| Project/Area Number |
06640509
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
物性一般(含基礎論)
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| Research Institution | KYUSHU UNIVERSITY |
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Principal Investigator |
ODAGAKI Takashi Kyushu Univ.Faculty of Science, Professor, 理学部, 教授 (90214147)
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| Co-Investigator(Kenkyū-buntansha) |
MATSUI Jun Kyushu Univ.Faculty of Science, Research associate, 理学部, 助手 (10274424)
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| Project Period (FY) |
1994 – 1996
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| Project Status |
Completed (Fiscal Year 1996)
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| Budget Amount *help |
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 1996: ¥300,000 (Direct Cost: ¥300,000)
Fiscal Year 1995: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1994: ¥1,400,000 (Direct Cost: ¥1,400,000)
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| Keywords | glass transition / slow relaxation and fast process / ideal three mode model / trapping diffusion model / non-gaussianity / molecular dynamics simulation / Vogel-Fulcher law / alpha-and beta-relaxation / 遅い緩和 / 速い過程 / ノンガウシアニティー / 二成分ソフトスフェア-系 / Vogel-Fulcher温度 / α-緩和,β-緩和 / log-コール・コールプロット / 分子動力学シュミレーション |
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| Research Abstract |
The main theme of the present research project is to understand the dynamical properties of vitrification process in a unified manner and to elucidate the physics of the glass forming process. We studied the trapping diffusion model (TDM) more throughly and gave the theoretical foundation of the model. We also performed a molecular dynamics simulation to find out the changes in dynamical properties of supercooled liquids.
We extended the TDM to include the trapped motion as well as the non-trapped jump motion and obtained the dynamical structure factor. We showed that the main relaxation time obeys the Vogel-Fulcher law and obtained the non-Gaussianity which agees qualitatively with experiments.We also devised a new technique (log-Cole-Cole analysis) with which we can find easily the nature of the relaxation.
The extensive MD simulation was carried out for a binary soft shpere system covering the liquid state, supercooled liquid state and glassy state. We found the Vogel-Fulcher law for the main relaxation time, Boson-peak and the fast process.
We proposed an ideal three model mode consisting of an oscillation and two kinds of stochastic motions and showed that this model can reproduce the dynamical charasteristics of supercooled liquids.
The foundation of the TDM was discussed extensively and it was shown that similar dynamics would be commonly observed in systems with activation processes with randam activation energies. We also showed that the divergence of various moments signifies the dynamical transitions and that the difference of temerature multiplied by the excess entropy from its value the glass transition point can serve as the scaling parameter for the transition.
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