| Budget Amount *help |
¥38,610,000 (Direct Cost: ¥29,700,000、Indirect Cost: ¥8,910,000)
Fiscal Year 2020: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2019: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2018: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2017: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2016: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
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| Outline of Final Research Achievements |
In this study, we constructed a variety of three-dimensional metal structures with planar chirality by combining various phosphorescent transition metal platforms with organic linkers, and investigated relationship between their molecular mobility and assembly-chirality ability, and luminescence properties, to develop highly functional luminescent materials.
First, we selected hetero-atom coordination platinum complexes with flexible coordination planes, which have potential luminescence but are non-luminescent in solution state at room temperature, and constructed novel luminescent materials with various planar chirality having unique three-dimensional structures such as wavelike, washcloth, and tongue.Then, we developed the chiral assembly and accumulation method of them, and clarified the relationship between molecular assembly state and chiral optical properties.
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