Iwasawa
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: 2018 Issue: 46 Pages: 5012-5018

    • DOI

      10.1002/ejic.201801257

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Aluminum-Metalloligand in Hydrosilylation of CO22017

    • Author(s)
      Takaya Jun、Iwasawa Nobuharu
    • Journal Title

      Journal of the American Chemical Society

      Volume: 139 Issue: 17 Pages: 6074-6077

    • DOI

      10.1021/jacs.7b02553

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible Light-Driven Carboxylation of Aryl Halides by the Combined Use of Palladium and Photoredox Catalysts2017

    • Author(s)
      K. Shimomaki, K. Murata, R. Martin, N. Iwasawa
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 139 Issue: 28 Pages: 9467-9470

    • DOI

      10.1021/jacs.7b04838

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Utilization of Donor-Acceptor Interaction for the Catalytic Acceleration of the Nucleophilic Addition to Aromatic Carbonyl Compounds2017

    • Author(s)
      T. Uchikura, K. Ono, K. Takahashi, N. Iwasawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 57 Issue: 8 Pages: 2130-2133

    • DOI

      10.1002/anie.201711726

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamic Interconversion Between Boroxine Cages Based on Pyridine Ligation2017

    • Author(s)
      K. Ono, S. Shimo, K. Takahashi, N. Yasuda, H. Uekusa, N. Iwasawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 57 Issue: 12 Pages: 3113-3117

    • DOI

      10.1002/anie.201713221

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Reactivity of Iron- and Cobalt-Dinitrogen Complexes Bearing PSiP-Type Pincer Ligands toward Nitrogen Fixation2017

    • Author(s)
      Imayoshi Ryuji、Nakajima Kazunari、Takaya Jun、Iwasawa Nobuharu、Nishibayashi Yoshiaki
    • Journal Title

      European Journal of Inorganic Chemistry

      Volume: 2017 Issue: 32 Pages: 3769-3778

    • DOI

      10.1002/ejic.201700569

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanistic Study of the Rhodium-Catalyzed Carboxylation of Simple Aromatic Compounds with Carbon Dioxide2017

    • Author(s)
      Suga, T.; Saitou, T.; Takaya J.; Iwasawa, N.
    • Journal Title

      Chem. Sci.

      Volume: 8 Issue: 2 Pages: 1454-1462

    • DOI

      10.1039/c6sc03838g

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Construction of a Visible Light-Driven Hydrocarboxylation Cycle of Alkenes by the Combined Use of Rh(I) and Photoredox Catalysts2017

    • Author(s)
      Murata, K.; Numasawa, N.; Shimomaki, K.; Takaya, J.; Iwasawa, N.
    • Journal Title

      Chem. Commun.

      Volume: 53 Issue: 21 Pages: 3098-3101

    • DOI

      10.1039/c7cc00678k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Metallic Reductant-Free Synthesis of α-Substituted Propionic Acid Derivatives through Hydrocarboxylation of Alkenes with Formate Salt2017

    • Author(s)
      Takaya, J.; Miyama, K.; Zhu, C.; Iwasawa, N.
    • Journal Title

      Chem. Commun.

      Volume: 53 Issue: 28 Pages: 3982-3985

    • DOI

      10.1039/c7cc01377a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Total Synthesis of (±)-Integrifolin2016

    • Author(s)
      Shimomaki, K.; Kusama, H.; Iwasawa, N.
    • Journal Title

      Chem. Eur. J.

      Volume: 22 Issue: 29 Pages: 9953-9957

    • DOI

      10.1002/chem.201601275

    • NAID

      130007722903

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Re(I)-Catalyzed Generation of α,β-Unsaturated Carbene Complex Intermediates from Propargyl Ethers for Preparation of Cycloheptadiene Derivatives2016

    • Author(s)
      Sogo, H.; Iwasawa, N.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 34 Pages: 10057-10060

    • DOI

      10.1002/anie.201604371

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Total Synthesis of Englerin A Utilizing Intermolecular [3+2] Cycloaddition Reaction of Platinum-Containing Carbonyl Ylide2016

    • Author(s)
      H. Kusama, A. Tazawa, K. Ishida, and N. Iwasawa
    • Journal Title

      Chem. Asian J.

      Volume: 11 Issue: 1 Pages: 64-67

    • DOI

      10.1002/asia.201500935

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Total Synthesis of Proposed Structure of Yuremamine and All Diastereomers Using [3+2]-Cycloaddition of Platinum-Containing Azomethine Ylide2015

    • Author(s)
      T. Ohyama, M. Uchida, H. Kusama, and N. Iwasawa
    • Journal Title

      Chem. Asian J.

      Volume: 10 Issue: 9 Pages: 1850-1853

    • DOI

      10.1002/asia.201500491

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fluorine-controlled C-H borylation of arenes catalyzed by a PSiN-pincer platinum complex2015

    • Author(s)
      Jun Takaya, Shisei Ito, Hironori Nomoto, Narumasa Saito, Naohiro Kirai and Nobuharu Iwasawa
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 100 Pages: 17662-17665

    • DOI

      10.1039/c5cc07263h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 大環状ボロン酸エステルをホスト分子触媒とする光付加環化反応の開発2021

    • Author(s)
      川崎 美波・大島 真理・高橋 講平・岩澤 伸治
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 2-キノリルベンゾジアザボリン誘導体のボラート形成挙動と光物性評価2020

    • Author(s)
      中村拓夢・志茂俊輔・高橋講平・鳥海尚之・岩澤伸治
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Rhodium-catalyzed meta-Selective Carboxylation Reaction of 1,1- Diarylethylenes via Hydrorhodation-Rhodium Migration2020

    • Author(s)
      SAITOU, Takanobu; TORIUMI, Naoyuki; IWASAWA, Nobuharu
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] trans-Selective Hydroboration of Terminal Alkynes Catalyzed by PSP Pincer Rh Catalyst2020

    • Author(s)
      LYU, Yanzong; TORIUMI, Naoyuki; IWASAWA, Nobuharu
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ルテニウムを配位子とする後周期遷移金属錯体の合成と反応2020

    • Author(s)
      中村優太・斉藤成将・鷹谷 絢・岩澤伸治
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ピンサー型ガリレン配位子を持つロジウム錯体によるニトリル の化学選択的ヒドロシリル化反応2020

    • Author(s)
      小川功喜・中屋良 太・鷹谷 絢・岩澤伸治
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ジアリールホスフィノ基の置換した PCP ピンサー型アルコキシカルベン配位子を有するイリジウム錯体とアルケンとの特異な反応性2020

    • Author(s)
      石川大志・高橋講平・岩澤伸治
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ホスフィノメチル基の置換した NHC 配位子を有するニッケララクトンの光反応性2020

    • Author(s)
      岩井朝希・高橋講平・岩澤伸治
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 四座ホスフィン配位子を有する 0 価ルテニウム錯体を触媒とす るアリルエーテルを用いた求電子的アリル化反応2020

    • Author(s)
      渡辺 雄太・平高 遥・高橋講平・岩澤伸治
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] レニウム触媒を用いた電子豊富なアルケンとο-エチニルフェニルカルボニル化合物からの多環性化合物とナフタレン誘導体の選択的合成2020

    • Author(s)
      高野拓人・岩澤伸治
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] CANER, Joaquim; SHIMOMAKI, Katsuya; MURATA, Kei; TORIUMI, Naoyuki; MARTIN, Ruben; IWASAWA, Nobuharu2020

    • Author(s)
      Clarification of the Nucleophilic Species in the Carboxylation of Aryl (Pseudo)Halides with CO2 using Pd/Photoredox Dual Catalysts
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 6,6”-ビスホスフィノテルピリジンを多座配位子とするルテニウム-後周期遷移金属二核錯体の合成、構造、反応性2019

    • Author(s)
      中村 優太, 斉藤 成将, 鷹谷 絢, 岩澤 伸治
    • Organizer
      錯体化学会 第69回討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Pd/Photoredox二元触媒系による二酸化炭素を用いたアリール及びアルケニルトリフラートの可視光駆動型触媒的カルボキシル化反応の開発2019

    • Author(s)
      中島知也、本田純、Joaquim Caner、鳥海尚之、岩澤伸治
    • Organizer
      第36回有機合成化学セミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] ホスフィノメチル基の置換したNHC-Pニッケル錯体を用いたエチレンと二酸化炭素からのアクリル酸塩の触媒的合成2019

