• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Optoelectronic Materials Based on Physical Chemistry

Research Project

Project/Area Number 03303008
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 工業物理化学・複合材料
Research InstitutionThe University of Tokyo

Principal Investigator

FUJISHIMA Akira  Faculty of Engineering, University of Tokyo : Profesor, 工学部, 教授 (30078307)

Co-Investigator(Kenkyū-buntansha) YANAGIDA Shozo  Faculty of Engineering, Osaka University : Professor, 工学部, 教授 (10029126)
IIZAWA Masuo  Faculty of Bioscience and Biotechnology, Tokyo Inst. of Technology : Professor, 生命理工学部, 教授 (00016742)
IRIE Masahiro  Inst. Advancd Material Study, Kyushu University : Professor, 機能物質科学研究所, 教授 (30001986)
YAMAZAKI Iwao  Faculty of Engineering, Hokkaido University : Professor, 工学部, 教授 (80002111)
UOSAKI Kohei  Faculty of Science, Hokkaido Univeersity : Professor, 理学部, 教授 (20133697)
Project Period (FY) 1991 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥9,300,000 (Direct Cost: ¥9,300,000)
Fiscal Year 1993: ¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 1992: ¥2,700,000 (Direct Cost: ¥2,700,000)
Fiscal Year 1991: ¥3,700,000 (Direct Cost: ¥3,700,000)
Keywordsindustrial physical chiemistry / opto-electonics / photo-functinal molecule / molecular desigh / optical information strage / biosensor / control of interfacial function / photochemical process / オプトエレクロニクス / オプトエレクトロニクス材料 / 光機能材料 / 分子素子 / 量子光電気化学 / 界面機能
Research Abstract

Anticipating for the coming changes in the 21st century, a century predicted to be the "ge of light", all members of our group have been interested light-related chemical phenomena. We have accomplished a variety of pioneering tasks in this field. Currently, we are engaged in basic and applied studies on the phenomena specifically occurring at the interface between a solid(a semiconductor or metal)and a solution or a gas, upon the application of light energy to the interface. We are expliring system shows characteristics distinctly different from those of any one phase, which at times have given us the delight of observing an unexpected phenomenon. Some of our recent results are summarized as follows.
Nanometer order chemical research with STM and AFM, these "atom-watching"mictoscopes prove their high research potential with their mechanisms, functions and pronciples. In a study performed in this area, an STM is used to directly observe the interface between a layred compound, exhibiting charge density waves and an electrolyte. Efforts in the development of information recording materials which uses these microscopes to write and erase are under way.
Metallization by(phto)chemical reactions of semiconductor thin films, concerns the metallization of various insulating substrates. As we see typically in the metallization of printed circuit boards, thes is one of the important processes in modern technology. We have recently developed a new metallization technique that uses(photo)chemical reactions of a certain of semiconductor thin films.

Report

(4 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • 1991 Annual Research Report
  • Research Products

    (69 results)

All Other

All Publications (69 results)

