• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Controle of self-assembly in artificial systems based on precise design of moleular surfaces

Planned Research

Project AreaDynamical ordering of biomolecular systems for creation of integrated functions
Project/Area Number 25102005
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionThe University of Tokyo

Principal Investigator

Hiraoka Shuichi  東京大学, 大学院総合文化研究科, 教授 (10322538)

Project Period (FY) 2013-06-28 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥98,930,000 (Direct Cost: ¥76,100,000、Indirect Cost: ¥22,830,000)
Fiscal Year 2017: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2016: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2015: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2014: ¥25,870,000 (Direct Cost: ¥19,900,000、Indirect Cost: ¥5,970,000)
Fiscal Year 2013: ¥50,440,000 (Direct Cost: ¥38,800,000、Indirect Cost: ¥11,640,000)
Keywords分子自己集合 / van der Waals力 / 疎水効果 / 分子認識 / 超分子化学 / 自己組織化 / 自己集合 / 分子間相互作用
Outline of Final Research Achievements

We carried out two unresolved issues in molecular self-assembly: (1) establishing design principle of “molecular hozo” for the construction of discrete self-assemblies only using very weak, non-directional intermolecular interactions (van der Waals and cation-pai interactions) and the hydrophobic effect in water and (2) revealing molecular self-assembly process by a novel method (QASAP), which was developed by us. In the first project, we designed gear-shaped amphiphiles, developed a novel method to synthesize C2v symmetric hexaphenylbenzene derivatives, and succeeded in developing a cubic assembly “nanocube” that is stable at 130 °C in water. In the second project, self-assembly processes of 14 coordination assemblies were revealed by QASAP, which shows several features in molecular self-assembly. Besides, chiral self-sorting processes where enantiomers are spontaneously sorted into homochiral assemblies were revealed by QASAP.

Report

(6 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report

Research Products

(112 results)

All 2018 2017 2016 2015 2014 2013 Other

All Int'l Joint Research (6 results) Journal Article (25 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 25 results,  Open Access: 3 results,  Acknowledgement Compliant: 1 results) Presentation (71 results) (of which Int'l Joint Research: 9 results,  Invited: 15 results) Book (1 results) Remarks (7 results) Patent(Industrial Property Rights) (1 results) Funded Workshop (1 results)

  • [Int'l Joint Research] University of Leed/University of Edinburgh(英国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] National Taiwan University(Taiwan)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] School of Chemistry/University of Leeds(英国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] School of Chemistry/University of St Andrews(英国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] School of Chemistry/University of Edinburgh(英国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Department of Chemistry/National Taiwan University(Taiwan)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Unresolved Issues that Remain in Molecular Self-Assembly2018

    • Author(s)
      Hiraoka Shuichi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 91 Issue: 6 Pages: 957-978

    • DOI

      10.1246/bcsj.20180008

    • NAID

      130007396844

    • ISSN
      0009-2673, 1348-0634
    • Year and Date
      2018-06-15
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembly Process of a Pd2L4 Capsule: Steric Interactions between Neighboring Components Favor the Formation of Large Intermediates2018

    • Author(s)
      Kai Shumpei、Nakagawa Masanori、Kojima Tatsuo、Li Xin、Yamashina Masahiro、Yoshizawa Michito、Hiraoka Shuichi
    • Journal Title

      Chemistry - A European Journal

      Volume: 24 Issue: 16 Pages: 3965-3969

    • DOI

      10.1002/chem.201705253

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembly of a Pd4L8 Double-Walled Square Partly Takes Place Through the Formation of Kinetically Trapped Species2018

    • Author(s)
      Tateishi Tomoki、Zhu Wenchao、Foianesi-Takeshige Leonardo Hayato、Kojima Tatsuo、Ogata Kazuho、Hiraoka Shuichi
    • Journal Title

      European Journal of Inorganic Chemistry

      Volume: 2018 Issue: 10 Pages: 1192-1197

    • DOI

      10.1002/ejic.201800037

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Effects on the Final Step of an Octahedron-shaped Coordination Capsule Self-assembly2018

    • Author(s)
      Y. Matsumura, S. Iuchi, S. Hiraoka, *H. Sato
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 20 Issue: 11 Pages: 7383-7386

    • DOI

      10.1039/c7cp08237a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multiple Pathways in the Self-Assembly Process of a Pd4L8 Coordination Tetrahedron2018

    • Author(s)
      Tateishi Tomoki、Kojima Tatsuo、Hiraoka Shuichi
    • Journal Title

      Inorganic Chemistry

      Volume: 57 Issue: 5 Pages: 2686-2694

    • DOI

      10.1021/acs.inorgchem.7b03085

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hyperthermostable cube-shaped assembly in water2018

    • Author(s)
      Zhan Yi-Yang、Ogata Kazuho、Kojima Tatsuo、Koide Takuya、Ishii Kentaro、Mashiko Takako、Tachikawa Masanori、Uchiyama Susumu、Hiraoka Shuichi
    • Journal Title

      Communications Chemistry

      Volume: 1 Issue: 1 Pages: 14-14

    • DOI

      10.1038/s42004-018-0014-2

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Flexibility of Components Alters the Self-assembly Pathway of Pd2L4 Coordination Cages2018

    • Author(s)
      S. Kai, S. P. Maddala, T. Kojima, S. Akagi, K. Harano, E. Nakamura, S. Hiraoka,
    • Journal Title

      Dalton Transactions

      Volume: 47 Issue: 10 Pages: 3258-3263

    • DOI

      10.1039/c8dt00112j

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Semi-quantitative evaluation of molecular meshing via surface analysis with varying probe radii2018

    • Author(s)
      Tanaka Naru、Zhan Yi-Yang、Ozawa Yuka、Kojima Tatsuo、Koide Takuya、Mashiko Takako、Nagashima Umpei、Tachikawa Masanori、Hiraoka Shuichi
    • Journal Title

      Chemical Communications

      Volume: 54 Issue: 27 Pages: 3335-3338

    • DOI

      10.1039/c8cc00695d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Programed dynamical ordering in self-organization processes of a nanocube: a molecular dynamics study2018

    • Author(s)
      Harada Ryuhei、Mashiko Takako、Tachikawa Masanori、Hiraoka Shuichi、Shigeta Yasuteru
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Issue: 14 Pages: 9115-9122

    • DOI

      10.1039/c8cp00284c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral self-sorting process in the self-assembly of homochiral coordination cages from axially chiral ligands2018

    • Author(s)
      Tateishi Tomoki、Kojima Tatsuo、Hiraoka Shuichi
    • Journal Title

      Communications Chemistry

      Volume: 1 Issue: 1 Pages: 20-20

    • DOI

      10.1038/s42004-018-0020-4

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Theoretical Study on Substituent and Solvent Effectsfor Nanocubes Formed with Gear-shaped Amphiphile Molecules2018

    • Author(s)
      増子 貴子、平岡 秀一、長嶋 雲兵、立川 仁典
    • Journal Title

      Journal of Computer Chemistry, Japan

      Volume: 17 Issue: 1 Pages: 31-37

    • DOI

      10.2477/jccj.2018-0010

    • NAID

      130006528560

    • ISSN
      1347-1767, 1347-3824
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] How Does Chiral Self-sorting Take Place in the Formation of Homochiral Pd6L8 Capsules Consisting of Cyclotriveratrylene-based Chiral Tritopic Ligands?2018

    • Author(s)
      S. Kai, T. Kojima, F. L. Thorp-Greenwood, M. J. Hardie, *S. Hiraoka
    • Journal Title

      Chem. Sci.

      Volume: - Issue: 17 Pages: 4104-4108

    • DOI

      10.1039/c8sc01062e

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Importance of Molecular Meshing for the Stabilization of Solvophobic Assemblies2018

    • Author(s)
      Zhan Yi-Yang、Tanaka Naru、Ozawa Yuka、Kojima Tatsuo、Mashiko Takako、Nagashima Umpei、Tachikawa Masanori、Hiraoka Shuichi
    • Journal Title

      The Journal of Organic Chemistry

      Volume: - Issue: 9 Pages: 5132-5137

    • DOI

      10.1021/acs.joc.8b00495

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Balance Between van der Waals and Cation-π Interactions That Stabilizes Hydrophobic Assemblies2018

    • Author(s)
      Zhan Yi-Yan、Kojima Tatsuo、Koide Takuya、Tachikawa Masanori、Hiraoka Shuichi
    • Journal Title