    • Author(s)
      岩井朝希、張錦良、高橋講平、岩澤伸治
    • Organizer
      第36回有機合成化学セミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] 高周期14族元素含有ピンサー型配位子を持つ鉄-亜鉛複核錯体の合成と反応2019

    • Author(s)
      瀧澤開、三浦律男、伊藤龍好、鷹谷絢、岩澤伸治
    • Organizer
      第36回有機合成化学セミナー
    • Related Report
      2019 Annual Research Report
  • [Presentation] ピンサー型アルコキシカルベン配位子を有するイリジウム錯体とアルケンおよびアルキンとの反応2019

    • Author(s)
      高橋 講平・岩澤 伸治
    • Organizer
      第66回有機金属化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] PSiP-ピンサー型白金錯体と銀塩によるベンゼンの C―H 結合変換反応2019

    • Author(s)
      中屋 良太・鷹谷 絢 ・岩澤 伸治
    • Organizer
      第66回有機金属化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 13 族メタリレン含有ピンサー型ロジウム錯体によ るニトリルのイミンへの選択的ヒドロシリル化反応2019

    • Author(s)
      小川 功喜・中屋 良太・鷹谷 絢・岩澤 伸治
    • Organizer
      第66回有機金属化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Reductants for Carboxylation Reactions2018

    • Author(s)
      N. Iwasawa
    • Organizer
      The 8th International Forum on Homogeneous Catalysis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Visible-light Driven Carboxylation Reactions2018

    • Author(s)
      N. Iwasawa
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Generation and Utilization of a,b-Unsaturated Carbene Complex Intermediates for the Construction of Useful Carbon Skeletons2018

    • Author(s)
      S. Watanabe, H. Sogo, N. Iwasawa,
    • Organizer
      The 1st Sino-Japanese Symposium on Catalysis for Precision Synthesis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of Visible Light-Driven Hydrocarboxylation of Alkenes by the Rh(I) and Photoredox Catalysts2018

    • Author(s)
      K. Murata, N. Numasawa, K. Shimomaki, J. Takaya, N. Iwasawa,
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] PSiP-Platinum Complexes-Promoted C-H Bond Activation and Transformation of Benzene2018

    • Author(s)
      R. Nakaya, J. Takaya, N. Iwasawa,
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ruthenium-catalyzed Synthesis of Acrylic Acid from Ethylene and CO22018

    • Author(s)
      T. Ito, K. Takahashi, N. Iwasawa,
    • Organizer
      The 4th International Symposium on C-H Activation
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ruthenium-catalyzed Synthesis of Acrylic Acid from Ethylene and CO22018

    • Author(s)
      T. Ito, K. Takahashi, N. Iwasawa,
    • Organizer
      The 14th International Kyoto Conference on New Aspects of Organic Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ru-Catalyzed C-H Borylation of Arylphosphines: A Powerful Tool for Modi cation of Phosphine Ligands2018

    • Author(s)
      K. Fukuda, R. Yamada, N. Iwasawa, J. Takaya,
    • Organizer
      The 14th International Kyoto Conference on New Aspects of Organic Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アクリジン含有ベンゾジアザボリン誘導体を用いたキラルアルコールの絶対立体配置の決定法2018

    • Author(s)
      志茂俊輔、高橋 講平、岩澤伸治
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ホストゲスト間のドナー・アクセプター相互作用を利用した超分子光触媒反応の開発2018

    • Author(s)
      大島真理、内倉達裕、高橋講平、岩澤伸治
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Al-Pd二核錯体を触媒とする高効率的ヒドロシリル化反応2018

    • Author(s)
      鷹谷絢、塩塚朗、斉藤成将、 岩澤伸治
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ルテニウム触媒によるアリールホスフィン類の C-H 結合ホウ素化反応2018

    • Author(s)
      福田一石、山田凌輔、岩澤伸治、鷹谷絢
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] N-ホスフィノメチル置換 NHC 配位子を有するニッケル触媒を用いたエチレンと二酸化炭素からのアクリル酸塩の効率的合成2018

    • Author(s)
      高橋講平、張錦良、岩井朝希、岩澤伸治
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ルテニウム触媒によるアリールホスフィンのオルト位C-H結合ホウ素化反応2018

    • Author(s)
      福田一石、岩澤伸治、鷹谷絢
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 四座配位子を持つルテニウム錯体を用いたエチレンと二酸化炭素からのアクリル酸合成の効率化2018

    • Author(s)
      平高遥、伊藤龍好、高橋講平、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ホスフィノメチル基の置換したNHC-ニッケル錯体を用いたエチレンと二酸化炭素からのアクリル酸塩の触媒的合成2018

    • Author(s)
      岩井朝希、張錦良、高橋講平、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電子豊富大環状ボロン酸エステルの自己組織化とその電子不足芳香族化合物の包接挙動2018

    • Author(s)
      川崎美波、福田賢也、内倉逹裕、高橋講平、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Pd/Photoredox 二元触媒系による二酸化炭素を用いたアリール及びアルケニルトリフラートの可視光駆動型カルボキシル化反応の開発2018

    • Author(s)
      中島知也、本田純、Caner Joaquim、鳥海尚之、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] α,β-不飽和カルベン錯体を活性種とする活性メチレン化合物の触媒的アリル化反応2018

    • Author(s)
      有尾茜、渡邊翔也、十河秀行、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 低原子価13族金属含有ピンサー型配位子を持つ9族金属ヒドリド錯体の合成と反応2018

    • Author(s)
      星野麻由子、植木加奈子、鷹谷絢、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 可視光エネルギーを利用した遷移金属種を用いない二酸化炭素固定化反応の開発2018

    • Author(s)
      本田純、下牧克也、鳥海尚之、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ホストゲスト間のドナー・アクセプター相互作用を利用した超分子光触媒反応の開発2018

    • Author(s)
      大島真理、内倉達裕、高橋講平、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 13族金属を配位子とするCpロジウムならびにイリジウム錯体の合成と反応2018

    • Author(s)
      山田凌輔、岩澤伸治、鷹谷絢
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高周期14族元素含有ピンサー型配位子を持つ鉄-亜鉛複核錯体の合成と反応2018

    • Author(s)
      瀧澤開、三浦律男、伊藤龍好、鷹谷絢、岩澤伸治
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Chiral Recognition of Mono-alcohols by Using 1-hydroxy-2,3,1-benzodiazaborine Having an Optical Active Cr-arene Moiety2018

    • Author(s)
      S. Shimo, K. Takahashi, N. Iwasawa
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Metal-ligand Cooperative Reaction of Alkenes and Alkynes on an Iridium Complex Bearing a Pincer-type Alkoxy Carbene Ligand2018

    • Author(s)
      K. Takahashi, N. Iwasawa
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 可視光エネルギーを利用するカルボキシル化反応2018

    • Author(s)
      岩澤伸治
    • Organizer
      日本化学会第98春季年会ATPプログラム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Ruthenium-catalyzed Synthesis of Acrylic Acid from Ethylene and CO22018

    • Author(s)
      Tatsuyoshi Ito, Kohei Takahashi, Nobuharu Iwasawa
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高周期14族元素含有ピンサー型配位子を持つ白金錯体の合成と反応2018

    • Author(s)
      中屋 良太、鷹谷 絢、岩澤 伸治
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Al-Pd二核錯体を触媒とするヒドロシリル化反応の開発2018

    • Author(s)
      塩塚 朗、斉藤 成将、鷹谷 絢、岩澤 伸治
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 内部に官能基を持つ籠型ボロキシン分子の構築とその構造変換挙動2018

    • Author(s)
      佐野 悠介、志茂 俊輔、小野 公輔、高橋 講平、岩澤 伸治
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] PGeP-ピンサー型配位子を有するレニウム錯体によるアレンのヒドロホウ素化反応2018

    • Author(s)
      村上 桃香、杉本 忠大、鷹谷 絢、岩澤 伸治
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] α,β-不飽和カルベン錯体を活性種とするエナミドのヒドロプロパルギル化反応2018

    • Author(s)
      有尾 茜、渡邊 翔也、岩澤 伸治
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ロジウム (I) 及びレドックス光増感剤を触媒として用いる可視光駆動型ヒドロカルボキシル化反応の効率化2018

