Precise Measurement of Properties of Monolayrs and in situ Observation of Structural Change of Them
| Project/Area Number | 04453003 |
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
物理化学一般
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| Research Institution | Utsunomiya University |
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Principal Investigator |
KATO Teiji Utsunomiya University, Faculty of Engineering, Professor, 工学部, 教授 (60008068)
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| Co-Investigator(Kenkyū-buntansha) |
SUZUKI Noboru Utsunomiya University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (40134259)
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| Project Period (FY) |
1992 – 1993
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| Project Status |
Completed(Fiscal Year 1993)
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| Budget Amount *help |
¥7,000,000 (Direct Cost : ¥7,000,000)
Fiscal Year 1993 : ¥5,000,000 (Direct Cost : ¥5,000,000)
Fiscal Year 1992 : ¥2,000,000 (Direct Cost : ¥2,000,000)
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| Keywords | Monolayr / Brewster Angle Microscope / Phase Transition / Instantaneous Multi-Channel Photospectroscopy / Long-Chain Acids / Long-Chain Ureas / Long-Chain Silanes / in situ観察 / A-T等圧線 / 崩壊膜 / 結晶核 / 固体膜 / 部分崩壊 |
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| Research Abstract |
Insoluble monolayrs on the water surface are the most fundamental existence of the amphiphatic materials, such as surfactants and long-chain acids or alcohols. It was difficult to study the structure of monolayrs in molecular order because of the ultrathin character of the films and/or trace amount of materials. We have constructed a Brewster Angle Microscope(BAM) which was developed at France in 1991. Our BAM can observe structure in monolayrs directly at the resolution of 10mum. We did in situ observation of the structural change of monolayrs with phase transitions, with changing temperature and pressure, and by addition of divalent metal ions using BAM.We have also studied photopolymerization of long-chain derivatives of diacetylene by using the instantaneous multichannel photospectroscopy. We have developed a temperature-programmable Langmuir trough of very high performance using a large amount of Peltier elements. With this instrument, we have found a curious phase transition of a monolayr accompanying area contraction with increasing temperature.
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Report
(3results)
Research Products
(20results)
