| Budget Amount *help |
¥32,110,000 (Direct Cost : ¥24,700,000、Indirect Cost : ¥7,410,000)
Fiscal Year 2016 : ¥6,370,000 (Direct Cost : ¥4,900,000、Indirect Cost : ¥1,470,000)
Fiscal Year 2015 : ¥6,370,000 (Direct Cost : ¥4,900,000、Indirect Cost : ¥1,470,000)
Fiscal Year 2014 : ¥6,370,000 (Direct Cost : ¥4,900,000、Indirect Cost : ¥1,470,000)
Fiscal Year 2013 : ¥6,370,000 (Direct Cost : ¥4,900,000、Indirect Cost : ¥1,470,000)
Fiscal Year 2012 : ¥6,630,000 (Direct Cost : ¥5,100,000、Indirect Cost : ¥1,530,000)
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| Outline of Final Research Achievements |
Various types of boron-containing functional pi-electron materials have been developed, which exhibit intriguing reactivity as well as photophysical and electronic properties due to the electron-deficient character of the tricoordinate boron isoelectronic with a carbenium ion. For example, we have discovered two new photoreaction modes of organoboranes. We have also successfully prepared a series of planarized boron-containing pi-electron materials as the models of boron-doped graphenes. In particular, we have prepared a columnar liquid crystalline material with ambipolar charge carrier transporting properties using a planarized triphenylborane as a mesogen.
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