      Chemistry - A European Journal

      Volume: - Issue: 36 Pages: 9130-9135

    • DOI

      10.1002/chem.201801376

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Energy‐Landscape‐Independent Kinetic Trap of Incomplete Cage in the Self‐assembly of a Pd2L4 Cage2018

    • Author(s)
      Nakagawa Masanori、Kai Shumpei、Kojima Tatsuo、Hiraoka Shuichi
    • Journal Title

      Chemistry - A European Journal

      Volume: 印刷中 Issue: 35 Pages: 8804-8808

    • DOI

      10.1002/chem.201801183

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Homochiral self-sorted and emissive IrIII metallo-cryptophanes2017

    • Author(s)
      V. E. Pritchard, D. R. Martir, S. Oldknow, S. Kai, S. Hiraoka, N. J. Cookson, E. Zysman-Colman, M. J. Hardie.
    • Journal Title

      Chem. Eur. J.

      Volume: 23 Issue: 26 Pages: 6290-6294

    • DOI

      10.1002/chem.201701348

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A reaction model on the self-assembly process of octahedron-shaped coordination capsules2017

    • Author(s)
      Matsumura Yoshihiro、Hiraoka Shuichi、Sato Hirofumi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 31 Pages: 20338-20342

    • DOI

      10.1039/c7cp03493h

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Effect of Solvent and Coordination Environment of Metal Source on the Self-Assembly Pathway of a Pd(II)-Mediated Coordination Capsule2017

    • Author(s)
      Kai Shumpei、Sakuma Yui、Mashiko Takako、Kojima Tatsuo、Tachikawa Masanori、Hiraoka Shuichi
    • Journal Title

      Inorganic Chemistry

      Volume: 56 Issue: 20 Pages: 12652-12663

    • DOI

      10.1021/acs.inorgchem.7b02152

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantitative Analysis of the Self-Assembly Process of a Pd12L24 Coordination Sphere2017

    • Author(s)
      Kai Shumpei、Shigeta Taro、Kojima Tatsuo、Hiraoka Shuichi
    • Journal Title

      Chem Asian J.

      Volume: 12 Issue: 24 Pages: 3203-3207

    • DOI

      10.1002/asia.201701351

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantitative Analysis of Self-Assembly Process of a Pd2L4 Cage Consisting of Rigid Ditopic Ligands2017

    • Author(s)
      Kai Shumpei、Mart?-Centelles Vicente、Sakuma Yui、Mashiko Takako、Kojima Tatsuo、Nagashima Umpei、Tachikawa Masanori、Lusby Paul J.、Hiraoka Shuichi
    • Journal Title

      Chemistry - A European Journal

      Volume: 24 Issue: 3 Pages: 663-671

    • DOI

      10.1002/chem.201704285

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Quantitative Analysis of the Self-Assembly Process of Hexagonal PtII Macrocyclic Complexes: Effect of the Solvent and the Components2017

    • Author(s)
      Baba Ayako、Kojima Tatsuo、Hiraoka Shuichi
    • Journal Title

      Chem. Eur. J., in press

      Volume: 24 Issue: 4 Pages: 838-847

    • DOI

      10.1002/chem.201702955

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical study on substituent and solvent effects for nanocube formed with gear-shaped amphiphile molecules2017

    • Author(s)
      T. Mashiko, S. Hiraoka, U, Nagashima, and M. Tachikawa,
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 2 Pages: 191627-1631

    • DOI

      10.1039/c6cp07754d

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Self-Assembly Process of Dodecanuclear Pt(II)-Linked Cyclic Hexagon2015

    • Author(s)
      A. Baba, T. Kojiam,S. Hiraoka
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 137 Issue: 24 Pages: 7664-7667

    • DOI

      10.1021/jacs.5b04852

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Dynamics and Principal Component Analysis for a Self-assembled Nanocube in Aqueous Solution2014

    • Author(s)
      T. Mashiko, K. Yamada, T. Kojima, S. Hiraoka, U. Nagashima, and M. Tachikawa
    • Journal Title

      Chemistry Letters

      Volume: 43 Issue: 3 Pages: 366-368

    • DOI

      10.1246/cl.130928

    • NAID

      130004868001

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Alternate Derivatization of the Hexaphenylbenzene Framework through a Thermodynamically Controlled Halogen Dance2014

    • Author(s)
      T. Kojima and S. Hiraoka
    • Journal Title

      Org. Lett.

      Volume: 16 Issue: 3 Pages: 1024-1027

    • DOI

      10.1021/ol500041j

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] How does coordination self-assembly take place?2018

    • Author(s)
      Shuichi Hiraoka
    • Organizer
      New Frontiers of Supramolecular Chemistry in Non-equilibrium Systems
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Ultra-Thermostable Cube-Shaped Assembly in Water2018

    • Author(s)
      Shuichi Hiraoka
    • Organizer
      新学術第6回国際シンポジウム
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Coordination Self-Assembly Process by QASAP2018

    • Author(s)
      Shuichi Hiraoka
    • Organizer
      新学術第6回国際シンポジウム
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Self-assembly process of a Pd(II) tetrahedron and the conversion pathway from a major intermediate2018

    • Author(s)
      TATEISHI, Tomoki; KOJIMA, Tatsuo; HIRAOKA, Shuichi
    • Organizer
      新学術第6回国際シンポジウム
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 自己集合過程の解明と平衡に支配されない自己集合2018

    • Author(s)
      平岡 秀一
    • Organizer
      日本化学会 第98春季年会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 軸不斉を有する配位子からなるPd2L4カゴ型錯体の自己集合過程およびキラルSelf-Sorting過程2018

    • Author(s)
      立石友紀、小島達央、平岡秀一
    • Organizer
      日本化学会 第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Counter anion of metal source alters the self-assembly mechanism of Pd2L4 coordination cages2018

    • Author(s)
      TAKESHIGE, Leonardo Hayato; ZHU, Wenchao; TATEISHI, Tomoki; KOJIMA, Tatsuo; KAI, Shumpei; AKAGI, Shota; HIRAOKA, Shuichi
    • Organizer
      日本化学会 第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Self-assembly of a Pd4L8 Double-walled Square Partly Takes Place through the Formation of Kinetically Trapped Species2018

    • Author(s)
      ZHU, Wenchao; TAKESHIGE, Leonardo Hayato; KOJIMA, Tatsuo; HIRAOKA, Shuichi,
    • Organizer
      日本化学会 第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Control of Kinetic Stability of Nanocubes Assembled by Hydrophobic Effect2018

    • Author(s)
      ZHAN, Yiyang, ISHII, Kentaro; KOJIMA, Tatsuo; SHOJI, Yoshiaki; HAKETA, Yohei; UCHIYAMA, Susumu; MAEDA, Hiromitsu; FUKUSHIMA, Takanori; HIRAOKA, Shuichi
    • Organizer
      日本化学会 第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Self-assembly Process of a Pd12L24 Sphere Complex2017

    • Author(s)
      KAI, Shumpei; SHIGETA, Taro; KOJIMA, Tatsuo; HIRAOKA, Shuichi
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 超耐熱性自己集合体の秩序形成2017

    • Author(s)
      平岡秀一
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 主要中間体の同定、単離、および反応性に基づくPd4L8 四面体型錯体の自己集合過程2017

    • Author(s)
      立石 友紀・小島 達央・平岡 秀一
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] U字型二座配位子からなるPd2L4かご型錯体の自己集合過程:準安定中間種の単離・同定・反応2017

    • Author(s)
      中川真徳・小島 達央・平岡 秀一
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Artificial synthetic monodispersed aggregate with highest decomposition temperature over 150 °C in water2017

    • Author(s)
      Yiyan Zhan, Tatsuo Kojima, Shuichi Hiraoka
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Self-assembly Process of a Pd2L4 Capsule Complex with a Ditopic Ligand Bearing Anthracene Panels2017

    • Author(s)
      KAI, Shumpei; NAKAGAWA, Masanori; LI, Xin; YAMASHINA, Masahiro; KOJIMA, Tatsuo; YOSHIZAWA, Michito; HIRAOKA, Shuichi
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Self-Assembly Process of Pd2L4 Cage Complex Consisiting of U-Shaped Ditopic Ligand2017

    • Author(s)
      Masanori Nakagawa, Kojima Tatsuo, Shuichi Hiraoka
    • Organizer
      The 5th International Symposium on Dynamical Ordering of Biomolecular Systems for Creation of Integrated Functions
    • Place of Presentation
      東京大学駒場キャンパス(東京都・目黒区)
    • Year and Date
      2017-01-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Self-Assembly Process of Tetrahedron-shaped Pd(II) Complex2017

    • Author(s)
      Tomoki Tateishi, Tatsuo Kojima, Shuichi Hiraoka
    • Organizer
      The 5th International Symposium on Dynamical Ordering of Biomolecular Systems for Creation of Integrated Functions
    • Place of Presentation
      東京大学駒場キャンパス(東京都・目黒区)
    • Year and Date
      2017-01-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The highest Thermostable Monodispersed Aggregate Through Molecular Engagement in Water2017

    • Author(s)
      Yiyang Zhan, Tatsuo Kojima, Hiraoka Shuichi
    • Organizer
      The 5th International Symposium on Dynamical Ordering of Biomolecular Systems for Creation of Integrated Functions
    • Place of Presentation
      東京大学駒場キャンパス(東京都・目黒区)
    • Year and Date
      2017-01-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanocube: Ultra-Thermostable Self-Assemblies in Water2017

    • Author(s)
      Shuichi Hiraoka
    • Organizer
      Frontier Bioorganization Forum 2017: Dynamical ordering and integrated functions of biomolecular systems
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 疎水効果を駆動力とした、超熱耐性自己集合体の創製2017

    • Author(s)
      Zhan Yiyang, Tatsuo Kojima, Shuichi Hiraoka
    • Organizer
      第15回ホスト-ゲスト・超分子化学シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Pd4L8 四面体型錯体の自己集合メカニズム: 主要中間体の同定・単離・反応性2017

    • Author(s)
      立石友紀、小島達央、平岡秀一
    • Organizer
      第15回ホスト-ゲスト・超分子化学シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Nanocube: Ultra-thermostable Self-assemblies In Water2017

    • Author(s)
      Shuichi Hiraoka
    • Organizer
      International Symposium on Pure & Applied Chemistry 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Kinetic stability and encapsulation behavior of ultra-thermostable self-assembly2017

    • Author(s)
      Zhan Yiyang, Tatsuo Kojima, Shuichi Hiraoka
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 光学活性な配位子からなるPd(II)カゴ型錯体の自己集合およびキラルソーティングのメカニズム2017

    • Author(s)
      立石友紀、小島達央、平岡秀一
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Coordination Self-Assembly Process and a Novel Method for the Formation of Coordination Self-Assemblies under Kinetic Control2017

    • Author(s)
      Shuichi Hiraoka
    • Organizer
      錯体化学会 第67回討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] キラリティーを有するPd2L4カゴ型錯体の自己集合/キラルソーティング過程2017

    • Author(s)
      立石友紀、小島達央、平岡秀一
    • Organizer
      錯体化学会 第67回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Pd(II)四面体型錯体の自己集合過程とその主要中間体からの変換経路の解明2017

    • Author(s)
      立石友紀、小島達央、平岡秀一
    • Organizer
      第7回CSJ化学フェスタ
    • Related Report
      2017 Annual Research Report
  • [Presentation] Pd4L8四面体型錯体の自己集合プロセス2016

    • Author(s)
      立石友紀・小島達央・平岡秀一
    • Organizer
      錯体化学会第66回討論会
    • Place of Presentation
      福岡大学七隈キャンパス(福岡県・福岡市)
    • Year and Date
      2016-10-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] 四面体型 Pd(II)錯体の自己集合過程2016

    • Author(s)
      立石友紀・小島達央・平岡秀一
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島国際会議場(広島県・広島市)
    • Year and Date
      2016-09-01
    • Related Report
      2016 Annual Research Report
  • [Presentation] U 字型配位子からなる Pd2L4かご型錯体の自己集合過程:準安定中間種の単離・同定・反応2016

    • Author(s)
      中川真徳・小島達央・平岡秀一
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島国際会議場(広島県・広島市)
    • Year and Date
      2016-09-01
    • Related Report
      2016 Annual Research Report
  • [Presentation] Self-Assembly Process of Coordination Rings, Cages, and Capsules2016

    • Author(s)
      Shuichi Hiraoka
    • Organizer
      International Symposium on Polymer and Related Materials
    • Place of Presentation
      ハルビン工程大学(Halbin, China)
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 超分子錯体の自己組織化機構2016

