| Budget Amount *help |
¥115,830,000 (Direct Cost: ¥89,100,000、Indirect Cost: ¥26,730,000)
Fiscal Year 2019: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2018: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2017: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2016: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2015: ¥52,910,000 (Direct Cost: ¥40,700,000、Indirect Cost: ¥12,210,000)
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| Outline of Final Research Achievements |
By using 6,6 ”-bisphosphinoterpyridine ligands, we have successfully realized a general method for the synthesis of hetero-dinuclear metal complexes containing metal-metal bonds by sequentially introducing two different metals to the scaffold. In addition, we were able to accumulate a lot of knowledge about the structure and bonding of these complexes based on single crystal X-ray structure analysis and theoretical methods. Furthermore, by utilizing the characteristic properties of the prepared complexes, we have developed a highly efficient hydrosilylation of carbon dioxide and a selective reduction of aromatic nitriles. In the former reaction, the highest turnover frequency was achieved.
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