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Development of Functional Organic and Inorganic Materials through Hierarchical Molecular Programming

Planned Research

Project AreaCoordination Programming - Science of Molecular Superstructures for Chemical Devices
Project/Area Number 21108014
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionMeijo University (2013)
The University of Tokyo (2009-2012)

Principal Investigator

FUJITA Norifumi  名城大学, 理工学部, 准教授 (10346819)

Project Period (FY) 2009-07-23 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥39,260,000 (Direct Cost: ¥30,200,000、Indirect Cost: ¥9,060,000)
Fiscal Year 2013: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2012: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2011: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Fiscal Year 2010: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2009: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Keywordsハイブリッド / プログラム / 自己集合 / 超分子化学 / 階層構造 / フェロセン / 分子集合 / 酸化・還元 / 大環状化合物 / ナノチューブ / 金属錯体
Research Abstract

From an idea to create a molecular assembly with unprecedented properties, Prussian blue, one of the porous metal complexes, has been successfully incorporated in inner space of one-dimensional molecular assemblies generated in low molecular-weight gels. Tetrasubstituted ferrocene having pyridyl groups at 1,1 ', 3,3' positions was designed to form self-assembled nanotube structure with silver (I) and ions, which has a uniform diameter of about 9 nm. Once Ferrocenes in the nanotube structure were oxidized to form ferrocenium ions by adding a suitable oxidizing agent, the ring structure was cut from the tubular structure and the reverse transformation was possible by the reduction of the ferrocenium ions in the ring structure.

Report

(6 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • 2009 Annual Research Report

Research Products

(26 results)

All 2014 2013 2012 2011 2010 2009 Other

All Journal Article (9 results) (of which Peer Reviewed: 4 results) Presentation (16 results) Remarks (1 results)

  • [Journal Article]2014

    • Author(s)
      T.Fukino, H.Joo, Y.Hisada, M.Obana, H. Yamagishi, T.Hikima, M.Takata, N.Fujita, T.Aida
    • Journal Title

      Science

      Volume: 344 Pages: 499-504

    • Related Report
      2013 Final Research Report
  • [Journal Article] Manipulation of Discrete Nanostructures by Selective Modulation of Noncovalent Forces2014

    • Author(s)
      Takahiro Fukino, Hyunho Joo, Yuki Hisada, Maiko Obana, Hiroshi Yamagishi, Takaaki Hikima, Masaki Takata, Norifumi Fujita, Takuzo Aida
    • Journal Title

      Science

      Volume: 344 Pages: 499-504

    • DOI

      10.1126/science.1252120

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article]2010

    • Author(s)
      T.Fukino, N.Fujita, T.AidaT.Fukino, N.Fujita, T.Aida
    • Journal Title

      Org. Lett.

      Volume: 12 Pages: 3074-3077

    • Related Report
      2013 Final Research Report
  • [Journal Article]2010

    • Author(s)
      P.Mukhopadhyay, N.Fujita, A.Takada, T.Kishida, M.Shirakawa, S.Shinkai
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 49 Pages: 6338-6342

    • Related Report
      2013 Final Research Report
  • [Journal Article]2009

    • Author(s)
      A.Dawn, N.Fujita, S.Haraguchi, K.Sada, S.-i.Tamaru S.Shinkai
    • Journal Title

      Org. Biomol. Chem

      Volume: 7 Pages: 4378-4385

    • Related Report
      2013 Final Research Report
  • [Journal Article]2009

    • Author(s)
      A.Dawn, N.Fujita, S.Haraguchi, K.Sada, S.Shinkai
    • Journal Title

      Chem. Commun.

      Pages: 2100-2102

    • Related Report
      2013 Final Research Report
  • [Journal Article] An organogel system can control the stereochemical course of anthracene photodimerization2009

    • Author(s)
      A.Dawn, et.al
    • Journal Title

      Chem.Commun

      Pages: 2100-2102

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical and electrical anisotropies of polydiacetylene derivative film aligned by shear stress2009

    • Author(s)
      M.Fujimoto, et.al
    • Journal Title

      Synth.Met.

      Volume: 159 Pages: 871-874

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Studies on a new class of organogelator containing 2-anthracenecarboxylic acid : influence of gelato2009

    • Author(s)
      A.Dawn, et.al
    • Journal Title

      Org.Biomol.Chem.

