| Project Area | Coordination Programming - Science of Molecular Superstructures for Chemical Devices |
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| Project/Area Number |
24108102
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| Research Category |
Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Kyushu University |
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Principal Investigator |
OHBA Masaaki 九州大学, 理学(系)研究科(研究院), 教授 (00284480)
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| Co-Investigator(Renkei-kenkyūsha) |
KOSHIYAMA Tomomi 九州大学, 大学院理学研究院, 助教 (30467279)
YONEDA Ko 佐賀大学, 大学院工学系研究科, 助教 (50622239)
HORI Akihiro 理化学研究所, 放射光科学総合研究センター, 特別研究員 (50595064)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Fiscal Year 2013: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
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| Keywords | 金属錯体化学 / 多孔性配位高分子 / 多孔性金属錯体 / スピン転移 / ゲスト応答性 / ヨウ素 |
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| Research Abstract |
The research project targeted creating novel high-order functions by strategic integration of the functional molecular units (FMUs) in the coordination frameworks. A porous coordination polymer {Fe(pz)[Pt(CN)4]} (pz = pyrazine) was used as a key material. The compound are rationally incorporated different FMUs, Fe(II) as a spin crossover center, p-conjugated ligand pz and coordination unsaturated Pt(II), in the porous framework to interlock the physical properties of FMUs and structural function of the framework. In the project, we succeeded in the following points for creating new multifunctional compounds, (1) control of the spin state through host-guest interaction and elucidation of its mechanism, (2) enhancement of guest responsivity by meso-particulation and (3) preparation of liposome-metal complex composite.
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