    • Author(s)
      沼澤 宣次、下牧 克也、村田 慧、岩澤 伸治
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] テルロフェン部位を有する大環状ボロン酸エステルの構築とその発光挙動2017

    • Author(s)
      志茂 俊輔・落合 淳一・高橋 講平・William Delgado・Eric Rivard・岩澤 伸治
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] ペリレン骨格を有するかご型ボロン酸エステルの構築と反応場としての利用2017

    • Author(s)
      熊谷澄人・佐藤弘樹・小野公輔・高橋講平・岩澤伸治
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] ポルフィリン含有大環状ボロン酸エステルの自己組織化2017

    • Author(s)
      福田賢也・志茂俊輔・高橋講平・岩澤伸治
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] ホスフィノメチル基の置換したNHC‐ニッケル錯体を用いたエチレンと二酸化炭素からのアクリル酸の触媒的合成2017

    • Author(s)
      張錦良・山田凌輔・伊藤龍好・高橋講平・岩澤伸治
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 新規高周期13族金属-ロジウム二核錯体の合成・構造・反応性 -Al,Ga,In配位子の機能評価-2017

    • Author(s)
      植木加奈子・斉藤成将・鷹谷絢・岩澤伸治
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] α,β-不飽和カルベン錯体を活性種とする分子内ヒドロプロパルギル化反応2017

    • Author(s)
      渡邊翔也・十河秀行・岩澤伸治
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] ポリマー架橋型ビスホスフィン配位子を用いた単純芳香族化合物のC-H結合カルボキシル化反応の開発2017

    • Author(s)
      齋藤崇伸・鷹谷絢・浅野輝一・千葉成倫・岩井智弘・澤村正也・岩澤伸治
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Visible-light Driven Carboxylation Reactions2017

    • Author(s)
      Nobuharu Iwasawa
    • Organizer
      1st Singapore Japan Germany Trilateral Symposium on Precision Synthesis & Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 遷移金属錯体触媒を用いるカルボキシル化反応の開発2017

    • Author(s)
      岩澤伸治
    • Organizer
      第28回グリーンケミストリーフォーラム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] PSiP-ピンサー型パラジウム錯体を用いる有機合成反応の開発2017

    • Author(s)
      岩澤伸治
    • Organizer
      第21回ケイ素化学協会シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] α,β-不飽和カルベン錯体を活性種とするシリルエノールエーテルのヒドロプロパルギル化反応2017

    • Author(s)
      渡邊翔也、十河秀行、岩澤伸治
    • Organizer
      第111回有機合成シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis, Structure and Reactivity of Iridium Complexes Having a Gallium-Containing Pincer Type Ligand2017

    • Author(s)
      Narumasa Saito, Jun Takaya, Nobuharu Iwasawa
    • Organizer
      19th INTERNATIONAL SYMPOSIA ON ORGANOMETALLIC CHEMISTRY DIRECTED TOWARDS ORGANIC SYNTHESIS (OMCOS 19)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Visible Light-Driven Carboxylation of Aryl Halides by the Combined Use of Pd and Photoredox Catalysts2017

    • Author(s)
      Katsuya Shimomaki, Kei Murata, Nobuharu Iwasawa
    • Organizer
      19th INTERNATIONAL SYMPOSIA ON ORGANOMETALLIC CHEMISTRY DIRECTED TOWARDS ORGANIC SYNTHESIS (OMCOS 19)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Al-Metalloligand in Hydrosilylation of CO22017

    • Author(s)
      Jun Takaya, Nobuharu Iwasawa
    • Organizer
      19th INTERNATIONAL SYMPOSIA ON ORGANOMETALLIC CHEMISTRY DIRECTED TOWARDS ORGANIC SYNTHESIS (OMCOS 19)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] α,β-不飽和カルベン錯体を活性種とするシリルエノールエーテルのヒドロプロパルギル化反応2017

    • Author(s)
      渡邊 翔也、十河 秀行、岩澤 伸治
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 13族金属含有ピンサー型配位子を持つイリジウム 錯体の合成とその構造と反応性2017

    • Author(s)
      斉藤 成将、鷹谷 絢、岩澤 伸治
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] パラジウム及び光酸化還元触媒を用いるハロゲン化アリールの可視光駆動型カルボキシル化反応2017

    • Author(s)
      下牧 克也、村田 慧、マーティン ルーベン、 岩澤 伸治
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Novel reactivity of a new iridium complex bearing a pincer-type alkoxycarbene ligand with alkenes and alkynes2017

    • Author(s)
      Kohei Takahashi, Nobuharu Iwasawa
    • Organizer
      錯体化学会第67回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 二酸化炭素固定化反応における還元手法の開発2017

    • Author(s)
      岩澤伸治
    • Organizer
      日本化学会第97春季年会 特別企画
    • Place of Presentation
      横浜
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 遷移金属触媒を用いた二酸化炭素との炭素-炭素結合形成反応の開発2017

    • Author(s)
      岩澤伸治
    • Organizer
      第119回触媒討論会 特別シンポジウム
    • Place of Presentation
      東京
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] α、β-不飽和カルベン活性種の簡便な発生法とその利用2016

    • Author(s)
      岩澤伸治
    • Organizer
      第110回有機合成シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Development of Enantioselective Hydrocarboxylation Reaction Catalyzed by Si-Chiral PSiP-Pincer Type Palladium Complexes2016

    • Author(s)
      Yamada, R.; Ito, T.; Takaya, J.; Iwasawa, N.
    • Organizer
      International Symposium on C-O Activation
    • Place of Presentation
      Himeji, Japan
    • Year and Date
      2016-10-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Pyrazole as a Removable Directing Group in Rhodium-Catalyzed Direct Carboxylation of Alkenyl C-H Bond with CO22016

    • Author(s)
      Saitou, T.; Isobe, K.; Suga, T.; Takaya, J.; Iwasawa, N.
    • Organizer
      International Symposium on C-O Activation
    • Place of Presentation
      Himeji, Japan
    • Year and Date
      2016-10-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ロジウム(I)及び光酸化還元触媒を用いる可視光駆動型ヒドロカルボキシル化反応の開発2016

    • Author(s)
      村田慧、沼澤宣次、下牧克也、鷹谷絢、岩澤伸治
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] PGeP-ピンサー型配位子を持つレニウムカルボニル錯体の合成と反応2016

    • Author(s)
      杉本忠大、下牧克也、村田慧、鷹谷絢、岩澤伸治
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] エチレンと二酸化炭素からのルテナラクトン形成とその反応性2016

    • Author(s)
      伊藤龍好、高橋講平、岩澤伸治
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Integrifolinの全合成2016

    • Author(s)
      下牧克也、草間博之、岩澤伸治
    • Organizer
      第58回天然有機化合物討論会
    • Place of Presentation
      札幌
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Reductants for Hydrocarboxylation Reactions2016

    • Author(s)
      Nobuharu Iwasawa
    • Organizer
      9th Asian-European Symposium on Metal-Mediated Efficient Organic Synthesis
    • Place of Presentation
      Stockholm, Sweden
    • Year and Date
      2016-09-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 新しい反応活性種創製法の開発2016

    • Author(s)
      岩澤伸治
    • Organizer
      有機金属の大潮流
    • Place of Presentation
      岡崎
    • Year and Date
      2016-09-02
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 籠型ボロキシン分子の構 築とそのルイス塩基との錯形成 に基づく動的構造変換2016

    • Author(s)
      志茂俊輔・小野公輔・高橋 講平・岩澤伸治
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島
    • Year and Date
      2016-09-01
    • Related Report
      2016 Annual Research Report
  • [Presentation] Electrophilic Activation of Aromatic Guest Molecules Utilizing a Macrocyclic Boronic Ester Containing Difluorobenzothiadiazole Moiety2016

    • Author(s)
      Uchikura, T.; Ono, K.; Takahashi, K.; Iwasawa, N.
    • Organizer
      20th International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Cobalt-Salophen Complex Catalyzed Preparation of Alkyl Iodides from Aldehydes via Oxidative Formylation2016

    • Author(s)
      Sumiyama, K.; Kaiho, A.; Sogo, H.; Kusama, H.; Iwasawa, N.
    • Organizer
      20th International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] コバルトサレン錯体を用いたアルデヒドの脱ホルミルを伴うヨウ化アルキルの合成2016

