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Effects of Nitrogen in Steel and Insert-metals on Diffusion Bonding Characteristics of Titanium to Steel Joint

Research Project

Project/Area Number 01550558
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 溶接工学
Research InstitutionMuroran Institute of Technology

Principal Investigator

MOMONO Tadashi  Muroran Institute of Technology, Fac, of Eng., Associate Prof., 工学部, 助教授 (10002940)

Project Period (FY) 1989 – 1990
Project Status Completed (Fiscal Year 1990)
Budget Amount *help
¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 1990: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1989: ¥2,000,000 (Direct Cost: ¥2,000,000)
KeywordsDiffusion Bonding / Bond strength / Clad steel / Titanium alloy / Nitriding / Insert-metal / Bond interface / Cromium steel / 表面処理
Research Abstract

The purpose of the present investigation is to make clear the between the bonding characteristics and the formation of interlayer in the diffusion bonding of titanium to steel. We have thoroughly the problem of 1) effect of nitrogen in base metal steel, that is the diffusion bonding with the format ion of TiN layer, and 2) effect of insert-metals, such as Ti-6Al-4V alloy, Fe-Si alloy and Fe-Cr alloy. The results are as follows :
1. Since Kirkendall voids are formed at the Ti side in the diffusion bonded Ti/steel joint, the bond strength of the joint is lowered.
2. Tin layer is formed at the bond interface in diffusion bonded Ti/soft-nitriding steel and Ti/ion-nitriding steel joints. Improvement of the bond strength, however, cannot be accomplished in this case. Since the TiN layer suppresses the diffusion of Fe or Ti into the other base metals as well as TiC, the TiN layer has the effect of preventing the formation of the brittle beta-Ti and Ti-Fe intermetallic compounds.
3. TiC layer is formed at the bond interface in diffusion bonded Ti-6Al-4V alloy/S20C joint bonded at 850^゚C, but TiC and TiFe_2 layers are formed at 1000^゚C. The tensile strength of joints increased with bonding temperature below 900^゚C, but above 900^゚C decreased with rise in bonding temperature. This fact suggests that the TiFe_2 layer coexisting with the TiC layer had more harmful effect on the joint strength than those formed individually.
4. Higher bond strength of 27 kgf/mm^2 was obtained in Ti/Fe-2%Si alloy joint bonded at 1000^゚C for 30min under 0.8kgf/mm^2. This accounts for the pronounced effects of the formation of the TiC layer and the prevention of the Kirkendall voids.
5. The maximum bond strength of 34 kgf/mm^2 was obtained in Ti/Fe-30Cr alloy joint bonded at 1000^゚C for 30min under 0.8kgf/mm^2. The reason why higher bond strength has obtained may be due to the effect of the decrease of unbonded area at 850^゚C and the depression of the growth of the interlayers at 1000^゚C.

Report

(3 results)
  • 1990 Annual Research Report   Final Research Report Summary
  • 1989 Annual Research Report
  • Research Products

    (9 results)

All Other

All Publications (9 results)

  • [Publications] T.Momono: "Effects of Carbon Content on the Diffusion Bonding of Iron and Steel to Titanium" ISIJ International. 30. 978-984 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 桃野 正: "鋼とTiー6Alー4V合金の拡散接合" 鉄と鋼.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Tadashi Momono: "Effects of Carbon Content on the Diffusion Bonding of Iron and Steel to Titanium" ISIJ International. Vol. 30. 978-984 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] Tadashi Momono: "Diffusion Bonding of Steel to Ti-6Al-4V Alloy"

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Momono: "Effects of Carbon Content on the Diffusion Bonding of Iron and Steel to Titanium" ISIJ International. 30. 978-984 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] 桃野 正: "鋼とTiー6Alー4V合金の拡散接合" 鉄と鋼.

    • Related Report
      1990 Annual Research Report
  • [Publications] 馬場寛,桃野正,平井伸治,片山博: "Ti-6Al-4V合金と鋼の拡散接合" 日本金属学会,日本鉄鋼協会両北海道支部合同春季講演大会. (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 桃野正,馬場寛,平井伸治,片山博: "鋼とTi-6Al-4V合金の拡散接合" 材料とプロセス(日本鉄鋼協会講演論文集). 2. 1337 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 桃野正,千葉賢吾,馬場寛,片山博,福田隆: "チタン/鋼拡散接合界面における中間層の性状と鋼中元素の関係" 材料とプロセス(日本鉄鋼協会講演論文集). 3. 355 (1990)

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2016-04-21  

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