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Development of anvil with sintered diamond core for high pressure high temperature experiments

Research Project

Project/Area Number 01840029
Research Category

Grant-in-Aid for Developmental Scientific Research

Allocation TypeSingle-year Grants
Research Field 鉱物学(含岩石・鉱床学)
Research InstitutionGakushuin University (1990-1991)
Kanazawa University (1989)

Principal Investigator

AKAOGI Masaki  Gakushuin Univ., professor, 理学部, 教授 (30126560)

Co-Investigator(Kenkyū-buntansha) NAGASAWA Hiroshi  Gakushuin Univ., professor, 理学部, 教授 (80080464)
Project Period (FY) 1989 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥8,100,000 (Direct Cost: ¥8,100,000)
Fiscal Year 1991: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1990: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1989: ¥6,500,000 (Direct Cost: ¥6,500,000)
KeywordsUltra-high pressure / sintered diamond / phase transition / Bridgman anvil / 高温高圧実験 / アンビル
Research Abstract

The purpose of this research project is to develop anvils with sintered diamond cores and to generate high pressures and high temperatures using the new anvils. We have developed two kinds of Bridgman anvils which consist of tungsten carbide with sintered diamond core. The diameters of tlie anvils are 26 and 20 mm. We have also constructed a 600-ton press, which is used to compress the Bridgman anvils to generate high pressures. Using these apparatus, the following results have been obtained during this project term.
1. We have successfully generated pressure up to about 20.5 GPa using the new anvils. This generated pressure is much higher than those attained by Bridgman anvils made of tungsten carbide. The new anvils have also been used for high pressure high temperature experiments up to 17 GPa and 1400 ゚C.
2. The following phase transition experiments have been caried out. Phase boundaries in KAlSi_3O_8 feldspar to K_2Si_4O_9 wadeite + Al_2SiO_5 kyanite + SiO_2 coesite (or stishovite) and further to KAlSi_3O_8 hollandite have been determined. Stability field of CaAl_2O_4 calcium ferrite has been examined. The decomposition boundary of CaFeSi_2O_6 clinopyroxene to CaSiO_3 perovskite + Fe_2SiO_4 spinel +SiO_2 stishovite has also been determined. These phase boundaries are of geophysical and geochemical importance in the lower mantle.
3. As a related topic, the rutile-alphaPbO_2 transition boundary in TiO_2 has accurately been determined by in situ x-ray diffraction techniques at high pressure and high temperature. This boundary is important for pressure calibration at high temperatures.

Report

(4 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • 1989 Annual Research Report
  • Research Products

    (30 results)

All Other

All Publications (30 results)

  • [Publications] Akaogi,M.: "The olivine-modified spinel-spinel transitions in the system Mg_2SiO_4-Fe_2SiO_4:calorimetric measurements,thermochemical calculation and geophysical application" J.Geophys.Res.94. 15671-15685 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Akaogi,M.: "The ZnSiO_3 clinopyroxene-ilmenite transition:heat capacity,enthalpy of transition,and phase equilibria" Phys.Chem.Minerals. 17. 17-23 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Akaogi,M.: "Thermodynamics and stability relations of mantle minerals" Dynamic Processes of Material Transport and Transformation in the Earth's Interior,(F.Marumo,ed.),Terra Sci.Publ.239-251 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Ito,E.: "Negative pressure-temperature slopes for reactions forming MgSiO_3 perovskite from calorimetry" Science. 249. 1275-1278 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Akaogi,M.: "Bridgman anvil with a sintered diamond core for phase transformation studies at high pressures and high temperatures" Proc.Japan Acad.67. 61-65 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Akaogi,M.: "High-pressure high-temperature stability of α PbO_2-type TiO_2 and MgSiO_3 majorite:calorimetric and in situ x-ray diffraction studies" High-Pressure Reseach:Application to Earth and Planetary Sciences(Y.Syono & M.H.Manghnani,eds),Terra Sci Publ.(1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] McMillan, P., Akaogi, M., Ohtani, E., Williams, Q., R. Nieman and Sato, R.: "Cation disorder in garnet along the Mg_3Al_2Si_3O_<12>Mg_4Si_4O_<12> join : an infrared, Raman and NMR study" Phys. Chem. Minerals. 16. 428-435 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Akaogi, M., Ito, E. and Navrotsky, A.: "The olivine-modified spinel-spinel transitions in the system Mg_2SiO_4-Fe_2SiO_4 : calorimetric measurements, thermochemical calculation and geophysical application" J. Geophys. Res.94. 15671-15685 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Akaogi, M., Yusa, H., Ito, E., Yagi, T., Suito, K. and J. T. Iiyama: "The ZnSiO_3 clinopyroxene-ilmenite transition : heat capacity, enthalpy of transition, and phase equilibria" Phys. Chem. Minerals. 17. 17-23 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Iiyama, J. T., Suzuki, K., Akaogi, M., Nishiyama, T., Fujimoto, K. and Kato, Y.: "Material transfer during metamorphic processes : experimental approaches" Dynamic Processes of Material Transport and Transformation in the Earth's Interior, (F. Marumo, ed.), Terra Sci. Publ. 119-137 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Akaogi, M.: "Thermodynamics and stability relations of mantle minerals" Dynamic Processes of Material Transport and Transformation in the Earth's Interior, (F. Marumo, ed.), Terra Sci. Publ. 239-251 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Ito, E., Akaogi, M., Topor, L. and Navrotsky, A.: "Negative pressure-temperature slopes for reactions forming MgSiO_3 perovskite from calorimetry" Science. 249. 1275-1278 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Akaogi, M. and Yamazaki, T.: "Bridgman anvil with a sintered diamond core for phase transformations tidies at high pressures and high temperatures" Proc. Japan Acad.67. 61-65 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Matsui, M. and Agaogi, M.: "Molecular dymamics simulation for the structural and physical properties of the four polymorphs of TiO_2" Mole. Simul.6. 239-244 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] McMillan, P., Akaogi, M. Sato, R., Poe, B. and Foley, J.: "Hydroxyl groups in beta-Mg_2SiO_4" Amer. Mineral.76. 354-360 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Akaogi, M., Kusaba, K., Susaki, J., Yagi, T., Matsui, M., Kikegawa, T., Yusa, H., and Ito, E.: "High-pressure high-temperature stability of alphaPbO_2-type TiO_2 and MgSiO_3 majorite : calorimetric and in situ x-ray diffraction studies" High-Pressure Research : Application to Earth and Planetary Sciences (Y. Syono & M. H. Manghnani, eds.), Terra Sci. Publ.(1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Uchiyama, Y., Yagi, T., Akaogi, M. and Ito, E.: "Isothermal compression curve of MgSiO_3 tetragonal garnet" Phys. Earth Planet. Inter.(1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Akaogi,M.: "Thermodynamics and stability relations of mantle minerals," Dynamic Processes of Material Transport and Transformation in the Earth's Interior (F.Marumo,ed.),Terra Sci.Publ.239-251 (1990)

    • Related Report
      1991 Annual Research Report
  • [Publications] Akaogi,M.: "Bridgman anvil with a sintered diamond core for phase transformation studies at high pressures and high temperatures," Proc.Japan Acad.67. 61-65 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Matsui,M.: "Molecular dynamics simulation of the structural and physical properties of the four polymorphs of TiO_2," Molecular Simulation. 6. 239-244 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] McMillan,P.F.: "Hydroxyl groups in β-Mg_2SiO_4" Amer.Mineral.76. 354-360 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Akaogi,M.: "High-pressure high-temperature stability of αPbO_2-type TiO_2 and MgSiO_3 majorite:calorimetric and in situ x-ray diffraction studies," High-Pressure Research:Application to Earth and Planetary Sciences (Y.Syono and M.H.Manghnani,eds.),Terra Sci.Publ.(1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] Akaogi,M.: "The ZnSiO_3 clinopyroxeneーilmenite transition:heat capacity,enthalpy of transition and phase equilibria." Phys.Chem.Minerals. 17. 17-23 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Ito,E.: "Negative pressureーtemperature slopes for reactions forming MgSiO_3 perovskite from calorimetry." Science. 249. 1275-1278 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Akaogi,M.: "Thermodynamics and stability relations of mantle minerals." Dynamic Processes of Material Transport and Transformation in the Earth's Interior.(1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] Matsui,M.: "Molecular dynamics simulation of the structural and physical properties of the four polymorphs of TiO_2." Mole.Simulation. (1991)

    • Related Report
      1990 Annual Research Report
  • [Publications] Akaogi,M.: "The olivine-modified spinel-spinel transitions in the system Mg_2SiO_4-Fe_2SiO_4:calorimetric measurements,ther-mochemical calculation and geophysical application." J.Geophts.Res.94. 15671-15685 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] McMillan,P.: "Cation disorder in garnets along the Mg_3Al_2Si_3O_<12>-Mg_4Si_4O_<12> join:an infrared,Raman and NMR study." Phys.Chem.Minerals. 16. 428-435 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] Akaogi,M.: "The ZnSiO_3 clinopyroxene-ilmenite transition:heat capa-city,enthalpy of transition,and phase equilibria." Phys.Chem.Minerals. 17. 17-23 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] Akaogi,M.: "Thermodynamics and stability relations of mantle minerals" Dynamic Processes of Material Transport and Transformation in the Earth's Interior(Terra Scientific Publishing Co.). (1990)

    • Related Report
      1989 Annual Research Report

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Published: 1989-04-01   Modified: 2019-02-15  

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