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Development of High-performance Organic Electroluminescent Devices Using Amorphous Molecular Materials

Research Project

Project/Area Number 06555261
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 工業物理化学
Research InstitutionOsaka University

Principal Investigator

SHIROTA Yasuhiko  Osaka University, Faculty of Engineering, Professor, 工学部, 教授 (90029091)

Co-Investigator(Kenkyū-buntansha) WAKIMOTO Takeo  Pioneer Electronic Co., Corporate Research and Development Laboratory, Researche, 総合研究所, 研究員
NAKANO Hideyuki  Osaka University, Faculty of Engineering, Research Associate, 工学部, 助手 (00222167)
NOMA Naoki  Osaka University, Faculty of Engineering, Research Associate, 工学部, 助手 (70208388)
Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥5,900,000 (Direct Cost: ¥5,900,000)
Fiscal Year 1995: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1994: ¥5,000,000 (Direct Cost: ¥5,000,000)
KeywordsOrganic Electroluminescent Device / Amorphous Molecular Materials / Starburst Molecules / Glass-transition Temperature / Thermal Stability / Durability / Driving Voltage / Luminance Efficiency
Research Abstract

Organic electroluminescent (EL) devices have received attention because of potential application to full color flat panel displays. There have been extensive studies on layred organic EL devices with the aim of achieving high brightness and multicolor emission. However, improvement in the luminance efficiency and durability of devices remains to be solved.
We have been studying the synthesis, properties and applications of photo- and electro-active amorphous molecular materials which form readily amorphous glasses above room temperature. It is expected that the amorphous molecular materials function as hole transport materials of organic EL devices since they form stable amorphous film and exhibit relatively high hole drift mobility.
In the present study, (1) we have designed and synthesized novel pi-electron starburst molecules and investigated the relationship between molecular structure and the ease of glass formation, glass stability, and glass-transition temperature, (2) we have investigated the hole transport properties of molecular glasses, and (3) we have fabricated layred organic EL devices using amorphous molecular materials as hole transport layr and found that the device exhibit significant durability. In addition, EL devices consisting of double hole transport layrs exhibits a high luminance efficiency. These results provide the novel strategy for developing organic EL devices with high stability and high luminance efficiency using amorphous molecular materials.

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (25 results)

All Other

All Publications (25 results)

  • [Publications] H.Inada,K.Ohnishi,S.Nomura,A.Higuchi,H.Nakano,Y.Shirota: "Photo-and Electro-active Amorphous Molecular Materials : Morphology,Structures,and Hole Transport Properties of Tri (biphenyl-4-yl) amine" J.Mater.Chem.4. 171-177 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A.Higuchi,Y.Shirota: "Amorphous Molecular Materials : Synthesis and Properties of a Novel Starburst Molecule,4,4',4"-Tri (N-phenoxazinyl) triphenylamine" Mol.Cryst.Liq.Cryst.242. 127-133 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Shirota,Y.Kuwabara,H.Inada,T.Wakimoto,H.Nakada,Y.Yonemoto,S.Kawami,K.Imai: "Multilayered organic electroluminescent device using a novel starburst molecule,4,4',4"-tris (3-methylphenylphenylamino) triphenylamine as a hole transport material" Appl.Phys.Lett.65. 807-809 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Kuwabara,H.Ogawa,H.Inada,N.Noma,Y.Shiroda: "Thermally Stable Multilayered Organic Electroluminescent Devices Using Novel Starburst Molecules,4,4',4"-Tri (N-carbazolyl) triphenylamine (TCTA) and 4,4',4"-Tris (3-methylphenylphenylamino) triphCylamine (m-MTDATA) is Hole-Transport Materials" Adv.Mater.6. 677-679 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Nomura,K.Nishimura,Y.Shirota: "Charge-Transport Properties of Arylaldehyde Hydrazones in Their Glassy States-Single Component and Doped Systems" Mol.Cryst.Liq.Cryst.253. 79-88 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] E.Ueda,H.Nakano,Y.Shirota: "Glass Formation and Phase Transition of Novel π-Electron Starburst Molecules,1,3,5-Tris (phenyl-2-thienylamino) benzene and 1,3,5-Tris (phenyl-3-thienylamino) benzene" Chem.Lett.2397-2400 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Nomura,K.Nishimura,Y.Shirota: "Charge Transport in the Glassy State of Arylaldehyde and Arylketone Hydrazones" Thin Solid Films. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Inada,Y.Yonemoto,T.Wakimoto,K.Imai,Y.Shirota: "Organic Electroluminescent Devices Using Novel Starburst Molecules,1,3,5-Tris-[4-(3-methylphenylphenylamino) phenyl] benzene and 4,4',4"-Tris (3-methylphenylphenylamino) triphenylamine as Hole Transport Materials" Mol.Cryst.Liq.Cryst.(in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Inada, K.Ohnishi, S.Nomura, A.Higuchi, H.Nakano, Y.Shirota: ""Photo-and Electro-active Amorphous Molecular Materials : Morphology, Structures, and Hole Transport Properties of Tri (biphenyl-4-yl) amine"" J.Mater.Chem.4. 171-177 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A.Higuchi, Y.Shirota: ""Amorphous Molecular Materials : Synthesis and Properties of a Novel Starburst Molecule, 4,4', 4''-Tri (N-phenoxazinyl) triphenylamine"" Mol.Cryst.Liq.Cryst.242. 127-133 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Shirota, Y.Kuwabara, H.Inada, T.Wakimoto, H.Nakada, Y.Yonemoto, S.Kawami, K.Imai: ""Multilayred organic electroluminescent device using a novel starburst molecule, 4,4', 4''-tris (3-methylphenylamino) triphenylamine sa a hole transport material"" Appl.Phys.Lett.65. 807-809 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Kuwabara, H.Ogawa, H.Inada, N.Noma, and Y.Shirota: ""Thermally Stable Multilayred Organic Electroluminescent Devices Using Novel Starburst Molecules, 4,4', 4''-Tri (N-carbazolyl) triphenylamine (TCTA) and 4,4', 4''-Tris (3-methylphenylphenylamino) triphenylamine (m-MTDATA) as Hole-Transport Materials"" Adv.Mater.6. 677-678 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Nomura, K.Nishimura, Y.Shirota: ""Charge-Transport Properties of Arylaldehyde Hydrazones in Their Glassy States-Single Component and Doped Systems"" Mol.Cryst.Liq.Cryst.253. 79-88 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] E.Ueta, H.Nakano, Y.Shirota: ""Glass Formation and Phase Transition of Novel pi-Electron Starburst Molecules, 1,3,5-Tris (phenyl-2-thienylamino) benzene and 1,3,5-Tris (phenyl-3-thienylamino) benzene"" Chem.Lett.2397-2400 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Nomura, K.Nishimura, Y.Shirota: ""Charge Transport in the Glassy State of Arylaldehyde and Arylketone Hydrazones"" Thin Solid Films. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Inada, Y.Yonemoto, T.Wakimoto, K.Imai, Y.Shitora: ""Organic Electroluminescent Devices Using Novel Starburst Molecules, 1,3,5-Tris [4- (3-methylphenylphenylamino) phenyl] benzene and 4,4', 4''-Tris- (3-methylphenylphenylamino) triphenylamine as Hole Transport Materials"" Mol.Cryst.Liq.Cryst.(in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] I.Tsukushi.O.Yamamuro.T.Ohta T.Marsuo.H.Y.Shirota: "Calorimetric Study on Configurational Enthalpy and Low-energy Excitation of Ground Amorphous Solid and Lipuid-qucnchcd Glass of 1,3,5-Tri-α-naphthylbenzene" J.Phys.,Condens.Matter. 8. 245-255 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Nomura.K.Nishimura Y.Shirota: "Charge Transport in the Glassy State of Arylaldehyde and Arylketone Hydrazones" Thin Solid Films. (in press).

    • Related Report
      1995 Annual Research Report
  • [Publications] H.lnada.Y.Yonemoto.T.Wakimoto K.lmai.Y.Shirota: "Organic Eiectroluminescent Devices Using Novel Starburst Molecules.1,3,5-Tris[4-(3-methylphenylphenylamino)phenyl]benzene and 4,4',4"-Tris(3-methylphenylphenylamino)triphenylamine as Hole Transport Materials" Mol.Cryst.Liq.Cryst.(in preSS).

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Tsuzuki,Y.Kuwabara N.Noma,Y,Shirota: "The Effect of Morphology on Photovoltaic Properties of Titanyl Phthalocyanine" Jap J.Appl.Plhys.(in press).

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Kageyama,K.Itano W.Ishikawa,Y.Shirota: "Striking Effects of Halogen Substituents on the Glass-forming Property,Glass-Transition Temperatire and Stability of the Glassy State of a New Family of Amorphous Molecular Materials,1,3,5-Tris(4-halogcnophenylphenylamino)banzcnes" J.Mater.Chem.(in press).

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Inada,K.Ohnishi,S.Nomura,A.Higuchi,H.Nakano,Y.Shirota: "Photo-and Electro-active Amorphous Molecular Materials:Morphology,Structures,and Hole Transport Properties of Tri(biphenyl-4-yl)amine" J.Mater.Chem.4. 171-177 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Y.Shirota,et al: "Multilayered organic electroluminescent device using a novel starburst molecule,4,4′,4″-tris(3-methylphenylphenylamino)triphenylamine as a hole transport material" Appl.Phys.Lett.65. 807-809 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Y.Kuwabara,H.Ogawa,H.inada,N.noma,Y.Shirota: "Thermally Stable Multilayered Organic Electroluminescent Devices Using Novel Starburst Molecules,4,4′,4″-Tri(N-carbazolyl)-triphenylamine(TCTA)and 4,4′,4″-Tris(3-methylphenylphenylamino)triphycylamine (m-MTDATA)as Hole-Transport Materials" Adv.Mater.6. 677-678 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] E.Ueta,H.Nakano,Y.Shirota: "Glass Formation and Phase Transition of Novel π-Electron Starburst Molecules, 1,3,5-Tris(phenyl-2-thienylamino)benzene and 1,3,5-Tris(phenyl-3-thienylamino)benzene" Chem.Lett.1994. 2397-2400 (1994)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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