| Budget Amount *help |
¥54,990,000 (Direct Cost: ¥42,300,000、Indirect Cost: ¥12,690,000)
Fiscal Year 2021: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2020: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2019: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
Fiscal Year 2018: ¥21,450,000 (Direct Cost: ¥16,500,000、Indirect Cost: ¥4,950,000)
Fiscal Year 2017: ¥15,990,000 (Direct Cost: ¥12,300,000、Indirect Cost: ¥3,690,000)
|
|---|
| Outline of Final Research Achievements |
We have succeeded in synthesizing sequence-controlled polymers composed of commodity repeating monomer units, such as (meth)acrylate, acrylamide, styrene, via (co)polymerization of special monomers (bulky monomers or divinyl monomers) carrying transformable bonds in the pendant. The monomer design allows the alternating propagation as well as the one-pot transformation, leading to syntheses of a series of sequence-controlled polymers with various side-chain substituents from one polymerization. Consequently, we have clarified the great impacts of sequence on physical properties, such as glass transition temperature, thermoresponsiveness, and liquid crystalline behavior, through comparison with non-sequence-controlled polymers having the same composition ratio.
|