    • Author(s)
      平岡秀一
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 六角形型Pt(II)環状錯体の自己集合過程:(1)実験的アプローチ2016

    • Author(s)
      馬場絢子、小島達央、平岡秀一
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] V字型二座配位子からなるPd2L4かご型錯体の自己集合過程2016

    • Author(s)
      甲斐詢平、小島達央、平岡秀一
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] U字型二座配位子からなるPd2L4かご型錯体の自己集合過程2016

    • Author(s)
      中川真徳、小島達央、平岡秀一
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 自己集合錯体の自己集合における単核Pd(II)錯体中の脱離配位子の効果2016

    • Author(s)
      甲斐詢平、増崎大悟、重田太郎、小島達央、平岡秀一
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] The Extremely High Thermal Stability of Water Soluble Nanocube based on Gear- Shaped Amphiphiles2016

    • Author(s)
      ZHAN Yiyang, KOJIMA Tatsuo, HIRAOKA, Shuichi
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Pd4L8ダブルウォールドスクエア型錯体の自己集合過程2016

    • Author(s)
      甲斐詢平、重田太郎、小島達央、平岡秀一
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Pd4L8四面体型錯体の自己集合過程2016

    • Author(s)
      立石友紀、小島達央、平岡秀一
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Self-assembly Process of Coordination Capsules and Cages2016

    • Author(s)
      Shuichi Hiraoka
    • Organizer
      The 9th Japan-China Joint Symposium on Functional Supramolecular Architectures
    • Place of Presentation
      分子化学研究所岡崎コンファレンスセンター(愛知県岡崎市)
    • Year and Date
      2016-02-24
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] The self-assembly Mechanism of Pd2L4 Coordination cages2016

    • Author(s)
      Shumpei Kai, Tatsuo Kojima, Shuichi Hiraoka
    • Organizer
      The 9th Japan-China Joint Symposium on Functional Supramolecular Architectures
    • Place of Presentation
      分子化学研究所岡崎コンファレンスセンター(愛知県岡崎市)
    • Year and Date
      2016-02-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Self-assembly Mechanism of Pt(II)-linked Coordination Macrocycles2016

    • Author(s)
      Ayako Baba, Tatsuo Kojima, Shuichi Hiraoka
    • Organizer
      The 9th Japan-China Joint Symposium on Functional Supramolecular Architectures
    • Place of Presentation
      分子化学研究所岡崎コンファレンスセンター(愛知県岡崎市)
    • Year and Date
      2016-02-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Self-assembly Process of Pd2L4 Cage Complex Constructed from U-shaped Rigid Ditopic Ligand2016

    • Author(s)
      Masanori Nakagawa, Tatsuo Kojima, Shuichi Hiraoka
    • Organizer
      The 9th Japan-China Joint Symposium on Functional Supramolecular Architectures
    • Place of Presentation
      分子化学研究所岡崎コンファレンスセンター(愛知県岡崎市)
    • Year and Date
      2016-02-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] The self-assembly process of Pd2L4 coordination cages2015

    • Author(s)
      Shumpei Kai, Tatsuo Kojima, Shuichi Hiraoka
    • Organizer
      4th International Symposium on Dynamical Ordering of Biomolecular Systems for Creation of Integrated Functions
    • Place of Presentation
      九州大学西新プラザ(福岡県博多市)
    • Year and Date
      2015-11-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] Self-assembly process of coordination macrocycles2015

    • Author(s)
      Ayako Baba, Tatsuo Kojima, Shuichi Hiraoka
    • Organizer
      4th International Symposium on Dynamical Ordering of Biomolecular Systems for Creation of Integrated Functions
    • Place of Presentation
      九州大学西新プラザ(福岡県博多市)
    • Year and Date
      2015-11-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] The effect of substituted groups on the stability of nanocube consisting of gear-shaped amphiphiles2015

    • Author(s)
      Kazuho Ogata, Tatsuo Kojima, Shuichi Hiraoka
    • Organizer
      4th International Symposium on Dynamical Ordering of Biomolecular Systems for Creation of Integrated Functions
    • Place of Presentation
      九州大学西新プラザ(福岡県博多市)
    • Year and Date
      2015-11-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] The importance of triple-π interaction and Van der Waals interaction for the thermal stability of nanocube based on gear-shaped amphiphiles2015

    • Author(s)
      Yiyang Zhan, Tatsuo Kojima, Shuichi Hiraoka
    • Organizer
      4th International Symposium on Dynamical Ordering of Biomolecular Systems for Creation of Integrated Functions
    • Place of Presentation
      九州大学西新プラザ(福岡県博多市)
    • Year and Date
      2015-11-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] Self-Assembly Process of Coordination Cages and Capsules2015

    • Author(s)
      Shuichi Hiraoka
    • Organizer
      3rd Workshop of Center for Instrumental Analysis, Frontier of Instrumental Analysis using Magnetic Resonance Spectroscopy
    • Place of Presentation
      新潟大学(新潟県新潟市)
    • Year and Date
      2015-10-30
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] メカニズム指向の自己組織化に挑戦! ~自己集合性金属錯体の形成機構の解明~2015

    • Author(s)
      平岡秀一
    • Organizer
      第5回CSJ化学フェスタ2015
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] ナノキューブ:水中における自己組織化と驚異的熱安定性2015

    • Author(s)
      平岡秀一
    • Organizer
      「動的秩序と機能」若手研究会
    • Place of Presentation
      愛知県西浦温泉ホテルたつき(愛知県蒲郡市)
    • Year and Date
      2015-10-05
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] エーテル結合で連結されたピリジル基を有する二座配位子からなるPd2L4型かご型錯体の自己集合過程2015

    • Author(s)
      甲斐詢平,小島達央,平岡秀一
    • Organizer
      26回基礎有機化学討論会
    • Place of Presentation
      愛媛大学(愛媛県松山市)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 六角形型Pt(II)環状自己組織化体の形成機構2015

    • Author(s)
      馬場絢子,小島達央,平岡秀一
    • Organizer
      26回基礎有機化学討論会
    • Place of Presentation
      愛媛大学(愛媛県松山市)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 剛直なU字型二座配位子からなるPd2L4型かご型錯体の自己集合過程2015

    • Author(s)
      中川 真徳,小島達央,平岡秀一
    • Organizer
      26回基礎有機化学討論会
    • Place of Presentation
      愛媛大学(愛媛県松山市)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 十二核Pt(II)環状錯体の自己集合プロセス2015

    • Author(s)
      馬場絢子,小島達央,平岡秀一
    • Organizer
      第65回錯体化学討論会
    • Place of Presentation
      奈良女子大学(奈良県奈良市)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] カプセル型Pd6L8錯体の自己集合過程に及ぼす溶媒および脱離配位子の効果2015

    • Author(s)
      甲斐詢平,小島達央,平岡秀一
    • Organizer
      第65回錯体化学討論会
    • Place of Presentation
      奈良女子大学(奈良県奈良市)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] Pd2L4型かご型錯体の自己集合過程へ剛直な配位子が及ぼす影響2015

    • Author(s)
      中川真徳,小島達央,平岡秀一
    • Organizer
      第65回錯体化学討論会
    • Place of Presentation
      奈良女子大学(奈良県奈良市)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] 十二核Pt(II)環状錯体の自己集合メカニズム2015

    • Author(s)
      馬場絢子,小島達央,平岡秀一
    • Organizer
      第13回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      東北大学川内北キャンパス(宮城県仙台市)
    • Year and Date
      2015-06-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] 二核Pd(II)かご型錯体の自己集合過程2015

    • Author(s)
      甲斐詢平,赤木勝太,小島達央,平岡秀一
    • Organizer
      第13回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      東北大学川内北キャンパス(宮城県仙台市)
    • Year and Date
      2015-06-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] 金属錯体型自己組織化のメカニズム2015

    • Author(s)
      平岡秀一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部(千葉県船橋市)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 二核Pd(II)かご型錯体の自己集合過程の追跡(3):配位子の柔軟性が及ぼす効果2015

    • Author(s)
      甲斐詢平,小島達央、平岡秀一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部(千葉県船橋市)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 八面体型 Pd(II)カプセル錯体の自己集合過程に及ぼす溶媒効果2015

    • Author(s)
      甲斐詢平,小島達央、平岡秀一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部(千葉県船橋市)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] ヘキサフェニルベンゼン骨格のリチオ化における交互型選択性の探求2015

    • Author(s)
      小島達央,平岡秀一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部(千葉県船橋市)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 十二核Pt(II)環状錯体の自己集合過程の研究2015

