• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of Dinuclear and Multinuclear Transition Metal Complexes with Novel Properties

Research Project

Project/Area Number 02640471
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 無機・錯塩・放射化学
Research InstitutionFaculgy of Science, Kanazawa University

Principal Investigator

UEHARA Akira  Fauclty of Science, Kanazawa University, Professor, 理学部, 教授 (30019484)

Co-Investigator(Kenkyū-buntansha) 鈴木 正樹  金沢大学, 理学部, 助教授 (20091390)
Project Period (FY) 1990 – 1991
Project Status Completed (Fiscal Year 1991)
Budget Amount *help
¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1991: ¥100,000 (Direct Cost: ¥100,000)
Fiscal Year 1990: ¥1,900,000 (Direct Cost: ¥1,900,000)
KeywordsDinuclear Cobalt Complexes / Dinuclear Iron Complexes / Dinuclear Manganese Complexes / Tetranuclear Manganese Complexes / Molecular Oxygen Complexes / Solid-phase Syntheses / Magnetic Interaction / 集積型金属錯体 / 二核クロム錯体
Research Abstract

(1) Design and Preparation of Tetranuclear Manganese Complexes for the Models of Manganese Clusters Involved in Oxygen Evolving Center (OEC) in Photo-system II : Novel tetranuclear manganese complexes with 1, 3-Bis[bis (2-pyridyl-methyl) amino]-2-propanol (Htpdp) and 1, 5-Bis[bis (2-pyridylmethyl) amino]-3-pentanol (Htmdp) were newly prepared and their structures were clarified. The complexes are characteristic of having two di (mu- oxo) Mn_2 (III, IV) units. Especially, the latter tmdp complex contains two water molecules in close proximity to the di (mu-oxo) Mn_2 (III, IV) units. Therefore, the complex is worth noting sa effective model for the tetranuclear manganese clusters involved in OEC.
(2) Preparation of Dinuclear Cobalt and Iron Complexes Which Reversibly React with Molecular Oxygen : The dinuclear cobalt (II, II) complex [Co_2 (tpdp or tmdp) (CH_3COO)]^<2+> was newly prepared. The complex was found to react with molecular oxygen to form mu -peroxo complex. In addition, the dinuclear iron (II, II) complex containing N, N, N', N'-Tetrakis[2-(6-methylpyridyl) methyl]-1, 3-diamino-propane-2-ol (6Me-Htpdp) was newly prepared. The complex is very interesting in that it reversibly reacts with molecular oxygen at -20゚C. We are trying to prepare the oxygen complex which can be isolated even under ambient conditions.
(3) Thermal Reactions of Solid Metal Complexes : For the construction of novel multinuclear metal complexes, a new solid-phase synthetic method must be developed in addition to usual liquid-phase method. To do this, the solid-phase thermal reactions of various metal complexes should be fully understood. The structural changes (especially isomerization) of a variety of nickel (II), cobalt(III), and chromium (III) complexes were investigated. The results obtained in the present study will give fundamental data for the development of a new synthetic method.

Report

(3 results)
  • 1991 Annual Research Report   Final Research Report Summary
  • 1990 Annual Research Report
  • Research Products

    (39 results)

All Other

All Publications (39 results)

  • [Publications] M.Suzuki,T.Sugisawa,and A.Uehara: "Dinuclear Cobalt(II) Complexes Containing 1,3-(or 1,5-)-Bis〔bis(2-pyridylmethyl)amino〕-2-propanolato (or-3-pentanolato): Preparation and Reaction with Molecular Oxygen" Bull.Chem.Soc.Jpn.63. 1115-1120 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M.Suzuki,H.Senda,M.Suenaga,T.Sugisawa,and A.Uehara: "Synthesis and Characterization of a Novel Linear Tetranuclear Manganese Complexes with Three Different Oxidation State(II,III,IV,II)" Chem.Lett.923-926 (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Y.Ihara,Y.Satake,Y.Fujumoto,H.Senda,M.Suzuki,and A.Uegara: "X-ray Crystal Structures of Octahedral Diaquabis(N,N-dialkylethylendiamine)nickel(II) Complexes Possessing Elongated Nickel(II)-Nitrogen Bonds along Axial Direction" Bull.Chem.Soc.Jpn.64. 2349-2352 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Y.Ihara,Y.Satake,M.Suzuki,and A.Uehara: "cis-trans Isometism among the Octahedral DIaqua(N,N- or N,N'-Dialkylethylenediamine)nickel(II) Complexes and Their Thermal Reaction Products" Bull.Chem.Soc.Jpn.64. 3647-3652 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M.Suzuki,Y.Hayashi,K.Munezawa,M.Suenaga,H.Senda,and A.Uehara: "Synthesis and Characterization of a Novel Dimer of Di(μ-oxo)-manganese Dimers with Two Coordinated Water Molecules in (III,IV,III,IV) Oxidation State" Chem.Lett.1929-1932 (1991)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Y.Hayashi,M.Suzuki,A.Uehara,Y.Mizutani,and T.Kitagawa: "(μ-Alkoxo)-diiron(II,II) Complexes of N,N,N',N'-Tetrakis〔2-(6-methylpyridyl)methyl〕-1,3-diaminopropane-2-olate and the Reversible Formation of the O_2-Adduct" Chem.Lett.91-94 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] E.Itoh,K.Yamamoto,M.Funato,M.Suzuki,and A.Uehara: "Preparation of Chromium(III) Complexes with a Series of Tetraazacycloalkanes,〔12〕aneN_4 to 〔16〕aneN_4,and Solid-state Thermal Isomerization of cis-〔CrCl_2(〔15〕- or 〔16〕aneN_4)〕^+" Thermochim.Acta.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] E.Itoh,M.Suzuki,and A.Uehara: "Thermal Isomerization of cis-〔CrCl_2(〔15〕aneN_4)〕SCN in the Soli State" Thermochim.Acta.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Y.Ihara,S.Naride,and A.Uehara: "Thermal Reactions of Nickel(II) Complexes Containing Optically Active 1,2-Cyclohexanediamine in Solid State.Comparison with Those of the Corresponding Complexes with the Racemate" Thermochim.Acta.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S.Yamaguchi,Y.Hayashi,M.Suzuki,and A.Uehara: "Solid-phase Thermal cis-trans Isomerizationof the Bis(diamine) and Tetraazacycloalkene Complexes of the Type 〔(Co or Cr)_2X_2-〔(diamine)_2 or (mac)〕^+" Thermochim.Acta.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Y.Satake,Y.Ihara,H.Senda,M.Suzuki,and A.Uehara: "Study on cis-Folded Macrocyclic Nickel(II) Complex.Molecular Structureand Thermal Reaction of cis-Diaqua(1,4,7,11-tetraaza-cyclotetradecane)nickel(II) Chloride" Inorg.Chem.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. Suzuki, T. Sugisawa, and A. Uehara.: "Dinuclear Cobalt (II) Complexes Containing 1, 3-(or 1, 5-)-Bis[bis (2-pyridylmethyl)-amino]-2-propanolato (or -3-pentanolato) : Preparation and Reaction with Molecular Oxygen." Bull. Chem. Soc. Jpn.63. 1115-1120 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. Suzuki, H. Senda, M. Suenaga, T. Sugisawa, and A. Uehara.: "Synthesis and Characterization of a Novel Linear Tetranuclear Manganese Complexes with Three Different Oxidation State (II, III, IV, II)." Chem. Lett.923-926 (1990)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Y. Ihara, Y. Satake, Y. Fujimoto, H. Senda, M. Suzuki, and A. Uehara.: "X-ray Crystal Structures of Octahedral Diaquabis (N, N-dialkylethylenediamine)-nickel (II) Complexes Possessing Elongated Nickel (II)-Nitrogen Bond along Axial Direction." Bull. Chem. Soc. Jpn.64. 2349-2352 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Y. Ihara, Y. Satake, M. Suzuki, and A. Uehara.: "cis-trans Isomerism among the Octahedral Diaqua (N, N- or N, N' -dialkylethylene-diamine) nickel (II) Complexes and Their Thermal Reaction Products." Bull. Chem. Soc. Jpn.64. 3647-3652 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M. Suzuki, Y. Hayashi, K. Munezawa, M. Suenaga, H. Senda, and A. Uehara: "Synthesis and Characterization of a Novel Dimer of Di (mu -oxo) manganese Dimers with Two Coordinated Water Molecules in (III, IV, III, IV) oxidation State." Chem. Lett.1929-1932 (1991)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Y. Hayashi, M. Suzuki, A. Uehara, Y. Mizutani, and T. Kitagawa.: "(mu -Alkoxo)-diiron (II, II) Complexes of N, N, N', N'-Tetrakis[2-(6-methylpyridyl)-methyl]-1, 3-diaminopropane-2-olate and the Reversible Formation of the O_2 Adduct." Chem. Lett.91-94 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] E. Itoh, K. Yamamoto, M. Funato, M. Suzuki, and A. Uehara.: "Preparation of Chromium (III) Complexes with a Series of Tetraazacycloalkanes, [12]aneN_4 to [16]aneN_4, and Solid-state Thermal Isomerization of cis-[CrCl_2-([15]- or [16]aneN_4) ]^+." Thermochim. Acta.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] E. Itoh, M. Suzuki, and A. Uehara.: "Thermal Isomerization of cis-[CrCl_2 ([15]aneN_4)]SCN in the Solid State." Thermochim. Acta.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Y. Ihara, S. Naride, and A. Uehara.: "Thermal Reactions of Nickel (II) Complexes Containing Optically Active 1, 2-Cyclohexanediamine in Solid State. Comparison with Those of the Corresponding Complexes with the Racemate." Thermochim. Acta.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] S. Yamaguchi, Y. Hayashi, M. Suzuki, and A. Uehara: "Solid-phase Thermal cis-trans Isomerizaion of the Bis (diamine) and Tetraazacycloalkane complexes of the Type [(Co or Cr)_2X_2 ((diamine)_2 or (mac))]^+." Thermochim. Acta.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] Y. Satake, Y. Ihara, H. Senda, M. Suzuki, and A. Uehara.: "Study on cis- Folded Macrocyclic Nickel (II) Complex. Molecular Structure and Thermal Reaction of cis-Diaqua (1, 4, 7, 11-tertraazacyclotetradecane) nickel (II) Chloride." Inorg. Chem.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1991 Final Research Report Summary
  • [Publications] M.Suzuki,T.Sugisawa,and A.Uehara: "Dinuclear Cobalt(II)Complexes Containing 1,3ー(or1,5ー)ーBis[bis(2ーpyridylmethyl)amino]ー2ーpropanolato(orー3ーpentanolato):Preparation and Reaction with Molecular Oxygen" Bull.Chem.Soc.Jpn.63. 1115-1120 (1990)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Suzuki,H.Senda,M.Suenaga,T.Sugisawa,and A.Uehara: "Synthesis and Characterization of a Novel Linear Tetranuclear Manganese Complexes with Three Different Oxidation State(II,III,IV,II)" Chem.Lett.923-926 (1990)

    • Related Report
      1991 Annual Research Report
  • [Publications] Y.Ihara,Y.Satake,Y.Fujimoto,H.Senda,M.Suzuki,and A.Uehara: "Xーray Crystal Structures of Octahedral Diaquabis(N,Nーdialkylethylenediamine)nickel(II)Complexes Possessing Elongated Nickel(II)ーNitrogen Bonds along Axial Direction" Bull.Chem.Soc.Jpn.64. 2349-2352 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Y.Ihara,Y.Satake,M.Suzuki,and A.Uehara: "cisーtrans Isomerism among the Octahedral Diaqua(N,Nーor N,N'ーdialkylethylenediamine)nickel(II)Comprexes and Their Thermal Reaction Products" Bull.Chem.Soc.Jpn.64. 3647-3652 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Suzuki,Y.Hayashi,K.Munezawa,M.Suenaga,H.Senda,and A.Uehara: "Synthesis and Characterization of a Novel Dimer of Di(μーoxo)ーmanganese Dimers with Two Coordinated Water Molecules in(III,IV,III,IV)Oxidation State" Chem.Lett.1929-1932 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Y.Hayashi,M.Suzuki,A.Uehara,Y.Mizutani,and T.kitagawa: "(μーAlkoxo)ーdiiron(II,II)Complexes of N,N,N',N'ーTetrakis[2ー(6ーmethylpyridyl)methyl]ー1,3ーdiaminopropaneー2ーolate and the Reversible Formation of the O_2ーAdduct" Chem.Lett.91-94 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] E.Itoh,K.Yamamoto,M.Funato,M.Suzuki,and A.Uehara: "Preparation of Chromium(III)Complexes with a Series of Tetraazacycloalkanes,[12]aneN_4 to[16]aneN_4,and Solidーstate Thermal Isomerization of cisー[CrCl_2([15]ーor[16]aneN_4)]^+" Thermochim.Acta,.

    • Related Report
      1991 Annual Research Report
  • [Publications] E.Itoh,M.Suzuki,and A.Uehara: "Thermal Isomerization of cisー[CrCl_2([15]aneN_4)]SCN in the Solid State" Thermochim.Acta,.

    • Related Report
      1991 Annual Research Report
  • [Publications] Y.Ihara,S.Naride,and A.Uehara: "Thermal Reactions of Nickel(II)Complexes Containing Optically Active 1,2ーCyclohexanediamine in Solid State.Comparison with Those of the Corresponding Complexes with the Racemate" Thermochim.Acta,.

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Yamaguchi,Y.Hayashi,M.Suzuki,and A.Uehara: "Solidーphase Thermal cisーtrans Isomerizationof the Bis(diamine)and Tetraazacycloalkane Complexes of the Type[(Co or Cr)_2X_2ー[(diamine)_2or(mac)]]^+" Thermochim.Acta,.

    • Related Report
      1991 Annual Research Report
  • [Publications] Y.Satake,Y.Ihara,H.Senda,M.Suzuki,and A.Uehara: "Study on cisーFolded Macrocyclic Nickel(II)Complex.Molecular Structure and Thermal Reaction of cisーDiaqua(1,4,7,11ーtatraazacyclotetradecane)nickel(II)Chloride" Inorg.Chem.

    • Related Report
      1991 Annual Research Report
  • [Publications] M.Kaneda,M.Suzuki,and A.Uehara: "Thermal Reactions of Metal Complexes under Quasiーisobaric andーisothermal Conditions.5.Thermal Behavior of Molybdenum(0) Dinitrogen Complexes in the Solid State." Thermochim.Acta. 138. 161-166 (1989)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Johda,M.Suzuki,and A.Uehara: "Preparation of μーCyano Dinuclear Chromium(III) Complexes M^I]F(en or tn)_2Cr(CN)Cr(CN)_5]from the Doubly Complexed Salts of the Form M^I[CrF(H_2O)(en or tn)_2]Cr(CN)_6]." Bull.Chem.Soc.Jpn.62. 738-744 (1989)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Suzuki,T.Sugisawa,H.Senda,H.Oshio,and A.Uehara: "Synthesis and Characterization of a Novel Tetranuclear Manganese(II,III,III,II)Mixed Valence Complex." Chem.Lett.1091-1094 (1989)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Suzuki,T.Sugisawa,and A.Uehara: "Dinuclear Cobalt(II) Complexes Containing 1,3ー(or 1,5ー)Bis[bis(2ーpyridylmethyl)amino]ー2ーpropanolate(or ー3ーpentanolate):Preparation and Reaction with Molecular Oxygen." Bull.Chem.Soc.Jpn.63. 1115-1120 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] M.Suzuki,H.Senda,M.Suenaga,T.Sugisawa,A.Uehara: "Synthesis and Characterization of a Novel Linear Tetranuclear Manganese Complex with Three Different Oxidation States(II,III,IV,II)." Chem.Lett.923-926 (1990)

    • Related Report
      1990 Annual Research Report
  • [Publications] Y.Ihara,Y.Sataka,Y.Fujimoto,H.Senda,M.Suzuki,and A.Uehara: "XーRay Crystal Structure of Octahedral Diaqua(n,Nーdialkylーethylenediamine)nickel(II)ーNitrogen Bonds along Axial Direction." Bull.Chem.Soc.Jpn.64. (1991)

    • Related Report
      1990 Annual Research Report

URL: 

Published: 1990-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi