| Co-Investigator(Kenkyū-buntansha) |
NAKAZATO Kazuro 名古屋大学, 大学院工学研究科, 教授 (90377804)
YAMANOI Yoshinori 東京大学, 大学院理学系研究科, 准教授 (20342636)
SAKAMOTO Ryota 東京大学, 大学院理学系研究科, 助教 (80453843)
KUSAMOTO Tetsuro 東京大学, 大学院理学系研究科, 助教 (90585192)
久米 晶子 広島大学, 理学(系)研究科(研究院), 准教授 (30431894)
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| Budget Amount *help |
¥144,820,000 (Direct Cost : ¥111,400,000、Indirect Cost : ¥33,420,000)
Fiscal Year 2013 : ¥25,610,000 (Direct Cost : ¥19,700,000、Indirect Cost : ¥5,910,000)
Fiscal Year 2012 : ¥26,520,000 (Direct Cost : ¥20,400,000、Indirect Cost : ¥6,120,000)
Fiscal Year 2011 : ¥28,080,000 (Direct Cost : ¥21,600,000、Indirect Cost : ¥6,480,000)
Fiscal Year 2010 : ¥44,460,000 (Direct Cost : ¥34,200,000、Indirect Cost : ¥10,260,000)
Fiscal Year 2009 : ¥20,150,000 (Direct Cost : ¥15,500,000、Indirect Cost : ¥4,650,000)
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| Research Abstract |
The purpose of this study is to achieve the construction of intelligent molecular networks using coordination programming, to analyze their physical and chemical characteristics, and to develop chemical devices based on their unique functions. We have revealed that the whole electron transfer behavior of a molecular network can be quantitatively estimated by adding the contribution of each molecular unit comprising the network. New methods to connect vinyl and aryl groups to Si surface were developed and used for fabrication of a photo-switch of molecular electrical conductivity. We also created an interfacial method to synthesize metal complex nanosheets, and succeeded in preparation of a redox active and electronically conductive single-layer nickelladitiolene pi-nanosheet. A highly sensitive photosensor based on a combination of bio-component, PSI with molecular wire, AuNP and electrode was constructed. Various kinds of new stimuli-responsive molecules were also synthesized.
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