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Control of Chirality Functions at Dynamic Interfaces

Planned Research

Project AreaCoordination Asymmetry: Design of Asymmetric Coordination Sphere and Anisotropic Assembly for the Creation of Functional Molecules
Project/Area Number 16H06518
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionNational Institute for Materials Science

Principal Investigator

ARIGA Katsuhiko  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA主任研究者 (50193082)

Project Period (FY) 2016-06-30 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥47,190,000 (Direct Cost: ¥36,300,000、Indirect Cost: ¥10,890,000)
Fiscal Year 2020: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Fiscal Year 2019: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Fiscal Year 2018: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Fiscal Year 2017: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Fiscal Year 2016: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Keywords超分子化学 / 表面・界面物性 / ナノ材料
Outline of Final Research Achievements

The aim of this project was to develop interface technologies to control the asymmetry function of molecular machines, etc. Using interface technologies such as the LB method, we explored the asymmetry function of two-dimensional supramolecular nano-assemblies and the functional molecules such as molecular machines. For example, control of the fluorescent behaviors of metal-complex-type molecular machines upon changing their orientation structure at the air-water interface was demonstrated. In addition to demonstrating the initial goal, we have achieved results far beyond our expectations, such as the control of stem cell differentiation by developing interface control technology.

Academic Significance and Societal Importance of the Research Achievements

特別な分子に対して特別な刺激にのみ反応するのではなく、分子を自分の手で自由に動かすことができるような誰でもどこでも制御しうる動作体系を確立する道筋を作ることができた。また、予期せぬ成果として、今回開発した技術では、分化因子を用いずに幹細胞の自発分化を誘導できた。これは効率的かつ安価な分化誘導技術として大きな可能性を秘めており、材料を基軸とする再生医療技術として社会的インパクトのある研究に発展することが期待される。

Report

(6 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (33 results)

All 2020 2019 2018 2017 2016

All Journal Article (33 results) (of which Int'l Joint Research: 16 results,  Peer Reviewed: 33 results,  Open Access: 8 results,  Acknowledgement Compliant: 4 results)

  • [Journal Article] Nanoarchitectonics beyond Self‐Assembly: Challenges to Create Bio‐Like Hierarchic Organization2020

    • Author(s)
      Ariga Katsuhiko、Jia Xiaofang、Song Jingwen、Hill Jonathan P.、Leong David Tai、Jia Yi、Li Junbai
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 59 Issue: 36 Pages: 15424-15446

    • DOI

      10.1002/anie.202000802

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Supramolecular Chiral Nanoarchitectonics2020

    • Author(s)
      Katsuhiko Ariga, Taizo Mori, Takashi Kitao, Takashi Uemura
    • Journal Title

      Adv. Mater.

      Volume: 32 Issue: 41 Pages: 1905657-1905657

    • DOI

      10.1002/adma.201905657

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The evolution of molecular machines through interfacial nanoarchitectonics: from toys to tools2020

    • Author(s)
      Ariga Katsuhiko
    • Journal Title

      Chemical Science

      Volume: 11 Issue: 39 Pages: 10594-10604

    • DOI

      10.1039/d0sc03164j

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Helicity Manipulation of a Double-Paddled Binaphthyl in a Two-Dimensional Matrix Field at the Air-Water Interface2020

    • Author(s)
      Ishii Masaki、Mori Taizo、Nakanishi Waka、Hill Jonathan P.、Sakai Hideki、Ariga Katsuhiko
    • Journal Title

      ACS Nano

      Volume: 14 Issue: 10 Pages: 13294-13303

    • DOI

      10.1021/acsnano.0c05093

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Large-Area Aligned Fullerene Nanocrystal Scaffolds as Culture Substrates for Enhancing Mesenchymal Stem Cell Self-Renewal and Multipotency2020

    • Author(s)
      Song Jingwen、Jia Xiaofang、Minami Kosuke、Hill Jonathan P.、Nakanishi Jun、Shrestha Lok Kumar、Ariga Katsuhiko
    • Journal Title

      ACS Applied Nano Materials

      Volume: 3 Issue: 7 Pages: 6497-6506

    • DOI

      10.1021/acsanm.0c00973

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Emission Control by Molecular Manipulation of Double‐Paddled Binuclear Pt II Complexes at the Air‐Water Interface2020

    • Author(s)
      Adachi Junya、Mori Taizo、Inoue Ryo、Naito Masaya、Le Ngoc Ha‐Thu、Kawamorita Soichiro、Hill Jonathan P.、Naota Takeshi、Ariga Katsuhiko
    • Journal Title

