| Project/Area Number |
03403004
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| Research Category |
Grant-in-Aid for General Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
構造化学
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| Research Institution | Tohoku University (1994)
The University of Tokyo (1991-1993) |
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Principal Investigator |
OHNO Koichi UNIVERSITY OF TOHOKU,FACULTY OF SCIENCE,PROFESSOR, 理学部, 教授 (60012499)
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| Co-Investigator(Kenkyū-buntansha) |
MUNAKATA Toshiaki INSTITUTE OF PHYSICAL AND CHEMICAL RESEARCH,RESEARCHER, 研究員 (20150873)
YAMAKADO Hideo UNIVERSITY OF TOHOKU,FACULTY OF SCIENCE,RESEARCH ASSOCIATE, 理学部, 助手 (30242035)
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| Project Period (FY) |
1991 – 1994
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| Project Status |
Completed (Fiscal Year 1994)
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| Budget Amount *help |
¥32,000,000 (Direct Cost: ¥32,000,000)
Fiscal Year 1994: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1993: ¥5,500,000 (Direct Cost: ¥5,500,000)
Fiscal Year 1992: ¥8,700,000 (Direct Cost: ¥8,700,000)
Fiscal Year 1991: ¥16,800,000 (Direct Cost: ¥16,800,000)
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| Keywords | Penning electron spectroscopy / photoelectron spectroscopy / Cluster / ionization / excited atom / クラスタ- |
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| Research Abstract |
In the present research, new electron spectroscopic techniques have been developed for verious molecular systems including clusters ; (1) Collision Energy Resolved Penning Ionization Electron Spectroscopy (CERPIES), (2) measurements for Collision Energy Dependence of Partial Penning Ionization Cross Sections (CEDPICS), (3) Two-Dimensional Penning Ionization Electron Spectroscopy (2D-PIES), (4) Time-Correlation Penning Ionzation Electron Spectroscopy (TCPIES), and (5) Laser-Desorption Penning Ionization Electron Spectroscopy (LDPIES). In the last year of the term of the project, 2DPIES,TCPIES,and LDPIES were developed.
The 2DPIES system including an order-made electronic system was constructed and the observation of 2DPIES was made for the first time.
The TCPIES technique using a cross-correration time-of-flight method was developed. Sensitivity of signal detection for velocity resolved Penning electron spectroscopy was improved by a factor of ca.10-30.
The LDPIES method was developed for observing PIES of low-volatile samples of little amount in a short time without thermal decomposition.
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