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Principles for the Design of Multifunctional Catalysts.

Research Project

Project/Area Number 07242107
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionWASEDA UNIVERSITY

Principal Investigator

KIKUCHI Eiichi  WASEDA UNIVERSITY, SCHOOL OF SCIENCE AND ENGINEERING, PROFESSOR, 理工学部, 教授 (90063734)

Co-Investigator(Kenkyū-buntansha) DOMEN Kazunori  TOKYO INSTITUTE OF TECHNOLOGY, RESEARCH LABORATORY OF RESOURCES UTILIZATION, PROFESSOR, 資源化学研究所, 教授 (10155624)
OTSUKA Kiyoshi  TOKYO INSTITUTE OF TECHNOLOGY, DEPARTMENT OF CHEMICAL ENGINEERING, PROFESSOR, 工学部, 教授 (60016532)
ICHIKAWA Masaru  HOKKAIDO UNIVERSITY, CATALYSIS RESEARCH CENTER PROFESSOR, 触媒化学研究センター, 教授 (70176288)
HASHIMOTO Kazuhito  UNIVERSITY OF TOKYO, RESEARCH CENTER FOR ADVANCED SCIENCE AND TECHNOLOGY, PROFESSOR, 先端科学技術研究センター, 教授 (00172859)
Project Period (FY) 1995 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥74,400,000 (Direct Cost: ¥74,400,000)
Fiscal Year 1997: ¥14,800,000 (Direct Cost: ¥14,800,000)
Fiscal Year 1996: ¥22,600,000 (Direct Cost: ¥22,600,000)
Fiscal Year 1995: ¥37,000,000 (Direct Cost: ¥37,000,000)
Keywordssolid catalyst / material for catalyst / catalyst design / solid state reaction field / environmental catalyst / unique reaction field / design of active site / molecular dynamics / 機能複合化 / 窒素酸化物除去 / ゼオライト / 水の光分解 / 複合酸化物 / 選択酸化 / 空気浄化 / 抗菌 / NO選択還元反応 / intrapore catalysis / 光分解触媒 / 水の完全分解 / 触媒反応分離 / 錯体触媒 / メタンホモロゲーション / 光と熱のハイブリッド / NO選択還元 / 光触媒 / ミクロ空間複合金属 / 複合触媒機能 / 水分解 / ヒドロキシルアミン
Research Abstract

Catalytic chemistry in multifunctional reaction fields was investigated on the purpose of designing the catalyst which can function in the critical conditions as environmental catalysts should work. Success in improvement of catalytic performance has been obtained by (1) combination with multi-catalytic (chemical) functions, (2) utilization of photo- and electo-functions, and (3) introduction of membrane separation and adsorption.

Report

(4 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • Research Products

    (44 results)

All Other

All Publications (44 results)

  • [Publications] E.Kiichi., et.al.: "Selective reduction of Nitric Oxide with Methane od Gallium and Indium Containing H-zam-5 Catalysis:Formation of Active Sites by Solid States Ion Exchange"J.Catal.. 161. 465-470 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] E.Kikuchi, et.al.: "The Effect of Zeolite Structure on Creation of InO^+ Active Sites for NO_x Reduction with Methane"Microporous Materials. 21. 533 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Ogura et.al.: "Intraore Catalysis in Reduction of Nitric Oxide with Methane"Catal.Today. 42. 159-166 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] E. Kikuchi, et. al.: "Selective reduction of Nitric Oxide with Methane on Gallium and Indium Containing H-zsm-5 Catalysts : Formation of Active Sites by Solid State Ion Exchange"J. Catal.. 161. 465-470 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] E. Kikuchi, et al: "The Effect of Zeolite Structure on Creation of InOィイD1+ィエD1 Active Sites for NOx Reduction with Methane"Microporous Materials. 21. 533 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M. Ogura et al.: "Intrapore Catalysis in Reduction of Nitric Oxide with Methane"Catal. Today. 42. 159-166 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] E.Kikuchi,M.Ogura: "Selective reduction of nitric oxide with methane on In/H-ZSM-5-based catalysts" Catalysis Surveys from Japan. 1. 227-237 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] R.Abe et al.: "Preparation of porous niobium oxides by soft-chemical process and their photocatalytic activity" Chem.Mater.9(10). 2179-2184 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Otsuka et al.: "Hydroformylation of Ethylene via Spontaneous Cell Reactions in the Gas Phase" Journal of Catalysis. 165. 221-230 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Shido et al.: "EXAFS/FT-IR Characterization of Tetra Iridium Carboyl Clusters Bound to Tris (Hydroxymethyl) Phophine Grafted Silica" Journal of Molecular Catalysis. A120. 33-45 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] R.Wang et al.: "Light-induced amphiphilic Surfaces" Nature. 388. 431-432 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Ogura et al.: "Precious metal. loaded In/H-ZSM-5 for Reduction of Nitric Oxide with Methane in the Presence of Water Vapor" Stud.Surf.Sci.Cat.101. 671-680 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] E.Kikuchi et al.: "Selective Reduction of Nitric Oxide with Methane on Gallium and Indium Containing H-ZSM-5 Catalysts" J.Catal.161. 465-470 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Ogura et al.: "Formation of Active Sites for Reduction of NO_2 with Methane by Solid State Exchange of In_2O_3 into H-ZSM-5" Stud.Surf.Sci.Cat.105. 1593-1600 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Ogura et al.: "Reduction of Nitric Oxide with Methane on Pd/Co/H-ZSM-5 Catalysts : Cooperative Effects of Pd and Co" Catal.Lett.42. 185- (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Ogura et al.: "Intrapore Catalyst in NO Reduction with Methane on Ir/In/H-ZSM-5 Catalyst" Chem.Lett.1017-1018 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] E.Kikuchi et al.: "Selective Reduction of Nitric Oxide with Methane on In/H-ZSM-5 Based Catalysts" (印刷中).

    • Related Report
      1996 Annual Research Report
  • [Publications] A.Tanaka et al.: "Photocatalytic Properties of Some Ion-Exchangeable Layered Oxides" Critical Rev.Surf Chem. (印刷中).

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Ikeda et al.: "Effect of the particle size for photocatalytic decomposition of water on Ni loaded K_4Nb_6O_<17>" Microporous Materials. (印刷中).

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Tanaka et al.: "Photocatalytic decomposition of water on spontaneously hydrated layered perovskites" Chemistry of Materials. (印刷中).

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Otsuka et al.: "A Hydrogen-Nitric Oxide Cell for the Synthesis of Hydroxylamine" J.Electrochem.Soc.143. 3491-3497 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Q.Zhang et al.: "Partial Oxidation of Light Alkanes during O_<2->H_2Cell Reactions at Room Temperature" Chem.Lett.(印刷中).

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Yamamoto et al.: "Ship-in-Bottle Synthesis of [P_<+15>(CO)_<30>]^<2-> Encapsulated in Ordered Hexagonal Mesoporous Channels of FSM-16" J.Am.Chem.Soc.118. 5810-5811 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Ichikawa et al.: "Surface-grafted Metal Oxide Clusters and Metal Carbonyl Clusters in Zeolite Micropores" J.Mol.Cat.A107. 23-38 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Ichikawa et al.: "Ru,Pt and Co Clusters in Zeolite Micropores ; EXAFS/FTIR/TPI Characterization and Catalytic Behaviors for Methane Homologa" Stud.Surf.Sci.Cat.101. 1075-1084 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.M.Salama et al.: "EXAFS/XANES,XRD and UV-VIS Characterization of Intrazeolite Gold(I) Prepared by Monolayer Dispersion of AuCl_3" J.Phys.Chem.100. 3688-3694 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.M.Salama et al.: "Studies in Selective Reduction of Nitric Oxide by Carbon Monoxide in the Presence of Hydrogen over Au/NaY Catalysts" J.Chem.Soc.,Faraday Trans. 92. 301-306 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Imada et al.: "Structural Characterization of Photoreduced Complete and Incomplete Cubane Type Molybdenum Oxide Clusters" Catal.Lett.38. 101-108 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.M.Salama et al.: "Highly Selective Catalytic Reduction of NO by H_2 over Au^0 and Au(I) Impregnated in NaY Zeolite Catalysts" J.Catal. 162. 169-178 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] G.C.Shen et al.: "Synthesis and Reversible Decarbonylation of Zeolite-Entrappea Bimetallic Carbonyl Clusters [HCoRu_3(CO)_<13>]" J.Phys.Chem.100. 14265-14268 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] G.C.Shen et al.: "Cobalt Clusters in NaY Zeolite Cages : Synthesis and characterization" J.Phys.Chem.100. 16947-16956 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Ichikawa et al.: "Ship-in-Bottle Synthesis of Pt and Ru Carbonyl Clusters in NaY Zeolite Micropore and Ordered Mesoporous Channels of FSM-16" Stud.Surf.Sci.Cat.105. 679-686 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.M.Salama et al.: "In situ FT-IR and Catalytic Studies of the Selective Reduction of Nitric Oxide by Carbon Monoxide over Au/NaY Catalysts" Stud.Surf.Sci.Cat.105. 1571-1578 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] F.-S.Xiao et al.: "Oxide-Supported Trirutenium Ketenylidene Clusters and their Catalytic Properties" J.Mol.Catal.A113. 427-444 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] I.Sopyan et al.: "Efficient TiO_2 Powder and Film Photocatalysts with Rutile Structure" Chem.Lett.69-70 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] I.Sopyan et al.: "An Efficient TiO_2 Thin Film Photocatalyst : Photocatalytic Properties in Gas-Phase Acetaldehyde Degradation" J.Photochem.Photobiol.98. 79-86 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] I.Sopyan et al.: "A Film-Type Photocatalyst Incorporating Highly Active TiO_2 Powder and Fluoresin Binder" J.Electroanal.415. 183-186 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Kikuchi et al.: "Photocatalytic Bactericidal Effect of TiO_2 Thin-Film : Dynamic View for the Active Oxygen Species Responsible" J.Photochem.Photobiol.(印刷中).

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Ikeda et al.: "Studies on Photocatalytic Reactions involving radical Chain Reaotions using Microelectrodes" J.Phys.Chem.(印刷中).

    • Related Report
      1996 Annual Research Report
  • [Publications] 橋本和仁他: "光活性酸化チタンをコートしたセラミックス:抗菌、防汚機能の付与" ニューセラミックス. 48. 55-61 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 藤嶋昭他: "光触媒が活躍開始:タイルの場合" 化学と工業. 49. 764-767 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 池田勝佳他: "光触媒反応における酸素の関わり" 光化学. 22. 54-58 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 橋本和仁他: "光が当たるときれいになる材料:酸化チタン光触媒の新しい応用" 現代化学. 305. 23-28 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 橋本和仁他: "半導体光電極.光触媒反応" セラミックス. 31. 815-820 (1996)

    • Related Report
      1996 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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