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A Study on Secondary Lithium Batteries Using Electropolymerized Conductive Polymers

Research Project

Project/Area Number 01550634
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 工業物理化学
Research InstitutionWaseda University

Principal Investigator

OSAKA Tetsuya  Waseda Univ., Applied Chem., Prof., 理工学部, 教授 (20097249)

Co-Investigator(Kenkyū-buntansha) NAKAMURA Sadako  Japan Women's Univ., Chemistry, Prof., 家政学部, 教授 (30060619)
Project Period (FY) 1989 – 1990
Project Status Completed (Fiscal Year 1990)
Budget Amount *help
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 1990: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1989: ¥1,400,000 (Direct Cost: ¥1,400,000)
KeywordsConductive Polymer / Electropolymerization / Lithium Battery / Compact Battery / Polymer Battery
Research Abstract

Electropolymerized conductive polymers were investigated for the purpose of applying to the active cathode materials of secondary lithium batteries. Among these polymers, we investigated polyaniline (PAn), polypyrrole (PPy) and polyazulene (PAz), and moreover their copolymers or composite polymers. An electroactive PAn is successfully obtained by electropolymerization from nonaqueous solution of propylene carbonate (PC) containing organic acid and LiClO_4. The most important factor to form electroactive PAn film is the existance of proton from an organic acid. Some other factors of polymerization solution, dielectric constant, viscosity and donor number, were also varied. The correlation between the battery performance using PAn cathode and the electrochemical properties of PAn film is obtained. Further, electrochemical coーpolymerization of pyrrole and azulene is well defined and fairly stoichiometric in PC solution. The battery performance is also investigated. PPy/PAn dual-layer, which has the merits or both films, is tried for the cathode materials. In this case, the PPy underlayer properties strongly affect the battery performance of Li/(PPy/PAn) battery. Finally, the Li ion transported PPy film doped with polymer anion is formed and the possibility of the application if the film th higher energy battery is shown.

Report

(3 results)
  • 1990 Annual Research Report   Final Research Report Summary
  • 1989 Annual Research Report
  • Research Products

    (34 results)

All Other

All Publications (34 results)

  • [Publications] T.Osaka,K.Naoi,M.Maeda,S.Nakamura: "Effect of Acrylonitrile Composition in NBR on Enhanced Anion DopingーUndoping Process of NBRーGuidedーGrownーPolypyrrole Film Electrode." J.Electrochem.Soc.136. 1385-1388 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 逢坂 哲彌,上山 健一,前田 美知子,中村 節子,: "NBR/ポリピロ-ル複合膜を用いたリチウム二次電池の特性:電解重合時の支持塩による影響" 電気化学. 57. 568-571 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Osaka,K.Ueyama,: "Electrochemical Study on Electropolymerized Polyazulene Film." 電気化学. 57. 572-577 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Osaka,K.Naoi,B.B.Owens,M.Maeda,: "Lithium Secondary Batteries:Role of Polymer Cathode Morphology." Proc.vol.of Sym.on Matl.and Processes for Lithium Batteries,Electrochem.Soc.89ー4. 269-280 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Osaka,W.H.Smyrl K.Naoi,K.Ueyama,: "Impedance Analysis of Ionic Transport in PolypyrroleーPolyazulene copolymer and Its ChargeーDischarge Characteristics." J.Electrochem.Soc.137. 494-499 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 逢坂 哲彌: "機能材料としての導電性高分子薄膜合成と評価" 電気化学. 58. 218-226 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Osaka,T.Nakajima,K.Naoi,B.B.Owens,: "Electroactive Polyaniline Film Deposited from NonーAqueous Media II:Effect of Acid Concentration in Solution." J.Electrochem.Soc.137. 2139-2142 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Osaka,T.Nakajima,K.Shiota,B.B.Owens: "Recharqeable Lithium/Polymer Cathode Batteries." Proc.Vol.of Sym.on Recharqeable Lithium Batteries,Electrochem.Soc.90ー5. 170-175 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Osaka,K.Ouchi,T.Fukuda: "An Application of Polypyrrole Films Electropolymerized in NaOH Aqueous Solution to NonーLinear MIM Devices." Chem.Lett.1900. 1535-1538 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Osaka: "Rechargeable Lithium/Polymer Batteries:Application of Electropolymerized Polymer Films to Lithium Batteries." Workshop Proc.by EPRI and US DOE. 4 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 逢坂 哲彌,小山 昇,大坂 武男: "電気化学法ー基礎測定マニュアルー" 講談社サイエンティフィク, 199 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] 逢坂 哲彌,小山 昇,: "電気化学法ー応用測定マニュアルー" 講談社サイエンティフィク, 283 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Osaka, K. Naoi, M. Maeda, S. Nakamura: "Effect of Acrylonitrile Composition in NBR on Enhanced Anion Doping-Undoping Process of NBR-Guided-Grown-Polypyrrole Film Electrode." J. Electrochem. Soc. 136-5. 1385 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] M. Maeda, S. Nakanura, K. Ueyama, T. Osaka: "Characteristics of Secondary Lithium Batteries Using an NBR/Polypyrrole Cathode : Effect of Anions at Polymerization." Denki Kagaku. 57-6. 568 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Osaka, K. Ueyama: "Electrochemical Study on Electropolymerized Polyazulene" Denki Kagaku. 57-6. 572 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. Naoi, B. B. Owens, M. Maeda, T. Osaka: "Lithium Secondary Batteries : Role of Polymer Cathode Morphology." Proc. Vol., Electrochem. Soc.89-4. 269 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] K. Naoi, K. Ueyama, T. Osaka, W. H. Smyrl,: "Impedance Analysis of Ionic Transport in Polypyrrole-polyazulene Copolymer and Its Charge-Discharge Characteristics" J. Electrochem. Soc. 137-2. 494 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Osaka: "Formation and Evaluation of Conducting Polymer Thin Films as a Functional Materials." Denki Kagaku. 58-3. 218 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Osaka, T. Nakajima, K. Shiota, B. B. Owens: "Rechargeable Lithium/Polymer Cathode Batteries." Proc. Vol., Electrochem. Soc.90-5. 170 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Osaka, T. Nakajima, K. Naoi, B. B. Owens: "Electroactive Polyaniline Film Deposited from Nonー Aqueous Media II : Effect of Acid Concentration in Solution." J. Electrochem. Soc.137-7. 2139 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Osaka, K. Ouchi, T. Fukuda: "An Application of polypyrrole Films Electropolymerized in NaOH Aqueous Solution to NonーLinear MIM Devices." Chem. Lett.1990. 1535 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T. Osaka: "Rechargeable Lithium/Polymer Batteries : Application of Electropolymerized Polymer Films to Lithium Batteries." Workshop Proc. by EPRI and US DOE. RP2415-22. C4 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1990 Final Research Report Summary
  • [Publications] T.Osaka,T.Nakajima,K.Shiota,B.B.Owens: "Rechargeable Lithium/Polymer Cathode Batteries." Proc.Vol.,Electrochem.Soc.90ー5. 170-175 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Osaka,T.Nakajima,K.Naoi,B.B.Owens: "Electroactive Polyaniline Film Deposited from NonーAqueous Media II: Effect of Acid Concentration in Solution." J.Electrochem.Soc.137ー7. 2139-2142 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Osaka,K.Ouchi,T.Fukuda: "An Application of Polypyrrole Films Electropolymerized in NaOH Aqueous Solution to NonーLinear MIM Devices." Chem.Lett.1990. 1535-1538 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Osaka,: "Rechargeable Lithium/Polymer Batteries: Application of Electropolymerized Polymer Films to Lithium Batteries." Workshop Proc.by EPRI and US DOE. RP2415ー22. C4 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] T.Osaka,K.Naoi,M.Maeda,S.Nakamura: "Effect to Acrylonitrile Composition in NBR on Enhanced Anion Doping-Undoping Process of NBR-Guided-Grown-Polypyrrole Film Electrode." J.Electrochem.Soc.136. 1385-1388 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 逢坂哲彌,上山健一,前田美知子,中村節子: "NBR/ポリピロ-ル複合膜を用いたリチウム二次電池の特性:電解重合時の支持塩による影響" 電気化学. 57. 568-571 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Osaka,K.Ueyama,: "Electrochemical Study on Electropolymerized Polyazulene Film." 電気化学. 57. 572-577 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Osaka,K.Naoi,B.B.Owens,M.Maeda,: "Lithum Secondary Batteried:Role of Polymer Cathode Morphology." Proc.of Sym.on Matl.and Processes for Lithium Batteries. 89-4. 269-280 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] T.Osaka,W.H.Smyrl K.Naoi,K.Ueyama.: "Impedance Analysis of Ionic Transport in Polypyrrole-Polyazulene copolymer and Its Charge-Discharge Characteristics." J.Electrochem.Soc.137. 494-499 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 逢坂哲彌: "機能材料としての導電性高分子薄膜合成と評価" 電気化学. 58. 218-226 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 逢坂哲彌,小山昇,大坂武男: "電気化学法-基礎測定マニュアル-" 講談社サンエンティフィク, P.199 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 逢坂哲彌,小山昇: "電気化学法-基礎測定マニュアル-" 講談社サンエンティフィク, P.283 (1990)

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2018-02-02  

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