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Study of spin dynamics of single molecule magnet at interface

Planned Research

Project AreaMolecular Architectonics: Orchestration of Single Molecules for Novel Function
Project/Area Number 25110005
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionTohoku University

Principal Investigator

Komeda Tadahiro  東北大学, 多元物質科学研究所, 教授 (30312234)

Co-Investigator(Kenkyū-buntansha) 道祖尾 恭之  東北大学, 多元物質科学研究所, 助教 (10375165)
高岡 毅  東北大学, 多元物質科学研究所, 講師 (90261479)
Project Period (FY) 2013-06-28 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥92,950,000 (Direct Cost: ¥71,500,000、Indirect Cost: ¥21,450,000)
Fiscal Year 2017: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Fiscal Year 2016: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
Fiscal Year 2015: ¥11,830,000 (Direct Cost: ¥9,100,000、Indirect Cost: ¥2,730,000)
Fiscal Year 2014: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
Fiscal Year 2013: ¥42,640,000 (Direct Cost: ¥32,800,000、Indirect Cost: ¥9,840,000)
Keywords近藤共鳴 / 単一分子磁石 / 分子マニピュレーション / スピン計測 / スピン偏極走査型プローブ顕微鏡 / スピントロニクス / 分子磁性 / 近藤効果 / 単分子磁石 / スピン偏極 / STM / 先端機能デバイス / ナノコンタクト / ナノ材料 / 走査プローブ顕微鏡 / 分子磁石 / 磁気抵抗素子 / 巨大磁気抵抗
Outline of Final Research Achievements

This group has set the research target on the designing, characterization and control of surfaces, which should provide infrastructure of the 'molecular architect'. Special attentions have been paid for the phenomena formed by the interaction between the molecular spins and the conduction electron. We have demonstrated that the Kondo resonance, which is a spin-screening effect of the conduction electrons for an isolated spin, can be used as a useful technique for characterizing the spin of magnetic molecules. This has been shown for the cases of the Cu corrole molecule and the porphyrin double-decker complex of Tb atom. For the latter, we showed that a dehydrogenation can switch ON/Off of the single molecule magnet (SMM) properties. In addition, we have developed spin-polarized STM (SP-STM) to characterize the direction of the spin in nano materials. This has been applied for the determination of the magnetic anisotropic energy (MAE) of Co bilayer film on Au(111) surface.

Report

(6 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (27 results)

All 2018 2017 2016 2015 2014 2013 Other

All Int'l Joint Research (1 results) Journal Article (15 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 15 results,  Open Access: 5 results,  Acknowledgement Compliant: 9 results) Presentation (10 results) (of which Int'l Joint Research: 5 results,  Invited: 7 results) Book (1 results)

  • [Int'l Joint Research] 3Donostia International Physics Center(Spain)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Inter-molecule interaction for magnetic property of vanadyl tetrakis (thiadiazole) porphyrazine film on Au(111)2018

    • Author(s)
      J. Hou, Y. Wang, K. Eguchi, C. Nanjo, T. Takaoka, Y. Sainoo, K. Awaga, T. Komeda
    • Journal Title

      Applied Surface Science

      Volume: 440 Pages: 16-19

    • DOI

      10.1016/j.apsusc.2018.01.001

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Spatially Resolved Magnetic Anisotropy of Cobalt Nanostructures on the Au(111) Surface2017

    • Author(s)
      P. Mishra, Z. K. Qi, H. Oka, K. Nakamura, T. Komeda
    • Journal Title

      Nano Letters

      Volume: 17 Issue: 9 Pages: 5843-5847

    • DOI

      10.1021/acs.nanolett.7b03114

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic-scale characterization of the interfacial phonon in graphene/SiC2017

    • Author(s)
      E. Minamitani, R. Arafune, T. Frederiksen, T. Suzuki, S. M. F. Shahed, T. Kobayashi, N. Endo, H. Fukidome, S. Watanabe, T. Komeda,
    • Journal Title

      Phys. Rev. B

      Volume: 96 Issue: 15 Pages: 155431-155431

    • DOI

      10.1103/physrevb.96.155431

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Deposition of an Ultraflat Graphene Oxide Nanosheet on Atomically Flat Substrates,2017

    • Author(s)
      M. Z. H. Khan, S. M. F. Shahed, N. Yuta, T. Komeda
    • Journal Title

      J. Electron. Mater.

      Volume: 11 Issue: 7 Pages: 1-6

    • DOI

      10.1007/s11664-017-5327-x

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Surface confinement of TbPc2-SMMs: structural, electronic and magnetic properties2016

    • Author(s)
      E. Moreno Pineda, T. Komeda, K. Katoh, M. Yamashita, M. Ruben,
    • Journal Title

      Dalton Trans.

      Volume: 45 Issue: 46 Pages: 18417-18433

    • DOI

      10.1039/c6dt03298b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] A scanning tunneling microscopy study of the electronic and spin states of bis(phthalocyaninato)terbium(III) (TbPc2) molecules on Ag(111)2016

    • Author(s)
      F. Ara, Z. K. Qi, J. Hou, T. Komeda, K. Katoh, M. Yamashita,
    • Journal Title

      Dalton Trans.

      Volume: 45 Issue: 42 Pages: 16644-16652

    • DOI

      10.1039/c6dt01967f

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] DFT calculations on atom-specific electronic properties of G/SiC (0001)2016

    • Author(s)
      M Kajihara, T Suzuki, SMF Shahed, T Komeda, E Minamitani, S Watanabe
    • Journal Title

      Surface Science

      Volume: 647 Pages: 39-44

    • DOI

      10.1016/j.susc.2015.12.004

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Frontier of Molecular Spintronics Based on Multiple-Decker Phthalocyaninato Tb(lll) Single-Molecule Magnets2016

    • Author(s)
      K. Katoh, T. Komeda, M. Yamashita
    • Journal Title

      Chemical Record

      Volume: 16 Issue: 2 Pages: 987-1016

    • DOI

      10.1002/tcr.201500290

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Modulation of the Molecular Spintronic Properties of Adsorbed Copper Corroles2015

    • Author(s)
      F. Wu, J. Liu, P. Mishra, T. Komeda, J. Mack, Y. Chang, N. Kobayashi, Z. Shen,
    • Journal Title

      Nat. Comm.

      Volume: 6 Issue: 1 Pages: 7547-7547

    • DOI

      10.1038/ncomms8547

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Visualizing Optoelectronic Processes at the Nanoscale2015

    • Author(s)
      P. Mishra, T. Komeda
    • Journal Title

      Acs Nano

      Volume: 9 Issue: 11 Pages: 10540-10544

    • DOI

      10.1021/acsnano.5b06282

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Variation of Kondo Tmenperature Induced by Molecule-Substrate decoupling in File Formation of Bis(phthalocyaninato)terbium(III) Molecules on Au(111)2014

    • Author(s)
      Tadahiro Komeda, Hironari Isshiki, Jie Liu, Keiichi Katoh, Masahiro Yamashita
    • Journal Title

      ACS Nano

      Volume: 8 Issue: 5 Pages: 4866-4875

    • DOI

      10.1021/nn500809v

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Spins of adsorbed molecules investigated by the detection of Kondo resonance2014

    • Author(s)
      *T. Komeda
    • Journal Title

      Surface Science

      Volume: 630 Pages: 343-355

    • DOI

      10.1016/j.susc.2014.07.012

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] STM and XPS study of CeO2(111) reduction by atomic hydrogen2014

    • Author(s)
      S. M. F. Shahed, T. Hasegawa, Y. Sainoo, Y. Watanabe, N. Isomura, A. Beniya, H. Hirata
    • Journal Title

      Surface Science

      Volume: 628 Pages: 30-35

    • DOI

      10.1016/j.susc.2014.05.008

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Double-decker phthalocyanine complex: Scanning tunneling microscopy study of film formation and spin properties2014

    • Author(s)
      Tadahiro Komeda, Keiichi Katoh, Masahiro Yamashita
    • Journal Title

      Progress in Surface Science

      Volume: 89 Issue: 2 Pages: 127-160

    • DOI

      10.1016/j.progsurf.2014.03.001

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Metal Electrode Formation on Organic Film Using Xe-Buffer-Layer-Assisted Deposition for Efficient Measurement of Inelastic Tunneling Spectroscopy2013

    • Author(s)
      A. Rahim, J. Liu, S. M. F. Shahed, T. Komeda
    • Journal Title

      Applied Physics Express

      Volume: 6 Issue: 4

    • DOI

      10.1063/1.4849595

    • NAID

      210000136837

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Spin Control of Magnetic Molecules with Scanning Tunneling Microscopy2017

    • Author(s)
      Tadahiro Komeda, Puneet Mishra, Jie Liu, Keizo Katoh, Masahiro Yamashita, Tomoko Inose, Daisuke Tanaka, Takuji Ogawa, Fan Wu, Zhen Shen
    • Organizer
      The First International Symposium on Frontiers in Coordination Chemistry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Spin Control of Magnetic Molecules with Scanning Tunneling Microscopy2016

    • Author(s)
      T. Komeda, P. Mishra, J. Liu, K. Katoh, M. Yamashita, T. Inose, D. Tanaka, T. Ogawa
    • Organizer
      The 15th International Conference on Molecule-Based Magnets
    • Place of Presentation
      Sendai International Convention Center (Miyagi, Sendai)
    • Year and Date
      2016-09-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Spin Observation and Control of Magnetic Molecules with Scanning Tunnelling Microscopy2016

    • Author(s)
      T. Komeda, P. Mishra, J. Liu, K. Katoh, M. Yamashita, T. Inose, D. Tanaka, T. Ogawa, F. Wu, Z. Shen
    • Organizer
      42nd edition of the International Conference on Coordination Chemistry in Brest
    • Place of Presentation
      Best, France
    • Year and Date
      2016-08-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Spin properties of adsorbed magnetic molecule detected by Kondo feature2015

    • Author(s)
      Tadahiro Komeda, Tomoko Inose, Daisuke Tanaka, Takuji Ogawa, Fan Wu, Zhen Shen
    • Organizer
      PACIFIC BASIN SOCIETIES 2015
    • Place of Presentation
      Hawaii Convention Center, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] GROWTH OF EPITAXIAL CEO2(111) FILM ON RU(0001) AND ITS REDUCTION BY HYDROGEN2015

    • Author(s)
      Tadahiro Komeda, Syed Mohammad Fakruddin Shahed, Yasuyuki Sainoo, Tomo Hasegawa
    • Organizer
      250th American Chemical Society National Meeting & Exposition
    • Place of Presentation
      Boston convention center, USA
    • Year and Date
      2015-08-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Spin Control of Magnetic Molecules with Scanning Tunneling Microscopy2014

    • Author(s)
      Tadahiro Komeda
    • Organizer
      DIET 14:Dynamics,Interactions and Electronic Transitions at Surfaces
    • Place of Presentation
      Pacific Grove, CA, アメリカ
    • Year and Date
      2014-10-13 – 2014-10-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Characterization and Manipulation of Spin of Single-Molecule-Magnet Double-Decker Phthalocyanine Molecule2014

    • Author(s)
      Tadahiro Komeda
    • Organizer
      Chinese Chemical Society (中国化学会第29回)
    • Place of Presentation
      北京大学、中国
    • Year and Date
      2014-08-04 – 2014-08-07
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Manipulation of spin of single-molecule-magnet double-decker2013

    • Author(s)
      Tadahiro Komeda
    • Organizer
      The 12th European Conference on Molecular Electronics (ECME2013)
    • Place of Presentation
      London, イギリス
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Kondo resonance observation of a organic radical molecule2013

    • Author(s)
      J. Liu and T. Komeda
    • Organizer
      12th International Conference on Atomically Controlled Surfaces, International and Nanostructures (ACSIN-12) in conjunction with 21st International Colloquium on Scanning Probe Microscopy (ICSPM21
    • Place of Presentation
      つくば市
    • Related Report
      2013 Annual Research Report
  • [Presentation] Adsorption and spin of single-molecule-magnet double-decker2013

    • Author(s)
      Tadahiro Komeda
    • Organizer
      19th International Vacuum Congress IVC-19
    • Place of Presentation
      Paris, フランス
    • Related Report
      2013 Annual Research Report
  • [Book] Molecular Architectonics:The Third Stage of Single Molecule Electronics2017

    • Author(s)
      Tadahiro Komeda
    • Publisher
      Springer International Publishing
    • ISBN
      9783319570969
    • Related Report
      2017 Annual Research Report

URL: 

Published: 2013-07-10   Modified: 2019-07-29  

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