    • Author(s)
      住山恵一、十河秀行、海寶篤志、草間博之、岩澤伸治
    • Organizer
      第109回有機合成シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2016-06-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] ピラゾールを除去可能な配向性官能基として利用するアルケン類の炭素-水素結合カルボキシル化反応の開発2016

    • Author(s)
      齋藤崇伸、磯部孝太郎、菅拓也、鷹谷絢、岩澤伸治
    • Organizer
      第109回有機合成シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2016-06-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] Si-キラル PSiP-ピンサー型パラジウム錯体を触媒とするエナンチオ選択的ヒドロカルボキシル化反応の開発2016

    • Author(s)
      山田凌輔、伊藤龍好、鷹谷絢、岩澤伸治
    • Organizer
      第109回有機合成シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2016-06-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] ジフルオロベンゾチアジアゾール部位を有する大環状ボロン酸エステルを用いた芳香族ゲスト分子の求電子的活性化2016

    • Author(s)
      内倉達裕、小野公輔、高橋講平、岩澤伸治
    • Organizer
      第14回ホストゲスト化学シンポジウム
    • Place of Presentation
      高知
    • Year and Date
      2016-06-04
    • Related Report
      2016 Annual Research Report
  • [Presentation] 籠形ボロキシン分子の構築とそのルイス塩基との錯形成に基づく動的構造変換2016

    • Author(s)
      志茂俊輔、小野公輔、高橋講平、岩澤伸治
    • Organizer
      第14回ホストゲスト化学シンポジウム
    • Place of Presentation
      高知
    • Year and Date
      2016-06-04
    • Related Report
      2016 Annual Research Report
  • [Presentation] CO2を用いる炭素-水素結合の直接カルボキシル化反応2016

    • Author(s)
      岩澤伸治
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 高周期14族元素含有ピンサー型配位子をもつ6族金属錯体の合成と反応2016

    • Author(s)
      永松麻由子、三浦律男、鷹谷絢、岩澤伸治
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Si-キラルPSiP-ピンサー型パラジウム錯体を触媒とするエナンチオ選択的ヒドロカルボキシル化反応の開発2016

    • Author(s)
      山田凌輔、伊藤龍好、鷹谷絢、岩澤伸治
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] PGeP-ピンサー型配位子を持つ7族金属カルボニル錯体の可逆な光幾何異性化反応2016

    • Author(s)
      杉本忠大、下牧克也、村田慧、鷹谷絢、岩澤伸治
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Total Synthesis of Integrifolin2016

    • Author(s)
      SHIMOMAKI, Katsuya; KUSAMA, Hiroyuki; IWASAWA, Nobuharu
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis, Structure, and Reactivity of Gallium-Iridium Heterobimetallic Complexes Utilizing an N,P-Multidentate Ligand2016

    • Author(s)
      SAITO, Narumasa; TAKAYA, Jun; IWASAWA, Nobuharu
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Electrophilic Activation of Aromatic Guest Molecules Utilizing a Macrocyclic Boronic Ester Containing Difluorobenzothiadiazole Moiety2016

    • Author(s)
      UCHIKURA, Tatsuhiro; ONO, Kosuke; TAKAHASHI, Kohei; IWASAWA, Nobuharu
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] クラウンエーテル部位を有する大環状ボロン酸エステルの合成とそのDiels-Alder反応加速効果2016

    • Author(s)
      中所亮輔、高橋講平、小野公輔、岩澤伸治
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] PSiN-ピンサー型金属錯体を触媒として用いるアレーンまたはアルケン類のホウ素化反応の開発2016

    • Author(s)
      伊藤志成、鷹谷絢、岩澤伸治
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 籠型ボロキシン分子の構築とそのルイス塩基との錯形成に基づく動的構造変換2016

    • Author(s)
      志茂俊輔、小野公輔、高橋講平、岩澤伸治
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 遷移金属触媒を用いるカルボキシル化反応の開発2016

    • Author(s)
      岩澤伸治
    • Organizer
      有機合成化学ミニシンポジウム
    • Place of Presentation
      千葉
    • Related Report
      2016 Annual Research Report
    • Invited

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Published: 2015-07-02   Modified: 2022-11-04  

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