| Budget Amount *help |
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2020: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2019: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2018: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
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| Outline of Final Research Achievements |
In this research project, we developed basic chiral theories describing asymmetry in complex systems and conducted basic researches on "coordination asymmetry" based on theoretical and computational chemistry. Specifically, research was conducted on the following several research topics; (1) Development of basic theories of chirality for complex systems and theoretical design of amplification of chiroptical properties, (2) Reaction mechanism of specific catalytic reactions in metal-macrocyclic framework, (3) Heat-resistant properties of phosphorescence and aggregation-induced luminescence of platinum complexes, (4) Structures, electronic structures, and chiroptical properties of silver nanoclusters. These studies were promoted mainly in collaboration with experimental researchers and aimed at conducting theoretical analysis and molecular design of various chemical events related to molecular asymmetry.
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