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Syntheses and Catalytic Function of Transition-metal Complexes Having Reactive Heavier Main Group ElementMetal Multiple Bonds

Planned

Project AreaStimuli-responsive Chemical Species for the Creation of Functional Molecules
Project/Area Number 24109011
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionTohoku University

Principal Investigator

Hashimoto Hisako  東北大学, 理学研究科, 准教授 (60291085)

Co-Investigator(Renkei-kenkyūsha) TOBITA Hiromi  東北大学, 大学院理学研究科, 教授 (30180160)
Research Collaborator OCHIAI Mitsuyoshi  東北大学, 大学院理学研究科, 大学院生
FUKUDA Testuya  東北大学, 大学院理学研究科, 大学院生
KOMURA Katsuto  東北大学, 大学院理学研究科, 大学院生
NISHIMURA Kimihiko  東北大学, 大学院理学研究科, 大学院生
YOSHIMOTO Takashi  東北大学, 大学院理学研究科, 大学院生
DHUNGANA P. Tara  
Project Period (FY) 2012-06-28 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥34,710,000 (Direct Cost: ¥26,700,000、Indirect Cost: ¥8,010,000)
Fiscal Year 2016: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2015: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2014: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2013: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2012: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Keywords高周期元素化学 / 錯体化学 / 有機金属化学 / 14族元素化学 / 基礎化学 / 有機化学 / 合成化学 / 無機化学 / 触媒開発 / 高周期元素 / ゲルマニウム / ケイ素 / 三重結合 / 鉄 / タングステン / 二重結合 / ヒドロシリル化反応 / シリレン錯体 / ゲルミレン錯体 / ゲルミリン錯体 / ルテニウム / アルデヒド
Outline of Final Research Achievements

We investigated new types of functional molecules and synthesized many “stimuli-responsive” metal complexes that have a variety of multiple bonds between silicon or germanium and transition metals. Spectroscopical properties and X-ray crystal structures of the products were clarified. The study of their reactivity resulted in finding several new types of reactions. Especially, through the investigation using triple bonded complexes, we obtained many kinds of new [2+2] cycloaddition products, ketone-coupling products, and also found the metathesis-like fragmentation reaction, which is the first example of this type of reaction in the silicon system and is a significant result from the viewpoint of the reaction chemistry.

Report

(6 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • 2012 Annual Research Report

Research Products

(74 results)

All 2017 2016 2015 2014 2013 2012 Other

All Journal Article (14 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 14 results,  Acknowledgement Compliant: 9 results,  Open Access: 4 results) Presentation (54 results) (of which Int'l Joint Research: 8 results,  Invited: 11 results) Book (2 results) Remarks (4 results)

  • [Journal Article] Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M-Si-H-Si four-membered ring2017

    • Author(s)
      Hisako Hashimoto, Katsuto Komura, Takatoshi Ishizaki, Yuto Odagiri, Hiromi Tobita
    • Journal Title

      Dalton Transacitions

      Volume: in press Pages: 8701-8704

    • DOI

      10.1039/c7dt00505a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of a Tungsten-Silylyne Complex via Stepwise Proton and Hydride Abstraction from a Hydrido Hydrosilylene Complex2016

    • Author(s)
      T. Fukuda, T. Yoshimoto, H. Hashimoto, H. Tobita
    • Journal Title

      Organometallics

      Volume: 35 Pages: 921-924

    • DOI

      10.1021/acs.organomet.6b00095

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Silylyne Tungsten Complex Having an Eind Group on Silicon: Its Dimer-Monomer Equilibrium and Cycloaddition Reactions with Carbodiimide and Diaryl Ketones2016

    • Author(s)
      T. Yoshimoto, H. Hashimoto, N. Hayakawa, T. Matsuo, H. Tobita
    • Journal Title

      Organometallics

      Volume: 35 Pages: 3444-3447

    • DOI

      10.1021/acs.organomet.6b00670

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Rhodium-catalyzed P-P bond exchange reaction of diphosphine disulfides2016

    • Author(s)
      Mieko Arisawa; Tomoki Yamada; Saori Tanii; Yuta Kawada; Hisako Hashimoto; Masahiko Yamaguchi
    • Journal Title

      Chemical Communications

      Volume: 52 Pages: 13580-13583

    • DOI

      10.1039/c6cc07302f

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Stabilization of a Silaaldehyde by its η2-Coordination to Tungsten2016

    • Author(s)
      Tetsuya Fukuda, Hisako Hashimoto, Shigeyoshi Sakaki, Hiromi Tobita
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Pages: 188-192

    • DOI

      10.1002/anie.201507956

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Unexpected Formation of NHC-Stabilized Hydrosilylyne Complexes via Alkane Elimination from Hydrido(alkylsilylene) Complexes2015

    • Author(s)
      Tetsuya Fukuda, Hisako Hashimoto, Hiromi Tobita
    • Journal Title

      Jounal of the American Chemical Society

      Volume: 137 (34) Pages: 10906-10909

    • DOI

      10.1021/jacs.5b06366

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Isolation of a Hydrogen-Bridged Bis(silylene) Tungsten Complex : A Snapshot of a Transition State for 1, 3-Hydrogen Migration2015

    • Author(s)
      Hisako Hashimoto, Yuto Odagiri, Yasuhiro Yamada, Nozomi Takagi, Shigeyoshi Sakaki, and Hiromi Tobita
    • Journal Title

      JOURNAL of THE AMERICAN CHEMICAL SOCIETY

      Volume: 137 Pages: 158-161

    • DOI

      10.1021/ja512336v

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Linking of phosphinidene-capped triruthenium carbonyl clusters with diphosphine ligands2015

    • Author(s)
      Taeko Kakizawa , Hisako Hashimoto, Hiromi Tobita
    • Journal Title

      Inorganica chimica acta

      Volume: 425 Pages: 7-10

    • DOI

      10.1016/j.ica.2014.09.003

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Reactions of a Tungsten-Germylyne Complex with α, β-Unsaturated Ketones : Complete Cleavage of the W=Ge Bond and Formation of Two Tvnes of η^3-Germoxyallyl Tungsten Complexes2014

    • Author(s)
      Tetsuya Fukuda, Hisako Hashimoto, Hiromi Tobita
    • Journal Title

      JOURNAL of THE AMERICAN CHEMICAL SOCIETY

      Volume: 136 Pages: 80-83

    • DOI

      10.1021/ja4109853

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Reactions of a Tungsten-Germylyne Complex with Alcohols and Aryla ldehvdes2013

    • Author(s)
      Tetsuya Fukuda, Hisako Hashimoto, Hiromi Tobita
    • Journal Title

      CHEMICAL COMMUNICATIONS

      Volume: 49 Pages: 4232-4234

    • DOI

      10.1039/c2cc37126j

    • Related Report
      2013 Annual Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrido(hydrosilylene)tungsten Complexes : Dynamic Behavior and Reactivity Toward Acetone2012

    • Author(s)
      Takahito Watanabe, Hisako Hashimoto, Hiromi Tobita
    • Journal Title

      Chemistry of Asian Journal

      Volume: (未定)(印刷中) Pages: 1408-1416

    • DOI

      10.1002/asia.201101058

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of a Germylyne Complex : Dehydrogenation of a Hydrido(hydrogermylene)tungsten Complex with Mesityl Isocyanate2012

    • Author(s)
      Hisako Hashimoto, Tetsuya Fukuda, Hiromi Tobita, Mausumi Ray, Sakaki Shigeyoshi
    • Journal Title

      Angew.Cbem.Int.Ed.

      Volume: 51 Pages: 2930-2933

    • DOI

      10.1002/anie.201107501

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reactions of a Neutral Silylene Ruthenium Complex with Heterocumulenes: C=O Hydrosilylation of Isocyanates vs C=S Bond Cleavage of Isothiocyanate2012

    • Author(s)
      M. Ochiai, H. Hashimoto, and H. Tobita
    • Journal Title

      Organometallics

      Volume: 31 Pages: 527-530

    • DOI

      10.1021/om2010854

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] カルベン錯体の高周期類縁体:新規シリレンおよびゲルミレン錯体の合成と不飽和有機化合物との反応2012

    • Author(s)
      橋本久子
    • Journal Title

      有機合成化学協会誌

      Volume: 70 Pages: 131-141

    • NAID

      10030481285

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] ケイ素上にEind基を有するタングステンシリリン錯体とアルデヒドおよびアルジミンとの反応2017

    • Author(s)
      ○吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] ヒドリド(シリレン)ルテニウム錯体を触媒とするアルデヒドまたはケトンとジヒドロシランとの反応2017

    • Author(s)
      ○野中寛之,橋本久子,飛田博実
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Reactions of Metal-Silicon Double and Triple Bonded Complexes with Unsaturated Organic Substrates2017