      Chemistry-An Asian Journal

      Volume: 15 Issue: 3 Pages: 406-414

    • DOI

      10.1002/asia.201901691

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multimodal Switching of a Redox-active Macrocycle2019

    • Author(s)
      Daniel T. Payne, Whitney A. Webre, Yoshitaka Matsushita, Nianyong Zhu, Zdenek Futera, Jan Labuta, Wipakorn Jevasuwan, Naoki Fukata, John S. Fossey, Francis D’Souza, Katsuhiko Ariga, Wolfgang Schmitt, Jonathan P. Hill
    • Journal Title

      Nature Communications

      Volume: 10 Issue: 1 Pages: 1007-1007

    • DOI

      10.1038/s41467-019-08978-5

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Amphiprotism-Coupled Near-Infrared Emission in Extended Pyrazinacenes Containing Seven Linearly Fused Pyrazine Units2019

    • Author(s)
      Richards Gary J.、Cador Ael、Yamada Shinji、Middleton Anna、Webre Whitney A.、Labuta Jan、Karr Paul A.、Ariga Katsuhiko、D’Souza Francis、Kahlal Samia、Halet Jean-Francois、Hill Jonathan P.
    • Journal Title

      Journal of the American Chemical Society

      Volume: 141 Issue: 50 Pages: 19570-19574

    • DOI

      10.1021/jacs.9b10952

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adaptive Liquid Interfacially Assembled Protein Nanosheets for Guiding Mesenchymal Stem Cell Fate2019

    • Author(s)
      Jia Xiaofang、Minami Kosuke、Uto Koichiro、Chang Alice Chinghsuan、Hill Jonathan P.、Nakanishi Jun、Ariga Katsuhiko
    • Journal Title

      Advanced Materials

      Volume: 32 Issue: 4 Pages: 1905942-1905942

    • DOI

      10.1002/adma.201905942

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mesoporous fullerene C70 cubes with highly crystalline frameworks and unusually enhanced photoluminescence properties2018

    • Author(s)
      Bairi Partha、Tsuruoka Tohru、Acharya Somobrata、Ji Qingmin、Hill Jonathan P.、Ariga Katsuhiko、Yamauchi Yusuke、Shrestha Lok Kumar
    • Journal Title

      Materials Horizons

      Volume: 5 Issue: 2 Pages: 285-290

    • DOI

      10.1039/c7mh00954b

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Junction-Controlled Topological Polymerization2018

    • Author(s)
      Li Mao、Kang Shusen、Du Jia、Zhang Jian、Wang Jinxin、Ariga Katsuhiko
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 57 Issue: 18 Pages: 4936-4939

    • DOI

      10.1002/anie.201713026

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Carbon Nanosheets by Morphology-Retained Carbonization of Two-Dimensional Assembled Anisotropic Carbon Nanorings2018

    • Author(s)
      Mori Taizo、Tanaka Hiroyuki、Dalui Amit、Mitoma Nobuhiko、Suzuki Kengo、Matsumoto Mutsuyoshi、Aggarwal Nikhil、Patnaik Archita、Acharya Somobrata、Shrestha Lok Kumar、Sakamoto Hirotoshi、Itami Kenichiro、Ariga Katsuhiko
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 57 Issue: 31 Pages: 9679-9683

    • DOI

      10.1002/anie.201803859

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Coordination Polymer Nanoglue: Robust Adhesion Based on Collective Lamellar Stacking of Nanoplates2017

    • Author(s)
      Zhao Yanyi、Li Wenwu、Jiang Xiangfen、Li Fengqiong、Li Xin、Zhang Wei、Jiang Ji-Sen、Liu Jian、Ariga Katsuhiko、Hu Ming
    • Journal Title

      ACS Nano

      Volume: 11 Issue: 4 Pages: 3662-3670

    • DOI

      10.1021/acsnano.6b08068

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Mechanically Induced Opening-Closing Action of Binaphthyl Molecular Pliers: Digital Phase Transition vs. Continuous Conformational Change2017

    • Author(s)
      T. Mori, D. Ishikawa, Y. Yonamine, Y. Fujii, J. P. Hill, I. Ichinose, K. Ariga, W. Nakanishi
    • Journal Title

      ChemPhysChem

      Volume: 印刷中 Issue: 11 Pages: 1470-1474

    • DOI

      10.1002/cphc.201601144

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanoarchitectonics: a navigator from materials to life2017

    • Author(s)
      Ariga Katsuhiko
    • Journal Title

      Mater. Chem. Front.

      Volume: 1 Issue: 2 Pages: 208-211

    • DOI

      10.1039/c6qm00240d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Intentional Closing/Opening of “Hole-in-Cube” Fullerene Crystals with Microscopic Recognition Properties2017

    • Author(s)
      Bairi Partha、Minami Kosuke、Hill Jonathan P.、Ariga Katsuhiko、Shrestha Lok Kumar
    • Journal Title

      ACS Nano

      Volume: 11 Issue: 8 Pages: 7790-7796

    • DOI

      10.1021/acsnano.7b01569

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective CO2 Capture and High Proton Conductivity of a Functional Star-of-David Catenane Metal-Organic Framework2017

    • Author(s)
      Huang You-Gui、Wu Shu-Qi、Deng Wei-Hua、Xu Gang、Hu Fa-Lu、Hill Jonathan P.、Wei Wei、Su Sheng-Qun、Shrestha Lok Kumar、Sato Osamu、Wu Ming-Yan、Hong Mao-Chun、Ariga Katsuhiko
    • Journal Title

      Advanced Materials

      Volume: 29 Issue: 42 Pages: 1703301-1703301

    • DOI

      10.1002/adma.201703301

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Conformation Manipulation and Motion of a Double Paddle Molecule on an Au(111) Surface2017

    • Author(s)
      Soe We-Hyo、Shirai Yasuhiro、Durand Corentin、Yonamine Yusuke、Minami Kosuke、Bouju Xavier、Kolmer Marek、Ariga Katsuhiko、Joachim Christian、Nakanishi Waka
    • Journal Title

      ACS Nano

      Volume: 11 Issue: 10 Pages: 10357-10365

    • DOI

      10.1021/acsnano.7b05314

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Facile synthesis of tellurium nanowires and study of their third-order nonlinear optical properties2017

    • Author(s)
      Robson R. Silva; Hans A. G. Mejia; Sidney J. L. Ribeiro; Lok K. Shrestha; Katsuhiko Ariga; Osvaldo N. Oliveira Jr.; Vanessa R. Camargo; Lauro J. Q. Maiae; Cid B. Araujo
    • Journal Title

      J. Braz. Chem. Soc.

      Volume: 28 Pages: 58-67

    • DOI

      10.5935/0103-5053.20160145

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Fluorescent mesomorphic pyrazinacenes2016

    • Author(s)
      Gary J. Richards; Shinsuke Ishihara; Jan Labuta; David Miklik; Toshiyuki Mori; Shinji Yamada; Katsuhiko Ariga; Jonathan P. Hill
    • Journal Title

      J. Mater. Chem. C

      Volume: 4 Issue: 48 Pages: 11514-11523

    • DOI

      10.1039/c6tc04628b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] From Chromonic Self-Assembly to Hollow Carbon Nanofibers for Efficient Materials in Supercapacitor and Vapor Sensing Applications2016

    • Author(s)
      J. Rodrigo Magana; Yury V. Kolen'ko; Francis Leonard Deepak; Conxita Solans; Rekha Goswami Shrestha; Jonathan P. Hill; Katsuhiko Ariga; Lok Kumar Shrestha; Carlos Rodriguez-Abreu
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 8 Issue: 45 Pages: 31231-31238

    • DOI

      10.1021/acsami.6b09819

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Thermally Induced Intra-Carboxyl Proton Shuttle in a Molecular Rack-and-Pinion Cascade Achieving Macroscopic Crystal Deformation2016

    • Author(s)
      You-Gui Huang, Yoshihito Shiota, Sheng-Qun Su, Shu-Qi Wu, Zi-Shuo Yao, Guo-Ling Li, Shinji Kanegawa, Soonchul Kang, Takashi Kamachi, Kazunari Yoshizawa, Katsuhiko Ariga, Osamu Sato
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 47 Pages: 14628-14632

    • DOI

      10.1002/anie.201607886

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Dependence of intestinal absorption profile of insulin on carrier morphology composed of β-cyclodextrin-grafted chitosan2016

    • Author(s)
      Yuki Daimon; Noriyasu Kamei; Kohsaku Kawakami; Mariko Takeda-Morishita; Hironori Izawa; Yuki Takechi-Haraya; Hiroyuki Saito; Hideki Sakai; Masahiko Abe; Katsuhiko Ariga
    • Journal Title

      Mol. Pharmaceutics

      Volume: 13 Issue: 12 Pages: 4034-4042

    • DOI

      10.1021/acs.molpharmaceut.6b00561

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechano-Nanoarchitectonics for Bio-Functions at Interfaces2016

    • Author(s)
      Katsuhiko Ariga
    • Journal Title

      Analytical Sciences

      Volume: 32 Issue: 11 Pages: 1141-1149

    • DOI

      10.2116/analsci.32.1141

    • NAID

      130005278018

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Supramolecular Differentiation for Constructing Anisotropic Fullerene Nanostructures by Time-Programmed Control of Interfacial Growth2016

    • Author(s)
      P. Bairi, K. Minami, J. P. Hill, W. Nakanishi, L. K. Shrestha, C. Liu, K. Harano, E. Nakamura, K. Ariga
    • Journal Title

      ACS Nano

      Volume: 10 Issue: 9 Pages: 8796-8802

    • DOI

      10.1021/acsnano.6b04535

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemically Organized Isolated Fullerene-Rich Thin Films with Optical Limiting Properties2016

    • Author(s)
      Shusen Kang; Jian Zhang; Liwen Sang; Lok Kumar Shrestha; Zhe Zhang; Ping Lu; Feng Li; Mao Li; Katsuhiko Ariga
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 8 Issue: 37 Pages: 24295-24299

    • DOI

      10.1021/acsami.6b06221

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nanoarchitectonics2016

    • Author(s)
      Katsuhiko Ariga; Masakazu Aono
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 55 Issue: 11 Pages: 1102A6-1102A6

    • DOI

      10.7567/jjap.55.1102a6

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Driving nanocars and nanomachines at interfaces: From concept of nanoarchitectonics to actual use in world wide race and hand operation2016

    • Author(s)
      Yasuhiro Shirai; Kosuke Minami; Waka Nakanishi; Yusuke Yonamine; Christian Joachim; Katsuhiko Ariga
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 55 Issue: 11 Pages: 1102A2-1102A2

    • DOI

      10.7567/jjap.55.1102a2

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Antibacterial Effect of Silver-Incorporated Flake-Shell Nanoparticles under Dual-Modality2016

    • Author(s)
      Qin Tang; Jia Liu; Lok Kumar Shrestha; Katsuhiko Ariga; Qingmin Ji
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 8 Issue: 29 Pages: 18922-18929

    • DOI

      10.1021/acsami.6b02507

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Cavitation and radicals drive the sonochemical synthesis of functional polymer spheres2016

    • Author(s)
      Badri Narayanan; Sanket A. Deshmukh; Lok Kumar Shrestha; Katsuhiko Ariga; Vilas G. Pol; Subramanian K. R. S. Sankaranarayanan
    • Journal Title

      Appl. Phys. Lett.

      Volume: 109 Issue: 4 Pages: 041901-041901

    • DOI

      10.1063/1.4959885

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] An Artificial Reaction Promoter Modulates Mitochondrial Functions via Chemically Promoting Protein Acetylation2016

    • Author(s)
      Yutaka Shindo; Hirokazu Komatsu; Kohji Hotta; Katsuhiko Ariga; Kotaro Oka
    • Journal Title

      Sci. Rep.

      Volume: 6 Issue: 1 Pages: 29224-29224

    • DOI

      10.1038/srep29224

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Nanoporous carbon materials with enhanced supercapacitance performance and non-aromatic chemical sensing with C1/C2 alcohol discrimination2016

    • Author(s)
      Lok Kumar Shrestha; Laxmi Adhikari; Rekha Goswami Shrestha; Mandira Pradhananga Adhikari; Rina Adhikari; Jonathan P. Hill; Raja Ram Pradhananga; Katsuhiko Ariga
    • Journal Title

      Sci. Technol. Adv. Mater.

      Volume: 17 Issue: 1 Pages: 483-492

    • DOI

      10.1080/14686996.2016.1219971

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Mesoporous Graphitic Carbon Microtubes Derived from Fullerene C70 Tubes as a High Performance Electrode Material for Advanced Supercapacitors2016

    • Author(s)
      Partha Bairi; Rekha Goswami Shrestha; Jonathan P. Hill; Toshiyuki Nishimura; Katsuhiko Ariga; Lok Kumar Shrestha
    • Journal Title

      J. Mater. Chem. A

      Volume: 4 Issue: 36 Pages: 13899-13906

    • DOI

      10.1039/c6ta04970b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed

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Published: 2016-07-04   Modified: 2022-01-27  

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