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Ozone production and loss in the tropospheric photochemistry

Research Project

Project/Area Number 04402012
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field 気象・海洋・陸水学
Research InstitutionUniversity of Tokyo

Principal Investigator

OGAWA Toshihiro  University of Tokyo, Graduate School of Science, Professor, 大学院・理学系研究科, 教授 (70011616)

Co-Investigator(Kenkyū-buntansha) KONDO Yutaka  Nagoya University, Solar-Terrestrial Environmental Laboratory, Professor, 太陽地球環境研究所, 教授 (20110752)
KITA Kazuyuki  University of Tokyo, Graduate School of Science, Assistant Professor, 大学院・理学系研究科, 助手 (30221914)
IWAGAMI Naomoto  University of Tokyo, Graduate School of Science, Associate Professor, 大学院・理学系研究科, 助教授 (30143374)
Project Period (FY) 1992 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥12,000,000 (Direct Cost: ¥12,000,000)
Fiscal Year 1994: ¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 1993: ¥3,900,000 (Direct Cost: ¥3,900,000)
Fiscal Year 1992: ¥4,600,000 (Direct Cost: ¥4,600,000)
KeywordsTropospheric Photochemistry / Tropospheric Ozone / Ozone Precursor / Tropospheric Nitrogen Oxides / Tropospheric Carbon Monoxide / Tropospheric Hydrocarbons / 対流圏メタン
Research Abstract

(1) We developed an instrument to measure atmospheric methane automatically using the He-Ne laser absorption technique. Since this instrument was found to be sensitive to variations in temperature, pressure and flow rate in the detector housing, we added devices to stabilize these variables. Adopting a calibration interval to be 1 minute, a precision of 50 ppbv has been attained. A time resolution of 1 minute is useful for platforms such as automobiles and airships. We made observations over the Tokyo metropolitan area using an airship and in the paddy fields using a car, to obtain the data for the emission sources of atmospheric methane.
(2) We modified a carbon monoxide instrument based on gas chromatograph/mercury oxide deduction detector to adapt for airborne operation. An aircraft experiment was made over East Hokkaido in winter, to find carbon monoxide mixing ratio to be 150-170 ppbv, broadly constant from the ground to 5km altitude. The instrument was further improved to attain a precision of 5 ppbv with a time resolution of 110s. It was extensively employed in the campaign observations at Mt.Norikura, in the airship observation over Tokyo, and in the aircraft campaign in East Hokkaido.
(3) Field observations for tropospheric ozone and its precursor gases were made at Mt.Norikura and over Tokyo aloft an airship using a newly developed carbon monoxide instrument together with instruments for a nitric oxide/total odd nitrogen, ozone, water vapor and other meteorological parameters. A significant variation was found in the concentrations of ozone, carbon monoxide, nitric oxide and total odd nitrogen between different air masses : In the Mt.Norikura observation the air mass changed from southern to northern one during the day of a typhoon and after its passage. In the Tokyo observation the airship experienced both polluted and relatively clean air masses in the metropolitan area and on its outskirts.

Report

(4 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • 1992 Annual Research Report
  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] Y.Kondo: "Nitric oxide and ozone in the free troposphere over the Weatern Pacific Ocean" J.Geophys.Res.98. 20527-20535 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Ogawa: "IMG,interferometric measurement of greenhouse gases from space" Adv.Space.Res.14. 25-28 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Ogawa: "Development of a FTIR sounder-IMG" High Spcetral,Resolution Infrared Remoto Sensing for Earth's Weather and Climate Studies. 37-59 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 小川 利紘(共著): "どうする地球環境" 大日本図書, 216 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Kondo, Y.: "Nitric oxide and ozone in the free troposphere over the western Pacific Ocean" J.Geophys.Res.98. 20527-20535 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ogawa, T.: "IMG,interferometric measurement of greenhouse gases from space" Adv.Space Res.14. 25-28 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ogawa, T.: "Development of a FTIR sounder - IMG" High Spectral Resolution Infrared Remote Sensing for Earth's Weather and Climate Studies. 37-59 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ogawa, T.: Dohsuru Chikyukankyo. Dainippon-Tosho, 1-216 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Kondo: "Nitric oxide and ozone in the free troposphere over the western Pacific Ocean" J.Geophys.Res.98. 20527-20535 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Ogawa: "IMG,interferometric measurement of greenhouse gases from space" Adv.Space Res.14. 25-28 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Ogawa: "Development of a FTIR sounder-IMG" High Spectral Resolution Infrared Remote Sensing for Earth's Weather and Climate Studies. 37-59 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] 小川 利絋 (供著): "どうする地球環境" 大日本図書, 216 (1993)

    • Related Report
      1994 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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