| Budget Amount *help |
¥38,610,000 (Direct Cost: ¥29,700,000、Indirect Cost: ¥8,910,000)
Fiscal Year 2020: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2019: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2018: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2017: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2016: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
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| Outline of Final Research Achievements |
This study has developed the synthesis, structures, and chemical properties of transition-metal polynuclear compounds under unsymmetrical environments. The successful research developments include pressure-induced molecular distortion and solid-state luminescence piezochromism of copper(I), silver(I), and gold(I) clusters, the fabrication of luminescent vapochromic crystals that adsorb volatile organic compounds (VOCs), the isolation of tetra- and hexanuclear copper(I) clusters with benzimidazole-thiol chelates and the solid-state dual emission in the visible-to-near infrared wavelength region, and the preparation of polymorphs of hydrogen-bonded honeycomb networks based on isonicotineamide (ina)-triruthenium(III) cluster compounds.
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