    • Author(s)
      馬場絢子,小島達央,平岡秀一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部(千葉県船橋市)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 二核Pd(II)かご型錯体の自己集合過程の追跡(1) : 動的挙動の観測2015

    • Author(s)
      田中 成,小島達央,平岡秀一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部(千葉県船橋市)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 不安定アリールリチウムをリチオ化剤とする、ヘキサフェニルベンゼン骨格の選択的交互型トリリチオ化2014

    • Author(s)
      小島達央、平岡秀一
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2014-03-23
    • Related Report
      2013 Annual Research Report
  • [Presentation] C2v対称性を有する歯車状両親媒性分子の高効率合成と水溶性ナノキューブへの自己組織化2014

    • Author(s)
      尾形和帆、平岡秀一、小島達央
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2014-03-23
    • Related Report
      2013 Annual Research Report
  • [Presentation] 自己集合性カプセル錯体の形成機構の解明の実験的アプローチ(1):自己組織化の律速段階2014

    • Author(s)
      辻本裕也、小島達央、平岡秀一
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2014-03-23
    • Related Report
      2013 Annual Research Report
  • [Presentation] 自己集合性カプセル錯体の形成機構の解明の実験的アプローチ(1):形成メカニズム2014

    • Author(s)
      辻本裕也、平岡秀一
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2014-03-23
    • Related Report
      2013 Annual Research Report
  • [Presentation] 金属錯体型自己組織化体の形成過程を実験的に追跡する2013

    • Author(s)
      平岡秀一
    • Organizer
      光とナノサイエンス特別講義 兼 第35回生物物理学セミナー
    • Place of Presentation
      奈良先端科学技術大学院大学(奈良県生駒市)
    • Year and Date
      2013-12-05
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] ヘキサフェニルベンゼン誘導体の位置選択的交互型トリリチオ化の反応機構研究2013

    • Author(s)
      小島達央、平岡秀一
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学(東京都豊島区)
    • Year and Date
      2013-09-07
    • Related Report
      2013 Annual Research Report
  • [Presentation] 八面体型Pd(Ⅱ)カプセルの自己組織化メカニズムの研究2013

    • Author(s)
      辻本裕也、小島達央、平岡秀一
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学(東京都豊島区)
    • Year and Date
      2013-09-05
    • Related Report
      2013 Annual Research Report
  • [Book] 溶液における分子認識と自己集合の原理:分子間相互作用2017

    • Author(s)
      平岡 秀一
    • Total Pages
      232
    • Publisher
      サイエンス社
    • ISBN
      9784781914039
    • Related Report
      2017 Annual Research Report
  • [Remarks] 平岡研究室

    • URL

      http://hiraoka.c.u-tokyo.ac.jp/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 新学術領域研究「動的秩序と機能」領域

    • URL

      http://seimei.ims.ac.jp/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 東京大学総合文化研究科広域科学専攻 平岡研究室

    • URL

      http://hiraoka.c.u-tokyo.ac.jp/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 生命分子システムにおける動的秩序形成と高次機能発現

    • URL

      http://seimei.ims.ac.jp/

    • Related Report
      2016 Annual Research Report
  • [Remarks]

    • URL

      http://hiraoka.c.u-tokyo.ac.jp/index.html

    • Related Report
      2015 Annual Research Report
  • [Remarks]

    • URL

      http://hiraoka.c.u-tokyo.ac.jp/index.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 機能超分子化学研究室、研究概要

    • URL

      http://hiraoka.c.u-tokyo.ac.jp/Research/index.html

    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] ヘキサフェニルベンゼン骨格の位置選択的交互修飾方法2014

    • Inventor(s)
      平岡秀一,小島達央
    • Industrial Property Rights Holder
      平岡秀一,小島達央
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-045233
    • Filing Date
      2014-03-07
    • Related Report
      2013 Annual Research Report
  • [Funded Workshop] The 5th International Symposium on Dynamical Ordering of Biomolecular Systems for Creation of Integrated Functions2017

    • Place of Presentation
      東京大学駒場キャンパス(東京都・目黒区)
    • Year and Date
      2017-01-21
    • Related Report
      2016 Annual Research Report

URL: 

Published: 2013-07-10   Modified: 2022-05-18  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi