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Integrated syntheses of novel dynamic redox systems exhibiting assembled multiple functions

Planned Research

Project AreaOrganic Synthesis based on Integration of Chemical Reactions. New Methodologies and New Materials
Project/Area Number 21106012
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionHokkaido University

Principal Investigator

SUZUKI TAKANORI  北海道大学, 理学(系)研究科(研究院), 教授 (70202132)

Project Period (FY) 2009-07-23 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥33,150,000 (Direct Cost: ¥25,500,000、Indirect Cost: ¥7,650,000)
Fiscal Year 2013: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2012: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2011: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2010: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2009: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Keywords集積合成 / 酸化還元系 / 応答性分子 / エレクトロクロミズム / クロミズム応答 / 酸化還元 / フロー合成 / 空間的集積 / 応答性 / 外部刺激制御 / 次元性
Research Abstract

Electrochromism is a representative function of organic redox systems, by which electrochemical input is reversibly transduced into UV-Vis spectral output. Based on our previous studies on "dynamic redox (dyrex)" systems that undergo reversible C-C bond-formation/-cleavage upon electron transfer, we envisaged that the assembled multiple functions would be endowed under the novel molecular design, and such materials could be prepared exclusively only by using newly developed synthetic methods based on integrated reactions. This work can be divided into two parts: [1] studies on NOVEL MATERIALS exhibiting dynamic redox behavior prepared by integrated reactions; and [2] characterization and exploration of organic redox systems newly prepared by NOVEL INTEGRATED REACTIONS. Most of the research results have been published.

Report

(6 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (82 results)

All 2014 2013 2012 2011 2010 2009

All Journal Article (72 results) (of which Peer Reviewed: 72 results,  Open Access: 1 results) Presentation (10 results) (of which Invited: 9 results)

  • [Journal Article] Expandability of Ultralong C-C Bond: Largely Different C1-C2 Bond Length Determined by Low-temperature X-ray Analyses on Pseudopolymorphs of 1,1-Bis(4-fluorophenyl)-2,2-bis(4-methoxyphe nyl)pyracene2014

    • Author(s)
      Suzuki, T.; Uchimura, Y.; Nagasawa, F.; Takeda, T.; Kawai, H.; Katoono, R.; Fujiwara, K.; Murakoshi, K.; Fukushima, T.; Nagaki, A.;Yoshida
    • Journal Title

      J. Chem. Lett

      Volume: 43(1) Pages: 85-88

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Memory Units Based on Dynamic Redox Systems with a Dibenzoxepinone Skeleton: Drastic Change in Racemization Barrier and Electrochemical Bistability2014

    • Author(s)
      Wada, K.; Chiba, Y.; Takeda, T.; Kawai, H.; Katoono, R.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Heterocycles

      Volume: 88(2) Pages: 945-952

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Cyanoazulene-based Muti-stage Redox Systems Prepared from Vinylcyclopropanecarbonitrile and Cyclopentenone via Divinylcyclopropane-rearrangement Approach2014

    • Author(s)
      Tanino, K.; Yamada, Y.; Yoshimura, F.; Suzuki, T
    • Journal Title

      Chem. Lett

      Volume: 43(5) Pages: 607-609

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochromic and unique chiroptical properties of helically deformed tetraarylquinodimethanes generated from less hindered dicationic precursors upon reduction2014

    • Author(s)
      Suzuki, T.; Sakano, Y.; Iwai, T.; Iwashita, S.; Miura, Y.; Katoono, R.; Kawai, H.; Fujiwara, K.; Tsuji, Y.; Fukushima, T
    • Journal Title

      Pure Appl. Chem

      Volume: (in press) Issue: 4 Pages: 507-516

    • DOI

      10.1515/pac-2013-1003

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Complexation-induced inversion of helicity by an organic guest in a dynamic molecular propeller based on a tristerephtalamide host with a two-layer structure2014

    • Author(s)
      Katoono, R.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Chem. Commun

      Volume: 50(41) Pages: 5438-5440

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and structure of acenaphthylene-1,2-diyldi(9-acridine) derivatives with a long C=C bond2014

    • Author(s)
      Takeda, T.; Uchimura, Y.; Kawai, H.; Katoono, R.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Chem. Commun

      Volume: 50(30) Pages: 3924-3927

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochiroptical Response in Aqueous Media: 9.10-Dihydrophenanthrene-9,10-diyl Dications with Michlar's Hydrol Blue Chromophores Attached with Oligoethylene Glycol Units2014

    • Author(s)
      Suzuki, T..; Hanada, K.; Katoono, R.; Ishigaki, Y.; Higasa, S.; Higuchi, H.; Kikuchi, H.; Fujiwara, K.; Yamada, H.; T. Fukushima
    • Journal Title

      Chem. Lett

      Volume: (in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oxidative Protonolysis of the Expanded Central C-C Bond in a Di(spiroacridan)-type Hexaphenylethane Derivative Accompanied by UV-vis, FL, and CD Spectral Changes2014

    • Author(s)
      Suzuki, T.; Kuroda, Y.; Wada, K.; Sakano, Y.; Katoono, R.; Fujiwara, K.; Kakiuchi, F.; Fukushima, T
    • Journal Title

      Chem. Lett

      Volume: (in press) Issue: 6 Pages: 887-889

    • DOI

      10.1246/cl.140192

    • NAID

      130004868213

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Wurster's Blue-type Cation Radicals Framed in a 5,10-Dihydrobenzo[a]indolo[2,3-c]carbazole (BIC) Skeleton: Dual Electrochromism with Drastic Changes in UV-Vis-NIR and Fluorescence2014

    • Author(s)
      Suzuki, T.; Sakano, Y.; Tokimizu, Y; Miura, Y;. Katoono, R.; Fujiwara, K.; Yoshioka, N.; Fujii, N.; Ohno, H
    • Journal Title

      Chem. Asian J

      Volume: (in press)

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, Redox Properties, and perties, and X-ray Strucures of Electrochromic 11,11,12,12- Tetraarylanthraquinodimethane and Its Bianthraquinodimethane Analogue: Drastic Geometrical Changes upon Interconversion with the Dicationic Dyes2014

    • Author(s)
      Sakano, Y.; Katoono, R.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Chem. Lett

      Volume: (in press) Issue: 7 Pages: 1143-1145

    • DOI

      10.1246/cl.140393

    • NAID

      130004868285

    • Related Report
      2013 Final Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Chiral Memory Units Based on Dynamic Redox Systems with a Dibenzoepinone Skeleton2014

    • Author(s)
      K. Wada, Y. Chiba, T. Takeda, H. Kawai, R. Katoono, K. Fujiwara, T. Suzuki
    • Journal Title

      Heterocycles

      Volume: 88(2) Pages: 945-952

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Expandability of Ultralong C-C Bond: Largely Different C1-C2 Bond Length Determined by Low-temperature X-ray Analyses on Pseudopolymorphs of 1,1-Bis(4-fluorophenyl)-2,2-bis(4-methoxyphenyl)pyracene,2014

    • Author(s)
      T. Suzuki, Y. Uchimura, F. Nagasawa, T. Takeda, H. Kawai, R. Katoono, K. Fujiwara, K. Murakoshi, T. Fukushima, A. Nagaki, J. Yoshida,
    • Journal Title

      Chem. Lett.

      Volume: 43(1), Pages: 85-88

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cyanoazulene-based Muti-stage Redox Systems Prepared from Vinylcyclopropanecarbonitrile and Cyclopentenone via Divinylcyclopropane-rearrangement Approach,2014

    • Author(s)
      K. Tanino, Y. Yamada, F. Yoshimura, T. Suzuki,
    • Journal Title

      Chem. Lett.

      Volume: 43(5) Pages: 607-608

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and structure of acenaphthylene-1,2-diyldi(9-acridine) derivatives with a long C=C bond,2014

    • Author(s)
      T. Takeda, Y. Uchimura, H. Kawai, R. Katoono, K. Fujiwara, T. Suzuki,
    • Journal Title

      Chem. Commun

      Volume: 50 Pages: 3924-3927

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Complexation-induced inversion of helicity by an organic guest in a dynamic molecular propeller based on a tristerephtalamide host with a two-layer structure2014

    • Author(s)
      R. Katoono, K. Fujiwara, T. Suzuki
    • Journal Title

      Chem. Commun.

      Volume: 50 Issue: 41 Pages: 5438-5440

    • DOI

      10.1039/c4cc00323c

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochiroptical Response in Aqueous Media: 9.10-Dihydrophenanthrene-9,10-diyl Dications with Michlar's Hydrol Blue Chromophores Attached with Oligoethylene Glycol Units,2014

    • Author(s)
      T. Suzuki, K. Hanada, R. Katoono, Y. Ishigaki, S. Higasa, H. Higuchi, H. Kikuchi, K. Fujiwara, H. Yamada, T. Fukushima,
    • Journal Title

      Chem. Lett.

      Volume: 印刷中 Issue: 7 Pages: 982-984

    • DOI

      10.1246/cl.140163

    • NAID

      130004868230

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 7,7,8,8-Tetraaryl-o-quinodimethane Stabilized by Dibenzo-annulation: A Helical pi-Electron System that Exhibits Electrochromic and Unique Chiroptical Properties2013

    • Author(s)
      Suzuki, T.; Sakano, Y.; Iwai, T.; Iwashita, S.; Miura, Y.; Katoono, R.; Kawai, Fujiwara, K.; Tsuji, Y.; Fukushima, T
    • Journal Title

      Chem. Eur. J

      Volume: 19(1) Pages: 117-123

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hexaphenylethanes with an Ultralong C-C Bond: Expandability of the C-C Bond in Highly Strained Tetraarylopyracenes2013

    • Author(s)
      Takada, T.; Uchimura, Y.; Kawai, H.; Katoono, R.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Chem. Lett

      Volume: 42(9) Pages: 954-962

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Geometrical Remote Steric Effects in 4,5-Disubsitituted-9,10- dihydrophenanthrenes: Expansion of Prestrained C9-C10 Bond in Di(spiroacridan) Derivatives2013

    • Author(s)
      Wada, K.; Takeda, T.; Kawai, H.; Katoono, R.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Chem. Lett

      Volume: 42(10) Pages: 1194-1196

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Time-integrated one-pot synthesis, X-ray structure, and redox properties of electrochromic 1,3-diarylisobenzofurans2013

    • Author(s)
      Hamura, T.; Nakayama, R.; Hanada, K.; Sakano, Y.; Katoono, R.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Chem. Lett

      Volume: 42(10) Pages: 1244-1246

    • NAID

      10031201325

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] C3-symmetric chrioptical molecular propeller based on hexakis(phenylethynyl)benzene with a threefold terephthalamide: stereospecific propeller generation through the cooperative transmission of point chiralities on the host and guest upon complexation2013

    • Author(s)
      Katoono, R.; Kawai, H.; Ohkita, M.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Chem. Commun

      Volume: 49(88) Pages: 10352-10354

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, properties, and X-ray structures of bis(10-methyl-9-methyleneacridan)-type electron donors with a thiophene/bithiophene/terthiophene skeleton: Redox switching of thiophene-thienoquinoid structure accompanied by UV-Vis-NIR electrochromic response2013

    • Author(s)
      Suzuki, T.; Hoshiyama, Y.; Wada, K.; Ishigaki, Y.; Miura,Y.; Kawai, H.; Katoono, R.; Fujiwara, K.; Fukushima, T
    • Journal Title

      Chem. Lett

      Volume: 42(9) Pages: 1004-1006

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 5,10-Dihydrobenzo[a]indolo[2,3-c]-carbazole: A highly fluorescent disk-shaped electron donor exhibiting dual UV-Vis-NIR and fluorescence spectral changes upon electrolysis2013

    • Author(s)
      Suzuki, T.; Tokimizu, Y.; Sakano, Y.; Katoono, R.; Fujiwara, K.; Naoe, S.; Fujii, N.; Ohno, H
    • Journal Title

      Chem. Lett

      Volume: 42(9) Pages: 1001-1003

    • NAID

      10031194320

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oxidative conversion of tetraaryldihydrodibenzothiepins into elemental sulfur and stable cationic dyes accompanied by dual UV-Vis and CD spectral changes2013

    • Author(s)
      Suzuki, T.; Kuroda, T.; Tamaoki, H.; Higasa, S.; Katoono, R.; Fujiwara, K.; Fukushima, T.; Yamada, H
    • Journal Title

      Chem. Lett

      Volume: 42(7) Pages: 706-708

    • NAID

      10031183266

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Redox switching of conjugation length using 9,9,10,10-tetraaryl-9,10-dihydrophennanthene as an ON/OFF unit: Preparation, X-ray structure, and redox properties of perfluorobiphenyl derivative and its SNAr reactions to pi-extended analogues2013

    • Author(s)
      Suzuki, T.; Tamaoki, H.; Katoono, R.; Fujiwara, K.; Ichikawa, J.; Fukushima, T.
    • Journal Title

      Chem. Lett

      Volume: 42(7) Pages: 703-705

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrindacene-based acetylenic macrocycles with horizontally and vertically ordered functionality arrays2013

    • Author(s)
      Kawai, H.; Utamura, T.; Motoi, E.; Takahashi, T.; Sugino, H.; Tamura, M.; Ohkita, M.; Fujiwara, K.; Saito, T.; Tsuji, T.; Suzuki, T
    • Journal Title

      Chem. Eur. J

      Volume: 19(14) Pages: 4513-4524

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 7,7,8,8-Tetraaryl-o-quinodimethane Stabilized by Dibenzo-annulation: A Helical pi-Electron System that Exhibits Electrochromic and Unique Chiroptical Properties,2013

    • Author(s)
      T. Suzuki, Sakano, T. Iwai, S. Iwashita, Y. Miura, R. Katoono, H. Kawai, K. Fujiwara, Y. Tsuji, T. Fukushima,
    • Journal Title

      Chem. Eur. J.

      Volume: 19(1) Pages: 117-123

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Redox switching of conjugation length using 9,9,10,10-tetraaryl-9,10-dihydrophennanthene as an ON/OFF unit: Preparation, X-ray structure, and redox properties of perfluorobiphenyl derivative and its SNAr reactions to pi-extended analogues,2013

    • Author(s)
      T. Suzuki, H. Tamaoki, R. Katoono, K. Fujiwara, J. Ichikawa, T. Fukushima,
    • Journal Title

      Chem. Lett.

      Volume: 42(7) Pages: 703-705

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidative conversion of tetraaryldihydrodibenzothiepins into elemental sulfur and stable cationic dyes accompanied by dual UV-Vis and CD spectral changes2013

    • Author(s)
      T. Suzuki, Kuroda, H. Tamaoki, S. Higasa, R. Katoono, K. Fujiwara, T. Fukushima, H. Yamada,
    • Journal Title

      Chem. Lett.

      Volume: 42(7) Pages: 706-708

    • NAID

      10031183266

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 5,10-Dihydrobenzo[a]indolo[2,3-c]carbazole: A highly fluorescent disk-shaped electron donor exhibiting dual UV-Vis-NIR and fluorescence spectral changes upon electrolysis2013

    • Author(s)
      T. Suzuki, Y. Tokimizu, Y. Sakano, R. Katoono, K. Fujiwara, S. Naoe, N. Fujii, H. Ohno,
    • Journal Title

      Chem. Lett.

      Volume: 42(9) Pages: 1001-1003

    • NAID

      10031194320

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, properties, and X-ray structures of bis(10-methyl-9- methyleneacridan)-type electron donors with a thiophene/bithiophene/terthiophene skeleton: Redox switching of thiophene-thienoquinoid structure accompanied by UV-Vis-NIR electrochromic response2013

    • Author(s)
      T. Suzuki, Y. Hoshiyama, K. Wada, Y. Ishigaki, Y. Miura, H. Kawai, R. Katoono, K. Fujiwara, T. Fukushima,
    • Journal Title

      Chem. Lett.

      Volume: 42(9) Pages: 1004-1006

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] C3-symmetric chrioptical molecular propeller based on hexakis(phenylethynyl)benzene with a threefold terephthalamide: stereospecific propeller generation through the cooperative transmission of point chiralities on the host and guest upon complexation,2013

    • Author(s)
      R. Katoono, H. Kawai, M. Ohkita, K. Fujiwara, T. Suzuki,
    • Journal Title

      Chem. Commun.

      Volume: 49(88) Pages: 10352-10354

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Time-integrated one-pot synthesis, X-ray structure, and redox properties of electrochromic 1,3-diarylisobenzofurans2013

    • Author(s)
      T. Hamura, R. Nakayama, K. Hanada, Y. Sakano, R. Katoono, K. Fujiwara, T. Suzuki,
    • Journal Title

      Chem. Lett.

      Volume: 42(10), Pages: 1244-1246

    • NAID

      10031201325

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Geometrical Remote Steric Effects in 4,5-Disubsitituted-9,10-dihydrophenanthrenes: Expansion of Prestrained C9-C10 Bond in Di(spiroacridan) Derivatives2013

    • Author(s)
      K. Wada, T. Takeda, H. Kawai, R. Katoono, K. Fujiwara, T. Suzuki,
    • Journal Title

      Chem. Lett.

      Volume: 42(10) Pages: 1194-1196

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hexaphenylethanes with an Ultralong C-C Bond: Expandability of the C-C Bond in Highly Strained Tetraarylopyracenes,2013

    • Author(s)
      T. Takada, Y. Uchimura, H. Kawai, R. Katoono, K. Fujiwara, T. Suzuki,
    • Journal Title

      Chem. Lett. (Highlight Review)

      Volume: 42(9) Pages: 954-962

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidative conversion of tetraaryldihydrodibenzothiepins into elemental sulfur and stable cationic dyes accompanied by dual UV-Vis and CD spectral changes,2013

    • Author(s)
      T. Suzuki
    • Journal Title

      Chemistry Letters

      Volume: 42(7) Pages: 706-708

    • NAID

      10031183266

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Redox switching of conjugation length using 9,9,10,10-tetraaryl-9,10-dihydrophennanthene as an ON/OFF unit: Preparation, X-ray structure, and redox properties of perfluorobiphenyl derivative and its SNAr reactions to pi-extended analogues,2013

    • Author(s)
      T. Suzuki
    • Journal Title

      Chemistry Letters

      Volume: 42(7) Pages: 703-705

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 7,7,8,8-Tetraaryl-o-quinodimethane Stabilized by Dibenzo Annulation : A Helical π-Electron System That Exhibits Electrochromic and Unique Chiroptical Properties2013

    • Author(s)
      Takanori Suzuki, et al.
    • Journal Title

      Chemistry-A European Journal

      Volume: 19 Issue: 1 Pages: 117-123

    • DOI

      10.1002/chem.201203092

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Induced Preference for Axial Chirality in a Triarylmethylium o,o-Dimer upon Complexation with Natural gamma-Cyclodextrin: Strong ECD Signaling and Fixation of Supramolecular Chirality to Molecular Chirality2012

    • Author(s)
      Suzuki, T.; Tamaoki, H.; Wada, K.; Katoono, R.; Nehira, T.; Fujiwara, K
    • Journal Title

      Chem. Commun

      Volume: 48 (22) Pages: 2812-2814

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Gyroscope with a trans-cyclohexane-1,4-diimine rotor unit: Isolation and characterization of a geometrical isomer as a formal intermediate of hindered rotation2012

    • Author(s)
      Sugino, H.; Kawai, H.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Chem. Lett.

      Volume: 41 (1) Pages: 79-81

    • NAID

      10030222573

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Axle-Core, Macrocycle, and Side-Station Structures on the Threading and Hydrolysis Processes of Imine-Bridged Rotaxanes2012

    • Author(s)
      Sugino, H.; Kawai, H.; Umehara, T.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Chem. Eur. J

      Volume: 18(43) Pages: 13722-13733

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Non-additive Substituent Effects on Expanding Prestrained C-C Bond in Crystal: X-ray Analyses on Unsymmetrically Substituted Tetraarylpyracenes Prepared by a Flow Microreactor Method2012

    • Author(s)
      Suzuki, T.; Uchimura, Y.; Ishigaki, Y.; Takeda, T.; Katoono, R.; Kawai, H.; Fujiwara, Nagaki, A.; Yoshida
    • Journal Title

      J. Chem. Lett

      Volume: 41(5) Pages: 541-543

    • NAID

      10030619852

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stable neutral radicals based on the polyazaacene skeleton that exhibit high electrochemical amphotericity2012

    • Author(s)
      Miura, Y.; Chiba, H.; Katoono, R.; Kawai, Fujiwara, K.; Suzuki, S.; Okada, K.; Suzuki, T
    • Journal Title

      Tetrahedron Lett

      Volume: 53(48) Pages: 6561-6564

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stable neutral radicals based on the polyazaacene skeleton that exhibit high electrochemical amphotericity2012

    • Author(s)
      Youhei Miura, et al.
    • Journal Title

      Tetrahedron Letters

      Volume: 53 Issue: 48 Pages: 6561-6564

    • DOI

      10.1016/j.tetlet.2012.09.095

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nonadditive substituent effects on expanding prestrained c-c bond in crystal: X-ray analyses on unsymmetrically substituted tetraarylpyracenes prepared by a flow microreactor method2012

    • Author(s)
      Yusuke Ishigaki, et a1.
    • Journal Title

      Chemistry Letters

      Volume: 41 Issue: 5 Pages: 541-543

    • DOI

      10.1246/cl.2012.541

    • NAID

      10030619852

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Non-additive Substituent Effects on Expanding Prestrained C-C Bond in Crystal : X-ray Analyses on Unsymmetrically Substituted Tetraarylpyracenes Prepared by a Flow Microreactor Method2012

    • Author(s)
      T.Suzuki, ら
    • Journal Title

      Chem.Lett.

      Volume: (印刷中)

    • NAID

      10030619852

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hysteretic Tricolor Electrochromic Systems Based on the Dynamic Redox Properties of Unsymmetrically Substituted Dihydrophenanthrenes and Biphenyl-2,2'-Diyl Dications: Efficient Precursor Synthesis by a Flow Microreactor Method2011

    • Author(s)
      Ishigaki, Y.; Suzuki, T.; Nishida, J.; Nagaki, A.; Takabayashi, N.; Kawai, H; .Fujiwara, K.; Yoshida, J
    • Journal Title

      Materials

      Volume: 4 (11) Pages: 1906-1926

    • NAID

      120004996596

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 1,4-Diaryl-7,10-dimethoxyquinoxalino[2,3-b]q uinoxalines and their dihydro derivatives: Redox switching of NIR absorption and fluorescence2011

    • Author(s)
      Miura, Y.; Kawai, H.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Chem. Lett

      Volume: 40 (*9) Pages: 975-957

    • NAID

      10029522204

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photophysical characterization of 4,4'-bis(N-carbazolyl)tolan derivatives and their application in organic light emitting diodos2011

    • Author(s)
      Ohkita, M.; Endo, A.; Sumiya, K.; Nakanotani, H.; Suzuki, T.; Adachi, C. J
    • Journal Title

      Luminescence

      Volume: 131 (7) Pages: 1520-1524

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] イミン架橋によって環の動的挙動を制御する主鎖型オリゴロタキサンの構築とそのスイッチング特性2011

    • Author(s)
      杉野寛佳,河合英敏,藤原憲秀,鈴木孝紀
    • Journal Title

      高分子論文集

      Volume: 68 (12) Pages: 795-803

    • NAID

      10030170256

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Induced Preference for Axial Chirality in a Triarylmethylium o, o-Dimerupon Complexation with Natural gamma-Cyclodextrin : Strong ECD Signaling and Fixation of Supramolecular Chirality to Molecular Chirality2011

    • Author(s)
      Takanori Suzuki, Hitomi Tamaoki, Kazuhisa Wada, Ryo Katoono, Tatsuo Nehira, Hidetoshi Kawai, Kenshu Fujiwara
    • Journal Title

      Chemical Communications

      Volume: 48 Issue: 22 Pages: 2812-2814

    • DOI

      10.1039/c2cc17475h

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hysteretic Tricolor Electrochromic Systems Based on the Dynamic Redox Properties of Unsymmetrically Substituted Dihydrophenanthrenes and Biphenyl-2,2'-Diyl Dications : Efficient Precursor Synthesis by a Flow Microreactor Method2011

    • Author(s)
      T.Suzuki, ら
    • Journal Title

      Materials

      Volume: 4 Pages: 1906-1926

    • NAID

      120004996596

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Induced Preference for Axial Chirality in a Triarylmethylium o,o-Dimerupon Complexation with Natural gamma-Cyclodextrin : Strong ECD Signaling and Fixation of Supramolecular Chirality to Molecular Chirality2011

    • Author(s)
      T.Suzuki, ら
    • Journal Title

      Chem.Commun.

      Volume: 48 Pages: 2812-2814

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Drastic Change in Racemization Barrier upon Redox Reactions: Novel Chiral-memory Units Based on Dynamic Redox Systems2010

    • Author(s)
      Suzuki, T.; Wada, K.; Ishigaki, Y.; Yoshimoto, Y.; Ohta, E.; Kawai, H.; Fujiwara, K
    • Journal Title

      Chem. Commun

      Volume: 46(23) Pages: 4100-4102

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intramolecular Triarylmethane-methylium Complex: Generation, Properties and X-ray Structure of C-H Bridged Carbocation2010

    • Author(s)
      Suzuki, T.; Takeda, T.; Yoshimoto, Y.; Nagasu, T.; Kawai, H.; Fujiwara, K
    • Journal Title

      Pure Appl. Chem

      Volume: 82(4) Pages: 1033-1044

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intramolecular Chirality Transfer in trans-5,6-Diaryl-5,6-dihydro-1,10-phenanthroline-5,6-diols: Solvato- and Halochromic Responses by Circular Dichroism2010

    • Author(s)
      Suzuki, T.; Miura, Y.; Nehira, T.; Kawai, H.; Fujiwara, K
    • Journal Title

      Chem. Lett

      Volume: 39(7) Pages: 695-697

    • NAID

      10027182328

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Halochromic Chiroptical Response of Novel Bis(9-acridinyl)-type Fluorophores with a Helical pi-Framework2010

    • Author(s)
      Nehira, T.; Yoshimoto, Y.; Wada, K.; Kawai, H.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Chem. Lett

      Volume: 39(3) Pages: 165-167

    • NAID

      130004425755

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Phenanthrene-4,5-diylbis(10-methylacridinium) with a Short C^+ - - C^+ Contact: Preparation, Molecular Structure, Redox Properties, and Electrochromic Interconversion with Dihydropyrene Derivative2010

    • Author(s)
      Suzuki, T.; Yoshimoto, Y.; Wada, K.; Takeda, T.; Kawai, H.; Fujiwara, K
    • Journal Title

      Heterocycles

      Volume: 80(1) Pages: 149-155

    • NAID

      40016900091

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Drastic Change in Racemization Barrier upon Redox Reactions : Novel Chiral-memory Units Based on Dynamic Redox Systems2010

    • Author(s)
      T.Suzuki, K.Wada, Y.Ishigaki,, Y.Yoshimoto, E.Ohta, H.Kawai, K.Fujiwara
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 4100-4102

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phenanthrene-4,5-diylbis(10-methylacridinium) with a Short C+--C+ Contact : Preparation, Molecular Structure, Redox Properties, and Electrochromic Interconversion with Dihydropyrene Derivative2010

    • Author(s)
      T.Suzuki, Y.Yoshimoto, K.Wada, T.Takeda, H.Kawai, K.Fujiwara
    • Journal Title

      Heterocycles

      Volume: 80 Pages: 149-155

    • NAID

      40016900091

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Halochromic Chiroptical Response of Novel Bis(9-acridinyl)-type Fluorophores with a Helical pi-Framework2010

    • Author(s)
      T.Nehira, Y.Yoshimoto, K.Wada, H.Kawai, K.Fujiwara, T.Suzuki
    • Journal Title

      Chem.Lett.[Editor's Choice]

      Volume: 39 Pages: 165-167

    • NAID

      130004425755

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intramolecular Chirality Transfer in trans-5,6-Diaryl-5,6-dihydro-1,10-phenanthroline-5,6-diols : Solvato- and Halochromic Responses by Circular Dichroism2010

    • Author(s)
      T.Suzuki, Y.Miura, T.Nehira, H.Kawai, K.Fujiwara
    • Journal Title

      Chem.Lett.

      Volume: 39 Pages: 695-697

    • NAID

      10027182328

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intramolecular Triarylmethane-methylium Complex : Generation, Properties and X-ray Structure of C-H Bridged Carbocation2010

    • Author(s)
      T.Suzuki, T.Takeda, Y.Yoshimoto, T.Nagasu, H.Kawai, K.Fujiwara
    • Journal Title

      Pure Appl.Chem.

      Volume: 82 Pages: 1033-1044

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phenanthrene-4,5-diylbis(10-methylacridinium)with a Short C+--C+ Contact : Preparation, Molecular Structure, Redox Properties, and Electrochromic Interconversion with Dihydropyrene Derivative2010

    • Author(s)
      T.Suzuki, Y.Yoshimoto, K.Wada, T.Takeda, H.Kawai, K.Fujiwara
    • Journal Title

      Heterocycles 80

      Pages: 149-155

    • NAID

      40016900091

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Halochromic Chiroptical Response of Novel Bis(9-acridinyl)-type Fluorophores with a Helical pi-Framework2010

    • Author(s)
      T.Nehira, Y.Yoshimoto, K.Wada, H.Kawai, K.Fujiwara, T.Suzuki
    • Journal Title

      Chem.Lett.[Editor's Choice] 39

      Pages: 165-167

    • NAID

      130004425755

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multi-input-Multi-output Molecular Response System Based on Dynamic Redox Behavior of 3,3,4,4-Tetraaryldihydro[5]helicene Derivatives: Reversible Formation/Destruction of Chiral Fluorophore and Modulation of Chiroptical Properties by Solvent Polarity2009

    • Author(s)
      Suzuki, T.; Ishigaki, Y.; Iwai, T.; Kawai, H.; Fujiwara, K. Ikeda, H.; Kano, Y.; Mizuno, K
    • Journal Title

      Chem. Eur. J

      Volume: 15(37) Pages: 9434-9441

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intramolecular methylacridanmethylacridinium complexes with a phenanthrene-4,5-diyl or related skeleton: Geometry-properties relationship in isolable C-H bridged carbocations2009

    • Author(s)
      Suzuki, T.; Yoshimoto, Y.; Takeda, T.; Kawai, H.; Fujiwara, K
    • Journal Title

      Chem. Eur. J

      Volume: 15(9) Pages: 2210-2216

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dynamic Molecular Propeller: Supramolecular Chirality Sensing by Enhanced Chiroptical Response through the Transmission of Point Chirality to Mobile Helicity2009

    • Author(s)
      Katoono, R.; Kawai, H.; Fujiwara, K.; Suzuki, T
    • Journal Title

      J. Am. Chem. Soc

      Volume: 131(46) Pages: 16896-16904

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 4,5-Bis(diarylmethylene)-1,3-dithiole: A Novel Helical Electron Donor Exhibiting Electrochromic Behavior2009

    • Author(s)
      Suzuki, T.; Mikuni, S.; Ishigaki, Y.; Higuchi, H.; Kawai, H.; Fujiwara, K
    • Journal Title

      Chem. Lett

      Volume: 38(7) Pages: 748-749

    • NAID

      10025124556

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and X-ray Structures of trans-5,6-Diaryl-5,6-dihydro-1,10- phenanthroline-5,6-diols: Formation of Supramolecular Rod by Hydrogen Bonds2009

    • Author(s)
      Suzuki, T.; Miura, Y.; Tamaki, R.; Kawai, H.; Fujiwara, K
    • Journal Title

      Chem. Lett

      Volume: 38(7) Pages: 670-671

    • NAID

      10025123874

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Negligible diradical character for the ultralong C-C bond in 1,1,2,2-tetraarylpyracene derivatives at room temperature2009

    • Author(s)
      Takeda, T.; Kawai, Herges, R.; Mucke, E.; Sawai, Y.; Murakoshi, K.; H.; Fujiwara, K.; Suzuki, T
    • Journal Title

      Tetrahedron Lett

      Volume: 50(26)(50th anniversary special issue) Pages: 3693-3697

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multi-input-Multi-output Molecular Response System Based on Dynamic Redox Behavior of 3,3,4,4-Tetraaryldihydro[5]helicene Derivatives : Reversible Formation/Destruction of Chiral Fluorophore and Modulation of Chiroptical Properties by Solvent Polarity2009

    • Author(s)
      T.Suzuki, Y.Ishigaki, T.Iwai, H.Kawai, K.Fujiwara, H.Ikeda, Y.Kano, K.Mizuno
    • Journal Title

      Chem.Eur.J 15

      Pages: 9434-9441

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Toward the World-Record Compound with the Longest C-C Bond: X-ray Analyses on Unsymmetrically Substituted Tetraarylpyracenes Prepared by a Flow Microreactor Method2013

    • Author(s)
      Suzuki, T
    • Organizer
      The 8 th International Symposium on Integrated Synthesis (ISIS-8)
    • Place of Presentation
      Todaiji Temple Cultural Center, Nara
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Electrochromic and Unique Chiroptical Properties of Helically Deformed Tetraarylquinodimethanes2013

    • Author(s)
      Suzuki, T
    • Organizer
      The 15 th International Symposium on Novel Aromatic Compounds (ISNA-15)
    • Place of Presentation
      Howard Civil Service International House, Taiwan
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Electrochromic and Unique Chiroptical Properties of Helically Deformed Tetraarylquinodimethanes2013

    • Author(s)
      T.Suzuki
    • Organizer
      15th Internatinal Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Howard Civil Service International House (Taiwan)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Intramolecular Triarylmethane-methylium Complex: Generation, Properties and X-ray Structure of a C-H Bridged Carbocations2012

    • Author(s)
      Suzuki, T
    • Organizer
      2012 Hokkaido University & Peking University Joint Symposium on Organic and Organometallic Chemistry
    • Place of Presentation
      Hokkaido Univ., Sapporo
    • Year and Date
      2012-07-17
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Advanced Electrochromism Based on Dynamic Redox Systems: Toward the Realization of Unimolecular Memory and Multi-functional Properties2011

    • Author(s)
      Suzuki, T
    • Organizer
      12th Chitose International Forum on Photonics Science & Technology (CIF12)
    • Place of Presentation
      Chitose Institute of Science and Technology, Chitose
    • Year and Date
      2011-10-13
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Advanced Electrochromism Based on Dynamic Redox Systems : Toward the Realization of Unimolecular Memory and Multi-functional Properties2011

    • Author(s)
      T.Suzuki
    • Organizer
      12th Chitose International Forum on Photonics Science & Technology
    • Place of Presentation
      千歳科学技術大学(千歳市)(招待講演)
    • Year and Date
      2011-10-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] エレクトロクロミズム系の新展開:双安定性と多重出入力機能2009

    • Author(s)
      鈴木 孝紀
    • Organizer
      大阪大学大学院基礎工学研究院特別講演会
    • Place of Presentation
      大阪大学、豊中市
    • Year and Date
      2009-10-29
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] エレクトロクロミズム系の新展開:双安定性と多重出入力機能(英語)2009

    • Author(s)
      鈴木 孝紀
    • Organizer
      理化学研究所特別講演会
    • Place of Presentation
      理化学研究所, 和光市
    • Year and Date
      2009-01-14
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Intramolecular Methylacridan-acridinium Complexes: Isolation, Structure, and Reactivities of the C--H Bridged Carbocations2009

    • Author(s)
      Suzuki, T. Yoshimoto, Y.; Takeda, T.; Kawai, H.; Fujiwara, K
    • Organizer
      The 13 th International Symposium on Novel Aromatic Compounds (ISNA-13)
    • Place of Presentation
      The Hemicycle Conference Center, Luxembourg
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Molecular Response Systems based on Hexaphenylethanes: Toward the Realization of Unimolecular Memory and Multi-functional Properties2009

    • Author(s)
      Suzuki, T
    • Organizer
      The Second International Symposium on Interdisciplinary Materials and Science (ISIMS-2)
    • Place of Presentation
      University of Tsukuba, Tsukuba
    • Related Report
      2013 Final Research Report
    • Invited

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Published: 2009-04-01   Modified: 2019-07-29  

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