      Volume: 7 Pages: 4378-4385

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Molecular Programming on Tetra-substituted Ferrocenes for Nano- and Mesoscale Assemblies2014

    • Author(s)
      Norifumi Fujita
    • Organizer
      International Symposium on Coordination Programming (ISCP2014)
    • Place of Presentation
      東京大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] メタロセンナノチューブ(1):筒状集合体からの巨大環状錯 体の切り出し2013

    • Author(s)
      久田有希・吹野耕大・藤田典史・相田卓三
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津
    • Year and Date
      2013-03-22
    • Related Report
      2012 Annual Research Report
  • [Presentation] メタロセンナノチューブ(2):配位ナノチューブの不斉誘起2013

    • Author(s)
      山岸洋・吹野耕大・藤田典史・相田卓三
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津
    • Year and Date
      2013-03-22
    • Related Report
      2012 Annual Research Report
  • [Presentation] メタロセンナノチューブ(3):多種金属混合ナノチューブの開発2013

    • Author(s)
      吹野耕大・藤田典史・相田卓三
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津
    • Year and Date
      2013-03-22
    • Related Report
      2012 Annual Research Report
  • [Presentation] 四置換フェロセンを基体とする自己集合性配位ナノチューブ2012

    • Author(s)
      吹野 耕大・朱 賢鎬・藤田 典史・相田 卓三
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山
    • Year and Date
      2012-09-21
    • Related Report
      2012 Annual Research Report
  • [Presentation] π共役キラルフェロセンを回転軸とする多関節ポリマーの折りたたみと自己集合2012

    • Author(s)
      吹野耕大, 藤田典史, 相田卓三
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
  • [Presentation] π共役フェロセンナノチューブ2012

    • Author(s)
      朱賢鎬・吹野耕大・藤田典史・相田卓三
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
  • [Presentation] 四置換フェロセンを基体とする自己集合性配位ナノチューブ2012

    • Author(s)
      藤田典史
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山
    • Related Report
      2013 Final Research Report
  • [Presentation] メタロセンナノチューブ(1) : 筒状集合体からの巨大環状錯体の切り出し2012

    • Author(s)
      藤田典史
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津
    • Related Report
      2013 Final Research Report
  • [Presentation] メタロセンナノチューブ(2) : 配位ナノチューブの不斉誘起2012

    • Author(s)
      藤田典史
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津
    • Related Report
      2013 Final Research Report
  • [Presentation] メタロセンナノチューブ(3) : 多種金属混合ナノチューブの開発2012

    • Author(s)
      藤田典史
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津
    • Related Report
      2013 Final Research Report
  • [Presentation] 折りたたみによるナノ相分離構造の形成を指向した多関節ポリマーの開発2011

    • Author(s)
      吹野耕大, 藤田典史, 相田卓三
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
  • [Presentation] 階層分子プログラミングによる機能性有機/無機複合材料の開発2010

    • Author(s)
      藤田典史
    • Organizer
      新学術領域第3回全体会議
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] 剛直なジアセチレンと自由回転可能なキラルフェロセンからなる多関節オリゴマーの特異なコンフォメーション変化2010

    • Author(s)
      藤田典史
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜
    • Related Report
      2013 Final Research Report
  • [Presentation] 一次元π電子集積系の構築と機能-オルガノゲルをモチーフとして-2009

    • Author(s)
      藤田典史
    • Organizer
      日本化学会第3回関東支部大会
    • Place of Presentation
      東京
    • Year and Date
      2009-09-05
    • Related Report
      2013 Final Research Report
  • [Presentation] 一次元π電子集積系の構築と機能-オルガノゲルをモチーフとして-2009

    • Author(s)
      藤田典史
    • Organizer
      日本化学会 第3回関東支部大会
    • Place of Presentation
      東京
    • Year and Date
      2009-09-05
    • Related Report
      2009 Annual Research Report
  • [Remarks] 相田研究室

    • URL

      http://macro.chem.t.u-tokyo.ac.jp/AIDA_LABORATORY_JP/TOP_JP.html

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2009-03-31   Modified: 2018-03-28  

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