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Spatial in formation on the stress-strain in a polymer gel

Research Project

Project/Area Number 06453152
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 高分子構造・物性(含繊維)
Research InstitutionTOKYO INSTITUTE OF TECHNOLOGY

Principal Investigator

ANDO Isao  Tokyo Institute of Technology Faculty of Engineering, Professor, 工学部, 教授 (20016637)

Co-Investigator(Kenkyū-buntansha) KUROSU Hiromichi  Tokyo Institute of Technology Faculty of Engineering, Research Associate, 工学部, 助手 (20221228)
Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥6,800,000 (Direct Cost: ¥6,800,000)
Fiscal Year 1995: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1994: ¥5,700,000 (Direct Cost: ¥5,700,000)
KeywordsNMR imaging / polymer gel / hydrogel / 核磁気共鳴
Research Abstract

^1H NMR imaging patterns with information about the spatial distribution of ^1H spin density and ^1H spin-spin relaxation time T_2 of water molecules in a crosslinked polymer gel were successfully measured, in order to clarify the translational behavior of water molecules in the gel under the propagation of stress-strain and shrinkage process by the application of an electric field. From these experimental results it was found that the propagation mechanism of stress-strain and the shrinkage process were elucidated.

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (25 results)

All Other

All Publications (25 results)

  • [Publications] H.Kurosu,T.Shibuya H.Yasunaga,I.Ando: "Spatial information on a polymer gel as studied by ^1H NMR imaging. III" Polymer Journal. 28. 80-85 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Shibuya,H.Yasunaga,H.Kurosu,I.Ando: "Spatial information on a polymer gel as studied by ^1H NMR imaging. II" Macromolecules. 28. 4377-4382 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Kobayashi,I.Ando,T.Ishii,S.Amiya: "Structural study of poly (vinyl alcohol) in the gel state by high-resolution solid-state 13C NMR spectroscopy" Macromolecules. 28. 6677-6679 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Tsuchiya,A.Takahashi,N.Takeda,S,Kuroki,I.Ando: "Hydrogen-bonding effect on 13C NMR chemical shifts of amino acid residue CO carbons of some peptides" J.Mol.Structure. 350. 233-240 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Kuroki,S.Ando,I.Ando: "An MO study of nuclear quadrupole coupling constant and nuclear shielding of the carbonyl oxygen in solid peptides" Chemical Physics. 195. 107-116 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Yasunaga,H.Kurosu,I.Ando,: "Structures and dynamics of polymer gel systems viewed from NMR spectroscopy" Annual Reports on NMR Spectroscopy. 31(in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 安藤勲編: "高分子の構造I.磁気共鳴(新高分子実験学)" 共立出版, 572 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Kurosu, T.Shibuya, H.Yasunaga, I.Ando: "Spatial information on a polymer gel as studied by ^1H NMR imaging. III" Polymer Journal. 28. 80-85 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Shibuya, H.Yasunaga, H.Kurosu, I.Ando: "Spatial information on a polymer gel as studied by ^1H NMR imaging. II" Macromolecules. 28. 4377-4382 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Kobayashi, I.Ando, T.Ishii, S.Amiya: "Structural study of poly (vinyl alcohol) in the gel state by high-resolution solid-state ^<13>C NMR spectroscopy" Macromolecules. 28. 6677-6679 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Tsuchiya, A.Takahashi, N.Takeda, S.Kuroki, I.Ando: "Hydrogen-bonding effect on ^<13>C NMR chemical shifts of amino acid residue carbcnyl carbons of some peptides" J.Mol.Structure. 350. 233-240 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Kuroki, S.Ando, I.Ando: "An MO study of nuclear quadrupole coupling constant and nuclear shielding of the carbonyl oxygen in solid peptides" Chemical Physics. 195. 107-116 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Yasunaga, H.Kurosu, S.Matsukawa, M.Kobatashi, I.Ando: "Structures and dynamics of polymer gel systems viewed from NMR spectroscopy" Ann.Rept.NMR Spectroscopy. 31 (in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H. Kurosu, T. Shibuya H. Yasunaga, I. Ando: "Spatial information on a polymer gel as studied by ^1H NMR imaging. III" Polymer Journal. 28. 80-85 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Shibuya, H. Yasunaga, H. Kurosu, I. Ando: "Spatial information on a polymer gel as studied by ^1H NMR imaging. II" Macromolecules. 28. 4377-4382 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M. Kobayashi, I. Ando, T. Ishii, S. Amiya: "Structural Study of poly(vinyl alcohol) in the gel state by high-resolution solid-state 13C NMR spectroscopy" Macromolecules. 28. 6677-6679 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Tsuchiya, A. Takahashi, N. Takeda, S. Kuroki, I. Ando: "Hydrogen-bonding effect on 13C NMR chemical shifts of amino acid residue CO carbons of some peptides" J. Mol. Structure. 350. 233-240 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S. Kuroki, S. Ando, I. Ando: "An MO study of nuclear quadrupole coupling constant and nuclear shielding of the carbonyl oxygen in solid peptides" Chemical Physics. 195. 107-116 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H. Yasunaga, H. Kurosu, I. Ando: "Structures and dynamics of polymer gel systems viewed from NMR spectroscopy" Annual Reports on NMR Spectroscopy. 31(in press). (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] 安藤 勲編: "高分子の構造I. 磁気共鳴(新高分子実験学)" 共立出版, 572 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] I. Ando, H. Kurosu: "NMR studies of Higher-order structures of solid polymers" Annual Reports on NMR Spectroscopy. 28. 189-275 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] I. Ando, H. Kurosu: "Hydrogen-bonding structural study of solid peptides and polypeptides as studied by 17 O N M Rspectroscopy" Journal of Molecular Structure. 323. 197-208 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] I. Ando, H. Kurosu: "Spatial information on a polymer gel as studied by ^1H NMR imaging: 2. Shrinkage by the application of an electric field" Macromolecules. (印刷中). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] I. Ando, H. Kurosu: "Spatial information on a polymer gel as studied by ^1H NMR imaging. II" 5th SPSJ International Polymer Conference. 305-305 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 安藤 勲: "高分子の固体NMR" 講談社サイエンティフィク社, 220 (1994)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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