  • [Publications] T.Amemiya: "Faradaic Charge Transfer with Double-Layer Charging and/or Adsorption-Related Chartging at Polymer-Modified Electrodes as Observed by Color Impedance Spectroscopy" J.Phys.Chem.97. 9736-9740 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Morigaki: "In-Situ Electrochemical Actinometry Using an Azo Monolayer Film" Ber.Bunsenges.Phys.Chem.97. 860-864 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] L.A.Nagahara: "Scanning Probe and Transmission Electron Microscopy Observations of Cobalt Naphthalocyanine Molecules Deposited onto a NaCl Substrate" J.Vac.Sci.Technol.A. 11. 781-785 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] L.A.Nagahara: "Effects of HF Solution in the Electroless Deposition Process on Silicon Surfaces" J.Vac.Sci.Technol.A. 11. 763-767 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] R.Baba: "Characterization of the Molecular Orientation in LB Films of Rhodamine B Derivatives by the Optical Second Harmonic Generation Coherent Interferometry" Denki Kagaku. 61. 1030-1031 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Morigaki: "Electrochemical Counting of Photon Number Using the Assembled Monolayer Film of Azo Compound" Sensors and Actuators B. 13-14. 226-229 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] O.Sato: "Self-Ordered Film of Hamicyanine Derivative Characterized by Phase-Sensitive Optical Second-Harmonic Generation" Jpn.J.Appl.Phys.32. 1201-1203 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-storing Materials.Part II.Copper-Modified Palladium Electrode" J.Electroanal.Chem.348. 459-464 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Amemiya: "Dynamics of Faradaic Processed in Polypyrrole/Poly-styrenesulfonate Composite Films in the Presence and Absence a of Redox Species in Aqueous Solutions" J.Phys.Chem.97. 4192-4195 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Amemiya: "Frequency-Resolved Faradaic Processes in Polypyrrole Films Observed by Electromodilation Techniques:Electrochemical Impedance and Color Impedance Spectroscopies" J.Phys.Chem.97. 4187-4191 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Z.F.Liu: "Direct Observation of the Secondary Structure of Unfolded Pseudomonas-Cytochrome C_<551> by Scanning Tunneling Microscopy" Surf.Sci.Lett.284. L411-L415 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-storing Materials.Part I.The Effect of Hydrogen Absorption on the Electrochemical Behavior on Palladium Electrodes" J.Electroaanal.Chem.345. 445-456 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Ameriya: "Faradaic Charge Transfer with Double-Layr Charging and/or Adsorption-Related Chartging at Polymer-Modified Electrodes as Observed by Color Impedance Spectroscopy" J.Phys.Chem. 97(38). 9736-9740 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Morigaki: "In-Situ Electrochemical Actinometry Using an Azo Monolayr Film" Ber.Bunsenges.Phys.Chem. 97(7). 860-864

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] L.A.Nagahara: "Scanning Probe and Transmission Electron Microscopy Observations of Cobalt Naphthalocyanine Molecules Deposited onto a NaCl Substrate" J.Vac.Sci.Technol.A. 11(4). 781-785 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] L.A.Nagahara: "Effects of HF Solution in the Electroless Deposition Process on Silicon Surfaces" J.Vac.Sci.Technol.A. 11(4). 763-767 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] R.Baba: "Characterization of the Molecular Orientation in LB Films of Rhodamine B Derivatives by the Optical Second Harmonic Generation Coberent Interferometry" Denki Kagaku. 61(8). 1030-1031 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Morigaki: "Electrochemical Counting of Photon Number Using the Assembled Monolayr Film of Azo Compound" Sensors and Actuators B. 13-14. 226-229 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] O.Sato: "Self-Ordered Film of Hamicyanine Derivative Characterized by Phase-Sensitive Optical Second-Harmonic Generation" Jpn.J.Appl.Phys. 32(1), 3A. 1201-1203 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrorgen-storing Materials. Part II.Copper-Modified Palladium Electrode" J.Electroanal.Chem. 348. 459-464 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Ameriya: "Dynamics of Faradaic Processed in Polypyrrole/Polystirenesulfonate Composite Films in the Presence and Absence of a Redox Species in Aqueous Solutions" J.Phys Chem. 97(16). 4192-4195 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Ameriya: "Frequency-Resolved Faradaiv Processes in Polypyrrole Films Obseved by Electromodilation Techniques : Electrochemical impedance and Color Impedance Spestoscopies" J.Phys Chem. 97(16). 4187-4191 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Z.F.Liu: "Direct Observation of the Secondary Structure of Unfolded Pseudomonas-Cytochrome C_<551> by Scanning Tunneling Micoscopy" Surf.Sci.Lett. 284. l411-l415 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-storing Materials.Part I.The Effect of Hydrogen absorptiion on the Electrochemical Behavior on Palladium Electrodes" J.Electroaanal. Chem. 345. 445-456 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Amemiya: "Faradic Charge Transier with Double-Layer Charging and /or Adsorption-Related Charging at Polymer-Modified Electrodes As Observed by Colar Impedance Spectroscopy" J.Phys.Chem.,. 97. 9736-9740 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] K.Morigaki: "In-Site Electrochemical Actinometry Using an Monolayer Film" Ber.Bensengs.Phys.Chem.,. 97. 860-864 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] L.A.Nagahara: "Effects of HF Solution in the Electroless Deposition Process on Silicon Surfacs" J.Vac.Sci.Technol,A. 11. 763-767 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] R.Baba: "Characterization of the Molecular Orientation in LB Films of Rhodamine B Derivatives by the Optical Second Harmonic Generation Coherent Interferometry" 電気化学. 61. 1030-1031 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] L.A.Nagahara: "Scanning Probe and Transmission Electron Microscopy Observations of Cobalt Naphthalocyanine Molecules Deposited onto a NaCl Substrate" J.Vac.Sci.Technol.A.11. 781-785 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] K.Morigaki: "Electrochemical Counting of Photon Number Using the Assembled Monolayer Film of Azo Compound" Sensors and Actuators B. 13-14. 226-229 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] O.Sato: "Self-Ordered Film of Hemicyanine Derivative Characterized by Phase-Sensitive Optical Sccond-Harmonic Generation" Jpn.J.Appl.,Phys.,. 32. 1201-1203 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-Storing Materilas.Part II.Copper-Modified Palladium Electrode" J.Electroanal.Chem.,. 348. 459-464 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Amemiya: "Dynamics of Faradic Procssed in Polypyrrole/Polystyrenesulfonate Composite Films in the Presence and Absence of Redox Species in Aqueou Solutions" J.Phys.Chem.,. 97. 4192-4195 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Z.F.Liu: "Direct Observation of the Secondary Structure of Unfolded Pseudomonas-Cytochrome C_<551> by Scanning Tunneling Microscopy" Surface Sci.Lett.,. 284. L411-L415 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Amemiya: "Frequency-Resolved Faradaic Processes in Polypyrrole Films Observed by Electromodulation Techniques:Electrochemical Impedance and Color Impedance Spectroscopies" J.Phys.Chem.,. 97. 4187-4191 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-Storing Materials Part I.The Effect of Hydrogen Absorption on the Electrochemical Behavior on Palladium Electrodes" J.Electroanal.Chem.,. 345. 445-456 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] J.N.Yao,B.H.Loo,: "Photochomic Response of Vacuum-Evaporated Nb_2O_5 Thin Films in Ethanol Vapor" Ber.Bunsenges.Phys.Chem.96. 669-701 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Patel: "Photoelectrochemical Investigations on Boron-Doped Chemically Vapour-Deposited Diamond Electrodes" J.Photochem.Photobiol.A:Chem.65. 419-429 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] L.A.Nagahara,: "The Influence of Hydrofluoric acid Concentration on Electrodes Copper Deposition onto Silicon" J.Elictroanal.Chem. 333. 363-369 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Manivannan,: "Scanning Prbbe Microscopic Investigation of Epitaxially Grown C_<60> Film on MoS_2" Jpn.J.Appl.Phys.31. 3680-3685 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] A.Fujishima: "Biochemical Application of Photoelectorcheistry Photokilling of Malignant Cells with TiO_2 Powder" Elictrochimica Acta.18. 153-157 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] H.Yanagi: "Molecular Orientation of Vacuum-deposited This Films of Zincnaphthalocyanine" J.Appl.Phys.71. 5146-5153 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] Z.F.Liu: "A Novel photoelectrochemical Hybrid “OneーWay"Process Observed in the Azobenzene System" J.Electroanal Chem.297. 133-144 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Sakamaki: "Definitive Structure a Stacking Boundary of Charge Density Waves in lTーTaS_2 Using a Scanning Tunneling Microscope" J.Phys.Chem.Solids. 52. 409-418 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Kato: "New Approach to Chiral Conductive Materals.A Polymer Composite from Polypyrrole and an Optically Active Polyamide" Chem.Lett.713-716 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] R.Cai: "Photokilling of Malignant Cells with Ultrafine TiO_2" Bull.Chem.Soc.Japan. 64. 1268-1273 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Sakamaki: "In Situ Observation Using a Scanning Tunneling Microscope of a Local Morphological LightーInduced Transformation of nーMolybdenumdisulfide in Contact with Acetonitrile Containing a Samll Amount of Water" Collection Czechoslovak Chem.Commun.56. 104-111 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Patel: "PhotoーSinking Phenomenoma Photodecompositou Rate of Silane Bonded on TiO_2 Powders" Ber.Bunsenges.Phys.Chem.95. 176-180 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] H.Doring: "Photoassisted ElectronーBeam Deposition of AlーDoped ZnS Thin Films" J.Elecカrochem.Soc.138. 1416-1420 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] J.N.Yao: "Photochromic Characteristics of Mixed WO_3ーMoO_3 Thin Films in Alcohol Vapors" Ber.Bunseges.Phys.Chem.95. 554-556 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] J.N.Yao: "PhotoーEnhancement of Electrochromism in MoO_3 Thin Films" Ber.Bunsenges Phys.Chem.95. 557-559 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Sakamaki: "Photoelectrochemical In Situ Observation of nーMoS_2 in Aqueous Solutions Using a Scanning Tunneling Microscope" J.vac.Sci.Technol.B,9. 994-949 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] O.Sato: "Coherent Interferometric Analysis of the Molecular Orientation Based on the Study of the Optical Secont Harmonic Generation" J.Electroanal.Chem.306. 291-296 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Cai: "Semiconductive Properties and Photoelectrochemistry of Iron Oxide Electodes ーーVII.Photoresponses of Sintered znOーDoped Iron Oxide Electrode" Electrochimica Acta. 36. 1585-1590 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Cai: "Phenomena of Weak Electroluminescence of Iron and Other Application Potentiality in Electrochemistry" Electrochimica Acta. 36. 1591-1593 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Cai: "The NーType/PーType Photoresponse Trahsition of MgーDoped and ZnーDoped Polycrystalline Iron Electrodes" Corrosion Sci.31. 733-738 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] S.Yoshihara: "Photoacoustic Detection of Pb Underpotential Deposition on Ag" Electrochimica Acta. 36. 1959-1961 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Ohmori: "Morphological Transformation of Palladium Casued by Measurement of a Scanning Tunneling Microscope" Jpn.J.Appl.Phys.30. 1826-1829 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Amemiya: "Analyses of Spectroelectrochemical Behavior‐of Polypyrrole Films Using the Nernst Equationーー“Monomer Unit"and Polaron Bipolaron Model" J.Electrochem.Soc.138. 2845-2850 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] O.Sato: "Second Harmonic Generation Coherent Interferometry Disclosing the Orientation Submerged Hemicyanine Layer in a LangmuirーBlodgett Multilayer Stスucture" J.Phys.Chem.95. 9636-9638 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Z.F.Liu: "Thermal CisーTrans Isomerization Kinetics of Azo Compound in the Assembled Monolayer Film:An Electrochemical Approach" Chem.Phys.Lett.185. 501-504 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] K.Kobayakawa: "Photocatalytic Activity of CuInS_2 and CuIn_5S_8" Electrochimica Acta. 37. 465-467 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] Z.F.Liu: "Electrochemical Actinometry Using the Assembled Monolayer Film of an Azo Compound" Anal.Chem.64. 134-137 (1991)

    • Related Report
      1991 Annual Research Report
  • [Publications] T.Kato: "SelfーAssembly of Liquid Crystalline Complexes Having Angular Structures through Intermolecular Hydrogen Bonding" Chem.Lett.265-268 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] J.N.Yao: "Photochromism Induced in an Electrolytically Pretreated MoO_3 Thin Film by Visible Light" Nature. 355. 624-626 (1992)

    • Related Report
      1991 Annual Research Report
  • [Publications] R.Cai: "Phagocytosis of Titanium Dioxide Particles Chemically Modiffied by Hematoporphyrin" Denki Kagaku.

    • Related Report
      1991 Annual Research Report
  • [Publications] R.Cai: "Increment of Photocatalytic Killing of Cancer Cells Using TiO_2 with the Acid of Superoxide Dismutase" Chem.Lett.,.

    • Related Report
      1991 Annual Research Report
  • [Publications] R.Cai: "Induction of Cytotoxicity by Photoーexcited TiO_2 Particles" Cancer Res.,.

    • Related Report
      1991 Annual Research Report
  • [Publications] R.Cai: "Conversition of Photogenerated Superoxide Anion Into H_2O_2 in TiO_2 Suspension Systems" J.Electroanal.Chem.

    • Related Report
      1991 Annual Research Report

URL: 

Published: 1991-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi