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Main Group pi-Figuration

Planned Research

Project Areapi-System Figuration: Control of Electron and Structural Dynamism for Innovative Functions
Project/Area Number 26102006
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionSaitama University

Principal Investigator

Saito Masaichi  埼玉大学, 理工学研究科, 教授 (80291293)

Research Collaborator Furukawa Shunsuke  
Project Period (FY) 2014-07-10 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥38,090,000 (Direct Cost: ¥29,300,000、Indirect Cost: ¥8,790,000)
Fiscal Year 2018: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2017: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2016: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2015: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
Fiscal Year 2014: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
Keywords典型元素 / π造形 / 表裏二面性 / 強誘電性 / π拡張 / 配位高分子 / 遷移金属錯体 / ヘテラスマネン / 二重クロスカップリング反応 / ポリフルオロトリベンゾコロネン / ジアニオン性π配位子 / 異核金属錯体 / ナノ粒子 / π電子系 / 芳香族ジアニオン性配位子 / 異方性 / 共有結合有機構造体 / トリベンゾコロネン / アニオン性フェロセン / 炭素π電子系 / π配位子 / トリホスファスマネントリスルフィド / スピロ連結 / ジベンゾペンタレン / ジリチオスタンノール / ルテノセン / 混合原子価 / トリホスファスマネン / ヘキサヘテラ[6]サーキュレン / 鉛二価化学種 / 超分子 / 中性トリプルデッカー型遷移金属錯体
Outline of Final Research Achievements

We have accomplished the creation of pi-systems that cannot be accessed by the use of only carbon atoms but can be synthesized by taking advantage of heavy main group atoms, which adopt a wide variety of structures and exhibit a wide variety of reactivities. We have succeeded in the creation of a out-of-plane anisotropic pi-conjugated compound by the introduction of phosphorus functionalities. We have demonstrated a bowl-to-bowl inversion of a pi-conjugated compound bearing long C-main group atom bonds as a new strategy for the creation of organoferroelectric compounds. We have succeeded in the synthesis of a coordination polymer by the use of a vacant orbital of a divalent tin compound and a wide variety of transition-metal complexes that bear unique electronic structures derived from an aromatic dianionic tin compound.

Academic Significance and Societal Importance of the Research Achievements

得られた構造や物性は炭素のみからなる化学では達成できない、重典型元素がとりうる多彩な電子状態や反応性を活かしたからこそ達成できたものであり、物性化学における分子設計という観点から大きな波及効果がある。この成果を生み出した考え方が帰納的に用いられ、新しい物性化学が誕生するという社会的意義が期待される。また、重典型元素の必要性を示したという学術的な意義がある。従来あまり注目されてこなかった重典型元素を巧みに用いているので、学術的に独創的なアプローチである。

Report

(6 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report

Research Products

(90 results)

All 2019 2018 2017 2016 2015 2014 Other

All Int'l Joint Research (8 results) Journal Article (22 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 22 results,  Open Access: 6 results,  Acknowledgement Compliant: 8 results) Presentation (57 results) (of which Int'l Joint Research: 14 results,  Invited: 12 results) Remarks (3 results)

  • [Int'l Joint Research] デュッセルドルフ大学(ドイツ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] ヘブライ大学(イスラエル)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] カリフォルニア大学バークレー校(米国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] デュッセルドルフ大学/アーヘン工科大学(ドイツ)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] ヘブライ大学(イスラエル)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] デュッセルドルフ大学(ドイツ)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] ヘブライ大学(イスラエル)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] University of Duesseldorf(ドイツ)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Anionic Stannaferrocene and Its Unique Electronic State2019

    • Author(s)
      Saito Masaichi、Matsunaga Naoki、Hamada Jumpei、Furukawa Shunsuke、Tada Tomofumi、Herber Rolfe H.
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 2 Pages: 163-165

    • DOI

      10.1246/cl.180880

    • NAID

      130007590723

    • ISSN
      0366-7022, 1348-0715
    • Year and Date
      2019-02-05
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Creation of Exotic π-Electron Systems by Introduction of Heavy Elements and Expansion of the Concept of Aromaticity2018

    • Author(s)
      M. Saito
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 91 Issue: 7 Pages: 1009-1019

    • DOI

      10.1246/bcsj.20180047

    • NAID

      130007404811

    • ISSN
      0009-2673, 1348-0634
    • Year and Date
      2018-07-15
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis and Properties of Spiro-type Heterasumanenes containing Group 14 Elements as Bridging Atoms2018

    • Author(s)
      Furukawa, S.; Hayashi, K.; Yamagishi, K.; Saito, M.
    • Journal Title

      Mater. Chem. Front.

      Volume: 印刷中 Issue: 5 Pages: 929-934

    • DOI

      10.1039/c7qm00590c

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Figuration of bowl-shapedp-conjugatedmolecules: properties and functions2018

    • Author(s)
      Masaichi Saito, Hiroshi Shinokubo, Hidehiro Sakurai
    • Journal Title

      Mater. Chem. Front.

      Volume: 2 Issue: 4 Pages: 635-661

    • DOI

      10.1039/c7qm00593h

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Heterobimetallic Triple-decker Complexes Derived from an Dianionic Aromatic Stannole Ligand2018

    • Author(s)
      M. Saito, N. Matsunaga, J. Hamada, S. Furukawa, M. Minoura, S. Wegner, J. Barthel and C. Janiak
    • Journal Title

      Dalton Trans.

      Volume: 47 Issue: 27 Pages: 8892-8896

    • DOI

      10.1039/c8dt01455h

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Double aromaticity arising from σ- and π-rings2018

    • Author(s)
      Furukawa Shunsuke、Fujita Masahiro、Kanatomi Yoshihiko、Minoura Mao、Hatanaka Miho、Morokuma Keiji、Ishimura Kazuya、Saito Masaichi
    • Journal Title

      Communications Chemistry

      Volume: 1 Issue: 1 Pages: 60-60

    • DOI

      10.1038/s42004-018-0057-4

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Transition-metal Complexes Featuring Dianionic Heavy Group 14 Element Aromatic Ligands2018

    • Author(s)
      M. Saito
    • Journal Title

      Acc. Chem. Res.

      Volume: 51 Issue: 1 Pages: 160-169

    • DOI

      10.1021/acs.accounts.7b00367

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reactions of Dilithium Dibenzopentalenides with Cr(CO)3(CH3CN)3: Unexpected Formation of a Cubic Tetramer of an Anionic Hydrodibenzopentalenyl Complex2017

    • Author(s)
      T. Kuwabara, N. Kurokawa and M. Saito
    • Journal Title

      ChemPlusChem

      Volume: 82 Issue: 7 Pages: 1039-1042

    • DOI

      10.1002/cplu.201700043

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Triphosphasumanene Trisulfide: High Out-of-Plane Anisotropy and Janus-Type π-Surfaces2017

    • Author(s)
      Shunsuke Furukawa, Yuki Suda, Junji Kobayashi, Takayuki Kawashima, Tomofumi Tada, Shintaro Fujii, Manabu Kiguchi, Masaichi Saito
    • Journal Title

      Journal of the Americal Chemical Society

      Volume: 139 Issue: 16 Pages: 5787-5792

    • DOI

      10.1021/jacs.6b12119

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Formation of Dibenzopentalene-linking Polymers under the Two-zone CVD and Wet Conditions2017

    • Author(s)
      M. Saito, Y. Suda, S. Furukawa, T. Nakae, T. Kojima, H. Sakaguchi
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 8 Pages: 1099-1101

    • DOI

      10.1246/cl.170396

    • NAID

      130005906995

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anisotropic Crystals Based on Main-group Coordination Polymer with Alignment of Rigid π-Skeletons2017

    • Author(s)
      M. Saito, T. Akiba, S. Furukawa, M. Minoura, M. Hada and H. Y. Yoshikawa
    • Journal Title

      Organometallics

      Volume: 36 Issue: 14 Pages: 2487-2490

    • DOI

      10.1021/acs.organomet.7b00217

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Reactivity of a Ruthenocene-type Complex bearing an Aromatic π-Ligand with the Heaviest Group 14 Element2017

    • Author(s)
      Marisa Nakada, Takuya Kuwabara, Shunsuke Furukawa, Masahiko Hada, Mao Minoura, Masaichi Saito
    • Journal Title

      Chemical Science

      Volume: 8 Issue: 4 Pages: 3092-3097

    • DOI

      10.1039/c6sc04843a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Efficient Synthesis of 1,4-Bis-heteroatom-substituted Tetraselanylbenzenes via 1,4-Dilithiation of Hexaselanylbenzene and Investigation on Their Electronic Properties2017

    • Author(s)
      Masahiro Fujita, Shunsuke Furukawa, Masaichi Saito
    • Journal Title

      Chemistry An Asian Journal

      Volume: 1 Issue: 9 Pages: 1303-1305

    • DOI

      10.1002/asia.201700164

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] (η4-Butadiene)Sn(0) Complexes: A New Approach for Zero-valent p-Block Elements Utilizing a Butadiene as a 4π-Electron Donor2016

    • Author(s)
      T. Kuwabara, M. Nakada, J. Hamada, J. D. Guo, S. Nagase and M. Saito
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 35 Pages: 11378-11382

    • DOI

      10.1021/jacs.6b07304

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Soft Wet-chemical Synthesis of Ru-Sn Nanoparticles from Single-source Ruthenocene-stannole Precursors in an Ionic Liquid2016

    • Author(s)
      S. Wegner, M. Saito, J. Barthel and C. Janiak
    • Journal Title

      J. Organomet. Chem.

      Volume: 821. Pages: 192-196

    • DOI

      10.1016/j.jorganchem.2016.05.010

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] 256.The Chemistry of Heterasumanenes2016

    • Author(s)
      M. Saito, S. Furukawa, J. Kobayashi, T, Kawashima
    • Journal Title

      Chem. Rec.

      Volume: 16 Issue: 1 Pages: 64-72

    • DOI

      10.1002/tcr.201500211

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Serendipitous Reactions Involving a Silicone Grease2016

    • Author(s)
      L. C. Pop and M. Saito
    • Journal Title

      Coord. Chem. Rev.

      Volume: 314 Pages: 64-70

    • DOI

      10.1016/j.ccr.2015.07.005

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Diverse Coordination Modes in Tin Analogues of a Cyclopentadienyl Anion Depending on the Substituents on the Tin Atom2015

    • Author(s)
      T. Kuwabara, M. Nakada, J. D. Guo, S. Nagase and M. Saito
    • Journal Title

      Dalton Trans.

      Volume: 44 Issue: 37 Pages: 16266-16271

    • DOI

      10.1039/c5dt02202a

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of a Stannole Dianion Complex Bearing a μ-η1;η1-Coordination Mode: Different Electronic State of Stannole Dianion Ligands Depending on their Hapticity2015

    • Author(s)
      T. Kuwabara and M. Saito
    • Journal Title

      Organometallics

      Volume: 34 Issue: 17 Pages: 4202-4204

    • DOI

      10.1021/acs.organomet.5b00614

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A reversible two-electron redox system involving a divalent lead species2015

    • Author(s)
      M. Saito, M. Nakada, T. Kuwabara, M. Minoura
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 22 Pages: 4674-4676

    • DOI

      10.1039/c4cc09856k

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structures, and Electronic Properties of Triple-and Double-Decker Ruthenocenes Incorporated by a Group 14 Metallole Dianion Ligand2014

    • Author(s)
      T. Kuwabara, J.-D. Guo, S. Nagase, T. Sasamori, N. Tokitoh, and M. Saito
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 37 Pages: 13059-13064

    • DOI

      10.1021/ja507330p

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unexpected Dehalogenation Reactions of Dichloroborane Bearing a NCN-Pincer Ligand: Formation of a Borenium Salt2014

    • Author(s)
      M. Saito, K. Matsumoto, M. Fujita, M. Minoura
    • Journal Title

      Heteroatom Chem.

      Volume: 25 Issue: 5 Pages: 354-360

    • DOI

      10.1002/hc.21211

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Systematic Synthesis of Spiro-Type Heterasumanenes and Their Structures and Redox Properties2018

    • Author(s)
      山岸健(埼玉大院理工)、林敬祐(埼玉大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      28th International Symposium on the Organic Chemistry of Sulfur
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Organic Ferroelectricity of Trithiasumanenes Arising from Bowl-to-Bowl Inversion2018

    • Author(s)
      甲山雅也(埼玉大院理工)、Wu Jianyun(東北大多元研)、芥川智行(東北大多元研)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      28th International Symposium on the Organic Chemistry of Sulfur
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Application of Janus-Type π-Conjugated Molecule to Work Function Control of Metal Substrates2018

    • Author(s)
      須田裕貴(埼玉大院理工)、古川俊輔(埼玉大院理工)、設樂雄作(埼玉大院理工)、藤森厚裕(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      28th International Symposium on the Organic Chemistry of Sulfur
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Covalent Organic Frameworks Composed of Bowl-Shaped Trichalcogenasumanenes as π-Frameworks2018

    • Author(s)
      古川俊輔(埼玉大院理工)、林敬祐(埼玉大院理工)、河東田道夫(早大理工学術院総研)、今村穣(首都大院理工)、田代基慶(東洋大院理工)、久木一朗(阪大院工)、酒巻大輔(阪府大院理)、関修平(京大院工)、斎藤雅一(埼玉大院理工)
    • Organizer
      28th International Symposium on the Organic Chemistry of Sulfur
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Single-Molecule Electron Transport Properties of Sumanene Derivatives with Phosphine Sulfide Anchoring Groups2018

    • Author(s)
      岩根まどか(東工大院理工)、藤井慎太郎(東工大院理工)、木口学(東工大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      34th European Conference on Surface Science
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Covalent Organic Frameworks Containing Bowl-Shaped Trichalcogenasumanenes as π-Frameworks2018

    • Author(s)
      古川俊輔(埼玉大院理工)、林敬祐(埼玉大院理工)、河東田道夫(早大理工学術院総研)、久木一朗(阪大院工)、酒巻大輔(阪府大院理)、関修平(京大院工)、斎藤雅一(埼玉大院理工)
    • Organizer
      The Third International Symposium on the Synthesis and Application of Curved Organic π-Molecules & Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 非局在σ対称性軌道を有するポリヨードベンゼンの電荷輸送特性とその理論化学的考察2018

    • Author(s)
      髙田侑希(埼玉大院理工)、山岸正和(富山高専)、岡本敏宏(東大院新領域)、竹谷純一(東大院新領域)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] トリスタンナスマネンの二重クロスカップリング反応によるπ拡張分子の創製2018

    • Author(s)
      岩渕陽花(埼玉大院理工)、千葉宏伸(埼玉大院理工)、中尾宰(京工芸繊大院工芸)、清水正毅(京工芸繊大院工芸)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis of Dibenzopentalenides by the Reduction of Phenylsilylacetylenes -from by chance to on purpose-2018

    • Author(s)
      斎藤雅一(埼玉大院理工)
    • Organizer
      9th European Silicon Days
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] スマネン誘導体を用いた高い伝導性と安定性を併せ持つ単分子接合の作製2018

    • Author(s)
      岩根まどか(東工大院理工)、藤井慎太郎(東工大院理工)、木口学(東工大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      日本物理学会2018年秋季大会(物性)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 多置換テラニルベンゼンの系統的合成法の開発とσ対称性軌道相互作用を利用した酸化還元挙動2018

    • Author(s)
      壬生颯史(埼玉大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      第8回CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] ボウル型骨格の反転によるトリチアスマネンの強誘電性2018

    • Author(s)
      甲山雅也(埼玉大院理工)、Wu Jianyun(東北大多元研)、芥川智行(東北大多元研)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      第8回CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] プルンボールジアニオンを配位子とした遷移金属錯体の合成、構造および触媒活性2018

    • Author(s)
      斎藤雅一(埼玉大院理工)、中田麻理沙(埼玉大院理工)、桑原拓也(埼玉大院理工)、古川俊輔(埼玉大院理工)、Radhika Narayanan(首都大院理工)、阿部穣里(首都大院理工)波田雅彦(首都大院理工)、田中健(東工大物質理工)、山本芳彦(名大院創薬)
    • Organizer
      第22回ケイ素化学協会シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] スタンナフルオレンの二重クロスカップリング反応による新規π拡張分子の創製2018

    • Author(s)
      岩渕陽花(埼玉大院理工)、千葉宏伸(埼玉大院理工)、中尾宰(京工芸繊大院工芸)、清水正毅(京工芸繊大院工芸)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      第22回ケイ素化学協会シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Transition-metal Complexes Derived from Tin- and Lead-Bearing Aromatic Dianionic Ligands2018

    • Author(s)
      斎藤雅一(埼玉大院理工)
    • Organizer
      XVIII International Symposium on Selected Problems of Chemistry of Acyclic and Cyclic Heteroorganic Compounds
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] トリホスファスマネン誘導体の面外異方性と有機/金属界面化学への展開2018

    • Author(s)
      古川俊輔(埼玉大院理工)、須田裕貴(埼玉大院理工)、小林潤司(国際基督教大教養)、川島隆幸(東大院理)、多田朋史(東工大元素戦略セ)、藤井慎太郎(東工大院理工)、木口学(東工大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] トリホスファスマネンの誘導化と異方性をもつ単分子膜の作製2018

    • Author(s)
      須田裕貴(埼玉大院理工)、古川俊輔(埼玉大院理工)、設樂雄作(埼玉大院理工)、藤森厚裕(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] スピロ架橋型ヘテラスマネン類の系統的合成とその構造及び物性2018

    • Author(s)
      山岸健(埼玉大院理工)、林敬祐(埼玉大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] スタンナフルオレンの二重クロスカップリング反応によるπ拡張分子の創製2018

    • Author(s)
      岩渕陽花(埼玉大院理工)、千葉宏伸(埼玉大院理工)、中尾宰(京工芸繊維大院理工)、清水正毅(京工芸繊維大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 異なる鎖長のアルコキシ基を有するトリチアスマネンの系統的合成と固体状態での熱物性2018

    • Author(s)
      甲山雅也(埼玉大院理工)、呉筧(東北大多元研)、芥川智行(東北大多元研)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] フェロセンの位置選択的ポリリチオ化反応の開発とDouble-Layered COF合成への展開2018

    • Author(s)
      林敬祐(埼玉大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ボウル型トリカルコゲナスマネンを基本π骨格とする共有結合性有機構造体(COF)の合成と性質2017

    • Author(s)
      林敬祐(埼玉大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] トリホスファスマネントリカルコゲニドの面外異方性に対する置換基効果2017

    • Author(s)
      須田祐貴(埼玉大院理工)、古川俊輔(埼玉大院理工)、小林潤司(国際基督教大教養)、川島隆幸(東大院理)、斎藤雅一(埼玉大院理工)
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] ジボリル置換テトラセラニルベンゼンの合成とその電子状態の理論的考察2017

    • Author(s)
      藤田雅大(埼玉大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-18
    • Related Report
      2016 Annual Research Report
  • [Presentation] Electronic Structure and Property of an Anionic Ferrocene Analog Bearing Stannole Ligands2017

    • Author(s)
      松永直樹(埼玉大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] スピロ架橋型ヘテラスマネンの合成とその多段階酸化還元挙動2017

    • Author(s)
      山岸健(埼玉大理)、林敬祐(埼玉大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 重原子の導入による芳香族性の拡張と錯体化学への展開2017

    • Author(s)
      斎藤雅一(埼玉大院理工)
    • Organizer
      近畿化学協会有機金属部会 平成29年度第2回例会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] スピロ架橋型ヘテラスマネン類の系統的合成とその性質2017

    • Author(s)
      山岸健(埼玉大院理工)、林敬祐(埼玉大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ボウル型ヘテラスマネンを鍵骨格としたヘキサゴナルネットワークの創製2017

    • Author(s)
      林敬祐(埼玉大院理工)、古川俊輔(埼玉大院理工)、酒巻大輔(京大院工)、関修平(京大院工)、斎藤雅一(埼玉大院理工)
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 異なるアルキル鎖長をもつヘキサアルコキシトリチアスマネンの系統的合成とその熱物性測定2017

    • Author(s)
      甲山雅也(埼玉大院理工)、林敬祐(埼玉大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      第7回CSJ化学フェスタ
    • Related Report
      2017 Annual Research Report
  • [Presentation] ジベンゾペンタレンの新しい化学-偶然の発見と必然-2017

    • Author(s)
      斎藤雅一(埼玉大院理工)
    • Organizer
      第11回有機π電子系シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 有機鉛二価化学種の特徴を活かしたπ骨格の三次元的拡張2016

    • Author(s)
      斎藤雅一(埼玉大院理工)、秋葉知樹(埼玉大院理工)、古川俊輔(埼玉大院理工)、吉川洋史(埼玉大院理工)、波田雅彦(首都大院理工)
    • Organizer
      第43回有機典型元素化学討論会
    • Place of Presentation
      仙台市民会館(宮城県仙台市)
    • Year and Date
      2016-12-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] 大きな面外異方性を有するトリホスファスマネンの金属界面での物性2016

    • Author(s)
      須田祐貴(埼玉大院理工)、古川俊輔(埼玉大院理工)、小林潤司(国際基督教大教養)、川島隆幸(東大院理)、多田朋史(東工大元素戦略セ)、藤井慎太郎(東工大院理工)、木口学(東工大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      第6回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2016-11-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Synthesis and Properties of an Anionic Ferrocene Derivative Using a Stannole Ligand2016

    • Author(s)
      松永直樹(埼玉大院理工)、古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      早稲田大学西早稲田キャンパス(東京都新宿区)
    • Year and Date
      2016-09-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] ボウル型トリヘテラスマネンを基本π骨格とする共有結合性有機構造体2016

    • Author(s)
      林敬祐(埼玉大院理工)古川俊輔(埼玉大院理工)、斎藤雅一(埼玉大院理工)
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島国際会議場(広島県広島市)
    • Year and Date
      2016-09-01
    • Related Report
      2016 Annual Research Report
  • [Presentation] Aromatic and Antiaromatic Compounds with Tin and Lead Atoms: New Building Blocks for π-Figuration2016

    • Author(s)
      斎藤雅一(埼玉大院理工)
    • Organizer
      XVth International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead
    • Place of Presentation
      パルドゥビツェ大学(チェコ パルドゥビツェ)
    • Year and Date
      2016-08-30
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Triphosphasumanene2016

    • Author(s)
      古川俊輔(埼玉大院理工)、小林潤司(国際基督教大教養)、川島隆幸(東大院理)、斎藤雅一(埼玉大院理工)
    • Organizer
      The 21st International Conference on Phosphorus Chemistry
    • Place of Presentation
      コルストンホテル(ロシア カザン)
    • Year and Date
      2016-06-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] スタンノール配位子を有するトリプルデッカー型ルテニウム錯体の混合原子価状態の解明2016

    • Author(s)
      濵田純平、古川俊輔、宮坂等、斎藤雅一
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] スタンノール環を鍵配位子としたアニオン性フェロセン類縁体の創製2016

    • Author(s)
      松永直樹、古川俊輔、斎藤雅一
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] トリホスファスマネントリスルフィドの合成とそのπ平面二面性2016

    • Author(s)
      須田裕貴、古川俊輔、小林潤司、川島隆幸、多田朋史、藤井慎太郎、木口学、斎藤雅一
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] トリスタンナ(II)スマネンヘキサアニオンの発生2016

    • Author(s)
      千葉宏伸、古川俊輔、斎藤雅一
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis, Structure and Reactivity of Stannole- and Plumbole-based Transition-metal Complexes2015

    • Author(s)
      斎藤雅一
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ヒルトン・ハワイアンヴィレッジ(アメリカ)
    • Year and Date
      2015-12-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] スズ上の置換基に応じて変化するスタンノールアニオンの配位形式2015

    • Author(s)
      斎藤雅一、桑原拓也、中田麻理沙、Guo Jing Dong、永瀬茂
    • Organizer
      第42回有機典型元素化学討論会
    • Place of Presentation
      名古屋大学(愛知県名古屋市千種区)
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] トリホスファスマネントリスルフィド:表裏を有するπ共役化合物の創製2015

    • Author(s)
      須田裕貴、小林潤司、川島隆幸、古川俊輔、斎藤雅一
    • Organizer
      第26回基礎有機化学討論会
    • Place of Presentation
      愛媛大学(愛媛県松山市)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis, Structures and Reactions of Antiaromatic Organolead Compounds Stabilized by Lewis Bases2015

    • Author(s)
      斎藤雅一、秋葉知樹、中田麻理沙、金子美澄、古川俊輔、箕浦真生、波田雅彦
    • Organizer
      14th International Symposium on Inorganic Ring Systems
    • Place of Presentation
      レーゲンスブルグ大学(ドイツ)
    • Year and Date
      2015-07-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Replacement of a Skeletal Carbon Atom by a Heavier Atom to Tune the Properties of the Cp Ligand2015

    • Author(s)
      斎藤雅一
    • Organizer
      8th International Conference on Materials for Advanced Technologies of the Materials Research Society of Singapore
    • Place of Presentation
      SUNTECシンガポール(シンガポール)
    • Year and Date
      2015-06-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New Insight into the Chemistry of Sandwich Complexes: Utilization of Metallole Dianion2015

    • Author(s)
      斎藤雅一
    • Organizer
      11th International Conference on Heteroatom Chemistry
    • Place of Presentation
      カン大学(フランス)
    • Year and Date
      2015-06-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ヘキサシラ[6]サーキュレンの合成検討2015

    • Author(s)
      藤田雅大、古川俊輔、斎藤雅一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] プルンボールを配位子としたロジウム(I)錯体の構造と反応2015

    • Author(s)
      中田麻理沙、桑原拓也、古川俊輔、波田雅彦、斎藤雅一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] スタンノールジアニオンを配位子とした中性ヘテロバイメタリックトリプルデッカー型錯体の合成とその性質2015

    • Author(s)
      松永直樹、古川俊輔、Guo Jing Dong、永瀬茂、斎藤雅一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 特異な分子配列を有するプルンビレンワイヤーの構築2015

    • Author(s)
      秋葉知樹、古川俊輔、斎藤雅一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 重元素導入による特異なπ電子系の創製と芳香族性の概念の拡張2015

    • Author(s)
      斎藤雅一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] プルンボールを配位子としたルテノセンの合成と鉛上の置換基の構造に及ぼす影響2014

    • Author(s)
      中田麻理沙、桑原拓也、斎藤雅一
    • Organizer
      第61回有機金属化学討論会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis of Tin and Lead Analogs of Cyclopentadienyl Anion and their Application to Transition-metal Complexes2014

    • Author(s)
      斎藤雅一
    • Organizer
      Molecular Complexity in Modern Chemistry
    • Place of Presentation
      Russian Academy of Science
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Aromatic and Antiaromatic Organolead Compounds: Dilithioplumbole and Plumbacyclopentadienylidene2014

    • Author(s)
      斎藤雅一
    • Organizer
      41st International Conference on Coordination Chemistry
    • Place of Presentation
      SUNTEC Singapore
    • Year and Date
      2014-07-24
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] The Heaviest Ruthenocene Derived from a Silyl-substituted Dilithioplumbole2014

    • Author(s)
      中田麻理沙、桑原拓也、斎藤雅一、
    • Organizer
      26th International Conference on Organometallic Chemistry
    • Place of Presentation
      ロイトン札幌
    • Year and Date
      2014-07-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Transition-metal Complexes Derived from Aromatic Tin-containing Cyclopentadienyl Analogs2014

    • Author(s)
      斎藤雅一
    • Organizer
      26th International Conference on Organometallic Chemistry
    • Place of Presentation
      ロイトン札幌
    • Year and Date
      2014-07-16
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Remarks] 斎藤雅一研究室

    • URL

      http://www.chem.saitama-u.ac.jp/msaito-lab/index.html

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report 2016 Annual Research Report 2014 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.saitama-u.ac.jp/msaito-lab/index.html

    • Related Report
      2015 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.saitama-u.ac.jp/msaito-lab/English/indexEng.html

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2014-11-20   Modified: 2020-03-30  

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