    • Author(s)
      ○Hisako Hashimoto, Takashi Yoshimoto, Hiroyuki Nonaka, Naoki Hayakawa, Tsukasa Matsuo, Hiromi Tobita,
    • Organizer
      The 2nd International Symposium on Stimuli-responsive Chemical Species for the Creation of Functional Molecule
    • Place of Presentation
      Hiroshima
    • Year and Date
      2017-03-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Reactions of an Iron-Germanium Double Bond Complex with Organic Substrates Having C=N, C≡N, C=O, and C=S Bonds2017

    • Author(s)
      ○Tara Prasad DHUNGANA,橋本久子,飛田博実
    • Organizer
      第10回6専攻合同シンポジウム
    • Place of Presentation
      仙台
    • Related Report
      2016 Annual Research Report
  • [Presentation] シリリン錯体とベンズアルデヒドの反応:W-Si-O-C四員環メタラサイクルの生成およびシラン酸エステルへの分解2016

    • Author(s)
      ○吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      第43回有機典型元素化学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2016-12-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] ヒドリド(ジアルキルシリレン)鉄錯体の合成,構造および不飽和有機分子との反応2016

    • Author(s)
      ○橋本久子,白岩礼士,飛田博実
    • Organizer
      第20回ケイ素化学協会シンポジウム
    • Place of Presentation
      広島
    • Year and Date
      2016-10-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] シリリンタングステン錯体とC=NおよびC=O二重結合を有する不飽和有機基質との反応2016

    • Author(s)
      ○吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      第20回ケイ素化学協会シンポジウム
    • Place of Presentation
      広島
    • Year and Date
      2016-10-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] 陽イオン性水素架橋ビス(シリレン)ロジウム錯体の合成とケトンおよびニトリルとの反応2016

    • Author(s)
      ○萩庭莞爾,橋本久子,飛田博実
    • Organizer
      第20回ケイ素化学協会シンポジウム
    • Place of Presentation
      広島
    • Year and Date
      2016-10-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fe-HおよびGe-H結合を持つゲルミレン鉄錯体と幾つかの不飽和有機化合物との反応2016

    • Author(s)
      ○DHUNGANA Tara Prasad,橋本久子,飛田博実
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Reactions of a Tungsten Silylyne Complex with Aldehydes: Formation of Dimers of Silanone via Formal Metathesis Reactions2016

    • Author(s)
      ○吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Silicon and Germanium Analogs of Carbyne Complexes: Synthesis, Structure, and Some Reactions2016

    • Author(s)
      ○ Hisako Hashimoto, Tetsuya Fukuda, Hiromi Tobita
    • Organizer
      International Symposium on Pure & Applied Chemistry (ISPAC) 2016
    • Place of Presentation
      Kuchin, Malaysia
    • Year and Date
      2016-08-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and structure of anionic η2-sila-aldehyde-tungsten complexes2016

    • Author(s)
      Tetsuya Fukuda,○ Hisako Hashimoto, Hiromi Tobita
    • Organizer
      27th International Conference on Organometallic Chemistry
    • Place of Presentation
      Melbourne, Australia
    • Year and Date
      2016-07-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Dimeric Tungsten Silylyne Complex: Its Dimer-Monomer Dissociation Equilibrium and Reactions with Unsaturated Organic Substrates2016

    • Author(s)
      ○吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      47th Silicon Symposium
    • Place of Presentation
      Portland,USA
    • Year and Date
      2016-06-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アニオン性シリレンタングステン錯体の酸素化反応:アニオン性η2-シラアルデヒド錯体の単離2016

    • Author(s)
      ○橋本 久子,福田 哲也,榊 茂好,飛田 博実
    • Organizer
      新学術研究領域「感応性化学種」第6回公開シンポジウム
    • Place of Presentation
      東広島
    • Year and Date
      2016-05-20
    • Related Report
      2016 Annual Research Report
  • [Presentation] 低原子価ケイ素化学種の配位化合物2016

    • Author(s)
      橋本久子
    • Organizer
      錯体化学若手の会東北支部勉強会
    • Place of Presentation
      仙台
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Isolation of anionic η2-sila-aldehyde-tungsten complexes2015

    • Author(s)
      福田哲也,○橋本久子,飛田博実
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM)
    • Place of Presentation
      Honolulu
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of a dimeric silylyne tungsten complex and its dissociation equilibrium with a monomer in solution2015

    • Author(s)
      ○吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM)
    • Place of Presentation
      Honolulu
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Formation of a Tungsten-silylyne Complex and its Monomer-dimer Dissociation Equilibrium in Solution2015

    • Author(s)
      ○吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      Stimulating Meeting for Young Researchers in Chemistry on Stimuli–responsive Chemical Species
    • Place of Presentation
      京都
    • Year and Date
      2015-11-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ヒドリド(ヒドロシリレン)錯体の段階的脱水素化反応によるシリリン錯体の合成およびその構造2015

    • Author(s)
      ○吉本崇志,福田哲也,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      第19回ケイ素化学協会シンポジウム
    • Place of Presentation
      滋賀
    • Year and Date
      2015-10-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] “Synthesis and Structures of hydrido(germylene) iron complexes and their reactivity toward unsaturated organic substrates2015

    • Author(s)
      ○Tara Prasad Dhungana,橋本久子,飛田博実
    • Organizer
      第65回錯体化学討論会
    • Place of Presentation
      奈良
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] 陽イオン性水素架橋ビス(シリレン)ロジウム錯体の合成と性質2015

    • Author(s)
      ○萩庭莞爾,橋本久子,飛田博実
    • Organizer
      第65回錯体化学討論会
    • Place of Presentation
      奈良
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] シリリンタングステン錯体二量体とカルボニル化合物との反応2015

    • Author(s)
      ○吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      第62回有機金属化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Formation of a Tungsten Complex Having a Metal-Silicon Triple Bond and Its Monomer-dimer Dissociation Equilibrium2015

    • Author(s)
      ○吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      Tohoku University’s Chemistry Summer School 2015
    • Place of Presentation
      仙台
    • Year and Date
      2015-08-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] Tungsten-Germanium/–Silicon Triple Bonded Complexes: Syntheses and Structures2015

    • Author(s)
      橋本久子
    • Organizer
      Golden Jubilee Chemistry Conference (GJCC)
    • Place of Presentation
      singapore
    • Year and Date
      2015-08-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] タングステン―ケイ素/ゲルマニウム三重結合錯体の合成とその性質2015

    • Author(s)
      橋本久子
    • Organizer
      第32回無機・分析化学コロキウム
    • Place of Presentation
      川渡
    • Year and Date
      2015-06-05
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] ケイ素上にEind基を有するシリリン錯体の合成およびその二量体との解離平衡2015

    • Author(s)
      ○吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      第32回無機・分析化学コロキウム
    • Place of Presentation
      川渡
    • Year and Date
      2015-06-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] タングステン-ゲルマニウム/ケイ素三重結合錯体の新規合成2015

    • Author(s)
      ○橋本久子・福田哲也・吉本崇志・早川直輝・松尾司・飛田博実
    • Organizer
      新学術領域研究「感応性化学種」第4 回公開シンポジウム
    • Place of Presentation
      宇治
    • Year and Date
      2015-05-22
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 遷移金属―ケイ素/ゲルマニウム多重結合錯体の創製とその特異な性質2015

    • Author(s)
      橋本久子
    • Organizer
      京都大学化学研究所元素科学国際研究センター講演会
    • Place of Presentation
      宇治
    • Year and Date
      2015-01-23
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Reactivity of a Tungsten-Germanium Triple-Bond Complex toward Some Organic Substrates2014

    • Author(s)
      福田哲也,橋本久子,飛田博実
    • Organizer
      The 16th Japan-Korea Joint Symposium on Organometallic and Coordination Chemistry
    • Place of Presentation
      仙台
    • Year and Date
      2014-10-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] アニオン性η2-シラアルデヒド-タングステン錯体の合成と構造2014

    • Author(s)
      福田哲也,橋本久子,飛田博実
    • Organizer
      第61回有機金属化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] ケイ素上に嵩高いEind基を有する五員環状シリレンタングステン錯体の合成,構造および性質2014

    • Author(s)
      吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      第64回錯体化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis and Reactivity of Hydrido(dialkylsilylene) Ruthenium Complexes: Formation of the first η3-2-Aza-1-silaallyl Complex by the Reaction with Arylnitrile2014

    • Author(s)
      橋本久子,西村公彰,飛田博実
    • Organizer
      The 17th International Symposium on Silicon Chemistry (ISOS2014)
    • Place of Presentation
      ベルリン(ドイツ)
    • Year and Date
      2014-08-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis and Structures of Base-Stabilized Hydrosilylyne Tungsten Complexes2014

    • Author(s)
      福田哲也,橋本久子,飛田博実
    • Organizer
      The 17th International Symposium on Silicon Chemistry (ISOS2014)
    • Place of Presentation
      ベルリン(ドイツ)
    • Year and Date
      2014-08-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Reactions of a Tungsten Germylene Complex with N-Heterocyclic Carbenes: Formation of an Anionic Germylene Complex and a W-Ge-W-Ge Four-Membered-Ring Complex2014

    • Author(s)
      福田哲也,橋本久子,飛田博実
    • Organizer
      41th International Conference on Coordination Chemistry (ICCC41)
    • Place of Presentation
      シンガポール(シンガポール)
    • Year and Date
      2014-07-23
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Structure of the First η2,η2-Disilyne-Bridged Dinuclear Complex2014

    • Author(s)
      橋本久子,鳴島佳佑,加藤聡,福田哲也,飛田博実
    • Organizer
      XXVI International Conference on Organometallic Chemistry (ICOMC2014)
    • Place of Presentation
      札幌
    • Year and Date
      2014-07-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] タングステンゲルミリン錯体とα,β-不飽和カルボニル化合物との反応:二重[2+4]環化付加とW-Ge三重結合の可逆的切断2014

    • Author(s)
      橋本久子,福田哲也,飛田博実
    • Organizer
      新学術領域研究「感応性化学種が拓く新物質科学」第3回公開シンポジウム
    • Place of Presentation
      つくば
    • Year and Date
      2014-06-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] 立体的に保護された金属-ケイ素二重結合を持つ錯体の合成と反応性2014

    • Author(s)
      吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      東北大学第7回6専攻合同シンポジウム
    • Place of Presentation
      仙台
    • Related Report
      2013 Annual Research Report
  • [Presentation] Eind基をケイ素上に持つヒドリド(ヒドロシリレン)タングステン錯体の合成およびカルボジイミドとの反応2014

    • Author(s)
      吉本崇志,橋本久子,早川直輝,松尾司,飛田博実
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] Reactivity of a Germylyne Tungsten Complex toward Alcohols and Aldehydes2013

    • Author(s)
      Hisako Hashimoto
    • Organizer
      The 1st International Symposium on Stimuli-responsive Chemical Species for the Creation of Functional Molecules
    • Place of Presentation
      広島
    • Year and Date
      2013-03-26
    • Related Report
      2012 Annual Research Report
  • [Presentation] 水素架橋ビス(シリレン)錯体:新しい金属-ケイ素-水素結合の構築とその特異性2013

    • Author(s)
      飛田博実
    • Organizer
      第30回無機・分析化学コロキウム
    • Place of Presentation
      川渡,宮城県
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 水素架橋ビス(シリレン)錯体の特異な性質:動的挙動に関する理論的研究および反応性2013

    • Author(s)
      橋本久子、小田桐悠斗、松尾 里美、小村克斗、飛田博実、高木望、榊 茂好
    • Organizer
      新学術領域「感応性化学種が拓く新物質化学」第2回公開シンポジウム
    • Place of Presentation
      福岡
    • Related Report
      2013 Annual Research Report
  • [Presentation] Formation of a Germylyne Tungsten Complex and Its Reactions with Some Organic Substrates2013

    • Author(s)
      Hisako Hashimoto,, Tetsuya Fukuda, Hiromi Topbita
    • Organizer
      The 14th International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (GTL 2013)
    • Place of Presentation
      Baddeck,Canada
    • Related Report
      2013 Annual Research Report
  • [Presentation] タングステン-シリレンおよびゲルミレン錯体とN-ヘテロサイクリックカルベンとの反応:塩基安定化ヒドロシリリン錯体およびW-Ge-W-Ge四員環骨格を持つゲルミレン錯体の生成2013

    • Author(s)
      福田哲也,橋本久子,飛田博実
    • Organizer
      第60回有機金属化学討論会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水素架橋ビス(シリレン)ルテニウムおよび鉄錯体の合成と性質2013

    • Author(s)
      小村克斗,橋本久子,飛田博実
    • Organizer
      第60回有機金属化学討論会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] Reactions of a Tungsten-Germylyne Complex with Alcohols, Aldehydes, and α,β-Unsaturated Carbonyl Compounds2013

    • Author(s)
      福田哲也,橋本久子,飛田博実
    • Organizer
      平成25年度化学系学協会東北大会及び日本化学会東北支部70周年記念国際会議
    • Place of Presentation
      仙台
    • Related Report
      2013 Annual Research Report
  • [Presentation] Reactions of a Hydrogen-Bridged Bis(silylene) Tungsten Complex with Several Polar Organic Substrates2013

    • Author(s)
      小村克斗,橋本久子,飛田博実
    • Organizer
      平成25年度化学系学協会東北大会及び日本化学会東北支部70周年記念国際会議
    • Place of Presentation
      仙台
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis and Reactivity of Hydrido (silylene) Ruthenium Complexes: Formation of Novel η3-2-Aza-1-Silaallyl Complexes in their Reactions with Arylnitriles2013

    • Author(s)
      西村公彰,橋本久子,飛田博実
    • Organizer
      平成25年度化学系学協会東北大会及び日本化学会東北支部70周年記念国際会議
    • Place of Presentation
      仙台
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水素架橋ビス(シリレン)タングステン錯体の特異な性質および様々な有機基質との反応2013

    • Author(s)
      橋本久子,小村克斗,松尾里美,小田桐悠斗,飛田博実
    • Organizer
      第17回ケイ素化学協会シンポジウム
    • Place of Presentation
      箱根
    • Related Report
      2013 Annual Research Report
  • [Presentation] ヒドリド(ヒドロゲルミレン)タングステン錯体と幾つかのN-ヘテロ環式カルベンとの反応2013

    • Author(s)
      福田哲也,橋本久子,飛田博実
    • Organizer
      第17回ケイ素化学協会シンポジウム
    • Place of Presentation
      箱根
    • Related Report
      2013 Annual Research Report
  • [Presentation] 多様な性質を示す遷移金属―高周期14族元素多重結合錯体2013

    • Author(s)
      橋本久子
    • Organizer
      第2回触媒化学融合研究センター講演会
    • Place of Presentation
      筑波
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 鉄およびルテニウムの水素架橋ビス(シリレン)錯体の反応性2013

    • Author(s)
      小村克斗,橋本久子,石崎隆敏,飛田博実
    • Organizer
      第63回錯体化学討論会
    • Place of Presentation
      沖縄
    • Related Report
      2013 Annual Research Report
  • [Presentation] 反応活性なシリレンおよびゲルミレン錯体2012

    • Author(s)
      橋本久子
    • Organizer
      大阪府立大学 第37応用化学セミナー
    • Place of Presentation
      大阪
    • Year and Date
      2012-12-21
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Peculiar Reactivity of a Neutral Tungsten Germylene Complex2012

    • Author(s)
      Hisako Hashimoto
    • Organizer
      The 4th Asian Silicon Symposium (A-SiS-4)
    • Place of Presentation
      つくば
    • Year and Date
      2012-10-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] 感応性高周期元素-遷移金属多重結合を有する金属錯体の創製と触媒機能2012

    • Author(s)
      橋本久子
    • Organizer
      新学術領域研究「感応性化学種が拓く新物質科学」第1回公開シンポジウム
    • Place of Presentation
      宇治
    • Year and Date
      2012-09-29
    • Related Report
      2012 Annual Research Report
  • [Book] Chapter 21, “Tungsten- and ruthenium-silylene complexes,” in “Efficient Methods for Preparing Silicon Compounds,”ed by Herbert W. Roesky2016

    • Author(s)
      Hisako Hashimoto
    • Total Pages
      8
    • Publisher
      Elsevier
    • Related Report
      2016 Annual Research Report
  • [Book] 「ケイ素遷移金属錯体」,“現代ケイ素化学:体系的な基礎概念と応用に向けて” 吉良満夫・玉尾晧平編,第14章2013

    • Author(s)
      飛田博実,橋本久子
    • Publisher
      化学同人
    • Related Report
      2013 Annual Research Report
  • [Remarks] 東北大学大学院理学研究科化学専攻 無機化学研究室

    • URL

      http://inorg.chem.tohoku.ac.jp/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 無機化学研究室

    • URL

      http://inorg.chem.tohoku.ac.jp/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 東北大学理学研究科化学専攻無機化学研究室

    • URL

      http://inorg.chem.tohoku.ac.jp/

    • Related Report
      2014 Annual Research Report
  • [Remarks] 無機化学研究室ホームページ

    • URL

      http://inorg.chem.tohoku.ac.jp/

    • Related Report
      2013 Annual Research Report

URL: 

Published: 2012-11-27   Modified: 2019-07-29  

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