| Project/Area Number | 01550634 |
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| Research Category |
Grant-in-Aid for General Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Research Field |
工業物理化学
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| Research Institution | Waseda University |
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Principal Investigator |
OSAKA Tetsuya Waseda Univ., Applied Chem., Prof., 理工学部, 教授 (20097249)
逢坂 哲弥 早稲田大学, 理工学部, 教授
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| Co-Investigator(Kenkyū-buntansha) |
NAKAMURA Sadako Japan Women's Univ., Chemistry, Prof., 家政学部, 教授 (30060619)
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| Project Period (FY) |
1989 – 1990
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| Project Status |
Completed(Fiscal Year 1990)
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| Budget Amount *help |
¥2,300,000 (Direct Cost : ¥2,300,000)
Fiscal Year 1990 : ¥900,000 (Direct Cost : ¥900,000)
Fiscal Year 1989 : ¥1,400,000 (Direct Cost : ¥1,400,000)
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| Keywords | Conductive Polymer / Electropolymerization / Lithium Battery / Compact Battery / Polymer Battery |
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| Research Abstract |
Electropolymerized conductive polymers were investigated for the purpose of applying to the active cathode materials of secondary lithium batteries. Among these polymers, we investigated polyaniline (PAn), polypyrrole (PPy) and polyazulene (PAz), and moreover their copolymers or composite polymers. An electroactive PAn is successfully obtained by electropolymerization from nonaqueous solution of propylene carbonate (PC) containing organic acid and LiClO_4. The most important factor to form electroactive PAn film is the existance of proton from an organic acid. Some other factors of polymerization solution, dielectric constant, viscosity and donor number, were also varied. The correlation between the battery performance using PAn cathode and the electrochemical properties of PAn film is obtained. Further, electrochemical coーpolymerization of pyrrole and azulene is well defined and fairly stoichiometric in PC solution. The battery performance is also investigated. PPy/PAn dual-layer, which has the merits or both films, is tried for the cathode materials. In this case, the PPy underlayer properties strongly affect the battery performance of Li/(PPy/PAn) battery. Finally, the Li ion transported PPy film doped with polymer anion is formed and the possibility of the application if the film th higher energy battery is shown.
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