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Synthesis and reactions of bifunctional open-shell species of main group elements

Planned Research

Project AreaStimuli-responsive Chemical Species for the Creation of Functional Molecules
Project/Area Number 24109004
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionTohoku University

Principal Investigator

Iwamoto Takeaki  東北大学, 理学研究科, 教授 (70302081)

Co-Investigator(Renkei-kenkyūsha) ISHIDA Shintaro  東北大学, 理学研究科, 准教授 (90436080)
Research Collaborator HIRAKAWA Fumiya  
IIMURA Tomohiro  
KOSAI Tomoyuki  
MIURA Yuki  
SUZUKI Yuko  
ICHIKAWA Hitomi  
Project Period (FY) 2012-06-28 – 2017-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥44,070,000 (Direct Cost: ¥33,900,000、Indirect Cost: ¥10,170,000)
Fiscal Year 2016: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Fiscal Year 2015: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Fiscal Year 2014: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Fiscal Year 2013: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Fiscal Year 2012: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Keywords安定ラジカル / ホスフィニルラジカル / アンチモン / ビスマス / 遷移帰属 / シリレン / ヒ素 / 遷移金属 / 二官能性 / 典型元素 / 開殻化学種 / 合成 / 反応 / 鉄 / 二核 / 遷移金属錯体 / 酸化還元
Outline of Final Research Achievements

We have successfully synthesized a series of neutral two-coordinate radicals of heavy group-15 elements, which enable us to compare their structures and reactivity. Novel platinum and iron complexes ligated by the phosphine-centered radical were also synthesized and we found that the phosphinyl radical works as a stronger pi acceptor compared to trialkylphosphine and stabilizes the low-coordinate metal radical center. We also developed novel photochemical transformation reactions of azulenes in the presence of a dialkylsilylene. A novel silylene with balancing thermal stability and reactivity was synthesized. Using this new silylene, we disclosed unprecedented intermolecular C-H insertion reactions of a silylene as well as dehydroaromatization reactions.

Report

(6 results)
  • 2017 Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (60 results)

All 2018 2017 2016 2015 2014 2013 2012

All Journal Article (20 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 20 results,  Acknowledgement Compliant: 11 results,  Open Access: 1 results) Presentation (40 results) (of which Int'l Joint Research: 10 results,  Invited: 10 results)

  • [Journal Article] Structural Change upon One-Electron Reduction of an Isolable Dialkylsilylene2018

    • Author(s)
      Takashi Abe, Shintaro Ishida, and Takeaki Iwamoto
    • Journal Title

      Bulletin of Chemcal Society of Japan

      Volume: 91 Issue: 4 Pages: 684-686

    • DOI

      10.1246/bcsj.20170380

    • NAID

      130006707618

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Series of Two-coordinate Group-15 Element (P, As, Sb, Bi) Centered Radicals Having Bulky Alkyl Groups2018

    • Author(s)
      Shintaro Ishida, Fumiya Hirakawa, Takeaki Iwamoto
    • Journal Title

      Bulletin of Chemcal Society of Japan

      Volume: 印刷中 Issue: 7 Pages: 1168-1175

    • DOI

      10.1246/bcsj.20180057

    • NAID

      130007404810

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene2017

    • Author(s)
      Asami, S.-s.; Ishida, S.; Iwamoto, T.; Suzuki, K.; Yamashita, M.
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 56 Issue: 6 Pages: 1658-1662

    • DOI

      10.1002/anie.201611762

    • NAID

      120006305576

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Coordination-induced Hydrogen Abstraction in the Reactions of a Stable Dialkylphosphinyl Radical with BH3-Lewis Base Adducts2017

    • Author(s)
      Shintaro Ishida, Hitomi Ichikawa, Takeaki Iwamoto
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 6 Pages: 883-885

    • DOI

      10.1246/cl.170248

    • NAID

      130005689312

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Pt(0) complex with cyclic (alkyl)(amino)silylene and 1,3-divinyl-1,1,3,3-tetramethyldisiloxane ligands: synthesis, molecular structure, and catalytic hydrosilylation activity2017

    • Author(s)
      Tomohiro Iimura, Naohiko Akasaka, Tomoyuki Kosai, Takeaki Iwamoto
    • Journal Title

      Dalton Transaction

      Volume: 46 Issue: 27 Pages: 8868-8874

    • DOI

      10.1039/c7dt01113j

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene2016

    • Author(s)
      Ohsato, T.; Okuno, Y.; Ishida, S.; Iwamoto, T.; Lee, K.-H.; Lin, Z.; Yamashita, M.; Nozaki, K.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 38 Pages: 11426-11430

    • DOI

      10.1002/anie.201605005

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] A Two-Coordinate Cyclic (Alkyl)(amino)silylene: Balancing Thermal Stability and Reactivity2016

    • Author(s)
      Tomoyuki Kosai, Shintaro Ishida, Takeaki Iwamoto
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 50 Pages: 15554-15558

    • DOI

      10.1002/anie.201608736

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Dialkylsilylene-Pt(0) Complex with a DVTMS Ligand for the Catalytic Hydrosilylation of Functional Olefins2016

    • Author(s)
      Tomohiro Iimura, Naohiko Akasaka, Takeaki Iwamoto
    • Journal Title

      Organometallics

      Volume: 35 Issue: 24 Pages: 4071-4076

    • DOI

      10.1021/acs.organomet.6b00741

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Isolable Potassium Salt of a Borasilene - Chloride Adduct2016

    • Author(s)
      Suzuki, Y.; Ishida, S.; Sato, S.; Isobe, H.; Iwamoto, T.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 56 Issue: 16 Pages: 4593-4597

    • DOI

      10.1002/anie.201612545

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Persistent four-coordinate iron-centered radical stabilized by π-donation2016

    • Author(s)
      Yusuke Sunada, Shintaro Ishida, Fumiya Hirakawa, Yoshihito Shiota, Kazunari Yoshizawa, Shinji Kanegawa, Osamu Sato, Hideo
    • Journal Title

      Chem. Sci.

      Volume: 7 Issue: 1 Pages: 191-198

    • DOI

      10.1039/c5sc02601f

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Redox Reactions of a Stable Dialkylphosphinyl Radical2015

    • Author(s)
      Fumiya Hirakawa, Hitomi Ichikawa, Shintaro Ishida, Takeaki Iwamoto
    • Journal Title

      Organometallics

      Volume: 34 Issue: 12 Pages: 2714-2716

    • DOI

      10.1021/acs.organomet.5b00323

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Transformation of azulenes to bicyclic [4]dendralene and heptafulvene derivatives by photochemical cycloaddition of dialkylsilylene2015

    • Author(s)
      Tomoyuki Kosai, Shintaro Ishida, Takeaki Iwamoto
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 53 Pages: 10707-10709

    • DOI

      10.1039/c5cc03424h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Reactions of a Stable Phosphinyl Radical with Stable Aminoxyl Radicals2015

    • Author(s)
      石田真太郎、平川文弥、岩本武明
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 1 Pages: 94-96

    • DOI

      10.1246/cl.140885

    • NAID

      130004868307

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Persistent Antimony- and Bismuth-Centered Radicals in Solution2014

    • Author(s)
      石田真太郎、平川文弥、古川 貢、与座健治、岩本武明
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 53 Issue: 42 Pages: 11172-11176

    • DOI

      10.1002/anie.201405509

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Two-coordinate Dialkylsilylene-Coinage Metal Complexes2014

    • Author(s)
      Yuichiro Inagawa, Shintaro Ishida, Takeaki Iwamoto
    • Journal Title

      Chemistry Letters

      Volume: 43 Issue: 10 Pages: 1665-1667

    • DOI

      10.1246/cl.140651

    • NAID

      130004693817

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Near-IR Absorbing Nickel(II) Porphyrinoids Prepared by Regioselective Insertion of Silylenes into Antiaromatic Nickel(II) Norcorrole2014

    • Author(s)
      Takaki Fukuoka, Kenya Uchida, Young Mo Sung, Ji-Young Shin, Shintaro Ishida, Dr. Jong Min Lim, Satoru Hiroto, Ko Furukawa, Dongho Kim, Takeaki Iwamoto, Hiroshi Shinokubo
    • Journal Title

      Angewandte Chemie, International Edition

      Volume: 53 Issue: 6 Pages: 1506-1509

    • DOI

      10.1002/anie.201309921

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Unexpected Formation of Highly Strained 2,5-Dioxa-Silabicyclo[2.1.0]Pentane by the Reaction of Isolable Dialkylsilylene with Benzil2014

    • Author(s)
      Shintaro Ishida, Kenya Uchida, Takeaki Iwamoto
    • Journal Title

      Heteroatom Chemistry

      Volume: 25 Issue: 5 Pages: 348-353

    • DOI

      10.1002/hc.21162

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Two-Coordinate Palladium Complex with Two Dialkylphosphinyl Ligands2012

    • Author(s)
      Takeaki Iwamoto, Fumiya Hirakawa, Shintaro Ishida
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 51 Issue: 48 Pages: 12111-12114

    • DOI

      10.1002/anie.201206997

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Siloxy-Substituted Cyclopentadiene Showing Aggregation-Enhanced Emission: An Application of Cycloaddition of Isolable Dialkylsilylene2012

    • Author(s)
      Shintaro Ishida, Kenya Uchida, Tsunenobu Onodera, Hidetoshi Oikawa, Mitsuo Kira, Takeaki Iwamoto
    • Journal Title

      Organometallics

      Volume: 31 Issue: 17 Pages: 5983-5985

    • DOI

      10.1021/om3005178

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New Isolable Dialkylsilylene and its Isolable Dimer That Equilibrate in Solution2012

    • Author(s)
      Abe, T
    • Journal Title

      Journal of the American Chemical Society

      Volume: 134 Issue: 49 Pages: 20029-20032

    • DOI

      10.1021/ja310391m

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] 単離可能なジアルキルシリレンの環化付加反応によるシリル化フラーレンの合成と性質2018

    • Author(s)
      森真依子、石田真太郎、岩本武明
    • Organizer
      日本化学会第98春季年会2018
    • Related Report
      2016 Annual Research Report
  • [Presentation] Isolable Alkyl-Substituted Silylenes2017

    • Author(s)
      Takeaki Iwamoto
    • Organizer
      Cambridge-Tohoku Organic Chemistry Symposium
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 安定ホスフィニルラジカルとボラン錯体との反応2017

    • Author(s)
      市川ひとみ、石田真太郎、岩本武明
    • Organizer
      日本化学会第97春季年会2017
    • Related Report
      2016 Annual Research Report
  • [Presentation] ボラシレン Cl付加体の反応2017

    • Author(s)
      鈴木優子、石田真太郎、岩本武明
    • Organizer
      日本化学会第97春季年会2017
    • Related Report
      2016 Annual Research Report
  • [Presentation] 環状アルキルアミノシリレンの反応2017

    • Author(s)
      小齋智之、石田真太郎、岩本武明
    • Organizer
      日本化学会第97春季年会2017
    • Related Report
      2016 Annual Research Report
  • [Presentation] Novel Isolable Two-Coordinate Alkylsilylenes2017

    • Author(s)
      Takeaki Iwamoto
    • Organizer
      The 12th International Conference of Heteroatom Chemistry
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 安定シリレンの環化付加による新規シリル化フラーレンの合成と性質2017

    • Author(s)
      森真依子、石田真太郎、岩本武明
    • Organizer
      第29回万有仙台シンポジウム
    • Related Report
      2016 Annual Research Report
  • [Presentation] Novel Stable Multiply-Bonded Silicon Compounds Bearing Isolable Cyclic Alkylsilylene Units2017

    • Author(s)
      Takeaki Iwamoto
    • Organizer
      The 18th International Symposium on Silicon Chemistry (ISOS-XVIII) & the 6th Asian Silicon Symposium (ASiS-6)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and Properties of A Two-coordinate Cyclic (Alkyl)(amino)silylene2017

    • Author(s)
      Tomoyuki Kosai, Shintaro Ishida, Takeaki Iwamoto
    • Organizer
      The 18th International Symposium on Silicon Chemistry (ISOS-XVIII) & the 6th Asian Silicon Symposium (ASiS-6)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 安定環状アルキルアミノシリレンの反応性2017

    • Author(s)
      小齋智之、飯村智浩、赤坂直彦、石田真太郎、岩本武明
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 安定ジアルキルシリレンの環化付加反応により誘導される新規シリル化フラーレン2017

    • Author(s)
      森真依子、石田真太郎、岩本武明
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 単離可能な高周期15族元素中心ラジカル合成、構造と酸化還元反応2016

    • Author(s)
      岩本武明、三浦裕貴、石田 真太郎
    • Organizer
      新学術領域「感応性化学種が拓く新物質科学」第4回公開シンポジウム
    • Related Report
      2016 Annual Research Report
  • [Presentation] 安定ホスフィニルラジカルとホウ素化合物の反応2016

    • Author(s)
      市川ひとみ、石田真太郎、岩本武明
    • Organizer
      第27回基礎有機化学討論会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 高反応性と熱安定性を示す環状アルキルアミノシリレンの合成と性質2016

    • Author(s)
      小齋智之、石田真太郎、岩本武明
    • Organizer
      第43回有機典型元素化学討論会
    • Related Report
      2016 Annual Research Report
  • [Presentation] Series of persistent neutral heavy group-15 element radicals with bulky alkyl substituents2015

    • Author(s)
      Takeaki Iwamoto
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (PACIFICHEM) 2015
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 単離可能な中性二配位高周期15族元素中心ラジカル2015

    • Author(s)
      三浦裕貴、石田真太郎、岩本武明
    • Organizer
      第42回有機典型元素化学討論会
    • Place of Presentation
      名古屋大学、名古屋
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 単離可能なケイ素二価化学種を用いたアズレン類の骨格変換反応2015

    • Author(s)
      小齋智之、石田真太郎、岩本武明
    • Organizer
      第26回基礎有機化学討論会
    • Place of Presentation
      愛媛大学・松山大学、松山
    • Year and Date
      2015-09-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] A Persistent Dialkylphosphinyl Radical and Related Compounds2015

    • Author(s)
      Takeaki Iwamoto
    • Organizer
      The 6th Japanese-Sino Symposium on Organic Chemistry for Young Scientists
    • Place of Presentation
      Akiu, Sendai
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Transformation of Azulenes by Photoreaction with Silylene2015

    • Author(s)
      Tomoyuki Kosai, Shintaro Ishida, Takeaki Iwamoto
    • Organizer
      The 6th Japanese-Sino Symposium on Organic Chemistry for Young Scientists
    • Place of Presentation
      Akiu, Sendai
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 単離可能な中性二配位アンチモン中心ラジカル2015

    • Author(s)
      三浦裕貴、石田真太郎、岩本武明
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] ジアルキルシリレン11族遷移金属錯体の合成、構造および反応2015

    • Author(s)
      稲川雄一郎、石田真太郎、岩本武明
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Persistent Two-coordinate Radicals of Heavy Group-15 Elements2014

    • Author(s)
      Takeaki Iwamoto
    • Organizer
      The 16th Korea-Japan Joint Symposium on Organometallic and Coordination Chemistry
    • Place of Presentation
      Sendai
    • Year and Date
      2014-10-23
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Neutral Copper(I) Complexes Coordinated by Dialkylsilylene Ligand2014

    • Author(s)
      Yuichiro Inagawa, Shintaro Ishida, Takeaki Iwamoto
    • Organizer
      The 16th Korea-Japan Joint Symposium on Organometallic and Coordination Chemistry
    • Place of Presentation
      Sendai
    • Year and Date
      2014-10-23
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 嵩高い1,1,4,4-テトラシリルブタン-1,4-ジイル基によって安定化された単離可能な中性二配位アンチモンラジカル2014

    • Author(s)
      三浦裕貴、石田真太郎、岩本武明
    • Organizer
      第18回ケイ素化学協会シンポジウム
    • Place of Presentation
      那須
    • Year and Date
      2014-10-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 単離可能な中性二配位アンチモン中心ラジカルの合成と性質2014

    • Author(s)
      三浦裕貴、石田真太郎、岩本武明
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2014-09-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] 長寿命中性二配位高周期15族元素ラジカル2014

    • Author(s)
      岩本武明、平川文弥、三浦裕貴、石田真太郎
    • Organizer
      感応性化学種が拓く新物質科学第3回公開シンポジウム
    • Place of Presentation
      つくば
    • Year and Date
      2014-06-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] Persistent Neutral Two-coordinate Radicals of Heavy Group-15 Elements2014

    • Author(s)
      Takeaki Iwamoto
    • Organizer
      The International Symposium on Reactive Intermediates and Unusual Molecules (ISRIUM) 2014
    • Place of Presentation
      Hiroshima
    • Year and Date
      2014-04-01
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 二配位15族元素ラジカルとニトロキシラジカルとの反応2013

    • Author(s)
      平川文弥、石田真太郎、岩本武明
    • Organizer
      第40回有機典型元素化学討論会
    • Place of Presentation
      近畿大学
    • Year and Date
      2013-12-05 – 2013-12-07
    • Related Report
      2013 Annual Research Report
  • [Presentation] 嵩高いアルキル基で安定化された高周期典型元素二官能性化合物の合成、構造と反応2013

    • Author(s)
      岩本武明
    • Organizer
      日本化学会東北支部青森地区講演会
    • Place of Presentation
      弘前大学理工学部
    • Year and Date
      2013-10-04
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Diverse Reactivity of an Isolable Dialkylsilylene toward Aromatic Ketones2013

    • Author(s)
      Kenya Uchida, Shintaro Ishida, Takeaki Iwamoto
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      東北大学
    • Year and Date
      2013-09-28 – 2013-09-30
    • Related Report
      2013 Annual Research Report
  • [Presentation] A Stable Phosphorus-centered Radical:Synthesis, Structure, Properties, and Its Transition Metal Complexes2013

    • Author(s)
      Fumiya Hirakawa, Shintaro Ishida, Takeaki Iwamoto
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      東北大学
    • Year and Date
      2013-09-28 – 2013-09-30
    • Related Report
      2013 Annual Research Report
  • [Presentation] 中性二配位15族元素ラジカルの性質と反応2013

    • Author(s)
      平川文弥、石田真太郎、岩本武明
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学
    • Year and Date
      2013-09-05 – 2013-09-07
    • Related Report
      2013 Annual Research Report
  • [Presentation] 特異な構造と電子状態をもつ14および15族元素低配位化合物2013

    • Author(s)
      岩本武明
    • Organizer
      日本化学会関東支部群馬地区講演会
    • Place of Presentation
      群馬大学桐生キャンパス
    • Year and Date
      2013-07-16
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 安定ジアルキルホスフィニルラジカルとその10族遷移金属錯体2013

    • Author(s)
      平川文弥、石田真太郎、岩本武明
    • Organizer
      第24回万有仙台シンポジウム
    • Place of Presentation
      仙台国際センター
    • Year and Date
      2013-06-29
    • Related Report
      2013 Annual Research Report
  • [Presentation] 著しく長い高周期15族元素間結合を有するテトラアルキルジビスムタンおよびジスチバンの合成および性質2013

    • Author(s)
      平川文弥、石田真太郎、岩本武明
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Related Report
      2012 Annual Research Report
  • [Presentation] 単離可能なジアルキルシリレンとピリジン誘導体との反応:シリレンの環化付加による高度共役系の合成2013

    • Author(s)
      内田 健哉、石田 真太郎、岩本 武明
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Related Report
      2012 Annual Research Report
  • [Presentation] 単離可能なシリレンを用いた不飽和および芳香族ケトンの変換反応2012

    • Author(s)
      石田真太郎、内田健哉、小野寺恒信、及川英俊、吉良満夫、岩本武明
    • Organizer
      第59回有機金属化学討論会
    • Place of Presentation
      大阪
    • Related Report
      2012 Annual Research Report
  • [Presentation] 二官能性典型元素開殻化学種の創製と反応2012

    • Author(s)
      岩本武明
    • Organizer
      新学術領域「感応性化学種が拓く新物質科学」第1回公開シンポジウム
    • Place of Presentation
      京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] 著しく長い高周期15族元素間結合を有するテトラアルキル置換ジスチバンおよびジビスムタンの合成、構造、および性質2012

    • Author(s)
      平川文弥、石田真太郎、岩本武明
    • Organizer
      第39回典型元素化学討論会
    • Place of Presentation
      岩手
    • Related Report
      2012 Annual Research Report
  • [Presentation] 嵩高いアルキル基で速度論的に安定化された低配位高周期典型元素化合物の合成と構造2012

    • Author(s)
      岩本武明
    • Organizer
      第39回典型元素化学討論会
    • Place of Presentation
      岩手
    • Related Report
      2012 Annual Research Report
    • Invited

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Published: 2012-11-27   Modified: 2019-07-29  

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