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Borocarbide Superconductors, Materials and Properties

Research Project

Project/Area Number 07454077
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionUNIVERSITY OF TOKYO

Principal Investigator

TAKAGI Hidenori  University of Tokyo, Institute for Solid State Physics, Associate Professor, 物性研究所, 助教授 (40187935)

Co-Investigator(Kenkyū-buntansha) NOHARA Minoru  University of Tokyo, Institute for Solid State Physics, Research Associate, 物性研究所, 助手 (70272531)
Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥7,700,000 (Direct Cost: ¥7,700,000)
Fiscal Year 1996: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1995: ¥4,700,000 (Direct Cost: ¥4,700,000)
KeywordsSuperconductivity / Borocarbide superconductor / Flectronic states / Electron correlation / Gapless superconductivity / 磁場中比熱 / ホウ素炭化物 / Y(Lu)Ni_2B_2C / 反強磁性スピン揺らぎ
Research Abstract

Physical properties of borocarbide superconductors, LuNi_2B_2C and YNi_2B_2C,have been investigated by using a variety of experimental probes. These compounds were found to be clean limit type II superconductors with the upper and lower critical fields, -10T and -0.1T,respectively. Despite the layred structure, any significant anisotropy in the critical fields with fields parallel and perpendicular to the NiB plane was not observed, indicating that the borocarbides are electronically three dimensional rather than two dimensional. A relatively large electronic specific coefficient gamma=18mJ/molK^2 was estimated from the temperature dependent specific heat of LuNi_2B_2C,implying that the high density of states, associated with the presence of a narrow Ni3d band at the Fermi level, is part of the reason for the high-Tc.
The high density of state, on the other hand, suggests the importance of electron correlation effects. Indeed, we have shown experimentally that the strong electron correl … More ation indeed plays a very important role in the borocarbides. The resistivities of LuNi_2B_2C and YNi_2B_2C single crystals were found to show T^2-dependence at low temperatures, with the coefficient A satisfying Kadowaki-woods relationship which holds for a variey of correlated Fermi liquids. We found that the Ni 3d bandwidth of YNi_2B_2C determined by photoemission (with Fujimori group) is 20% narrower than the one estimated from the band calculation, which can be ascribed to the correlation efect. The ^<11>B and ^<61>Ni NMR measurements on LuNi_2B_2C and YNi_2B_2C (with Yasuoka group) indicated a strong enhancement of (T_1T)^<-1> in contrast to the weakly temperature dependent Knight shift. The borocarbide is therefore a superconductors with strong antiferromagnetic spin fluctuations.
Symmetry of Cooper pairs have been investigated through the quasiparticle states within the vortex core. Magnetic field dependence of the specific heat of LuNi_2B_2C was measured by a relaxation calorimeter. We found that the electronic specific heat coefficient gamma depends on the magnetic field H as gamma *ROO<H>, in contrast to those expected for conventional superconductors with an isotropic gap, gamma*H.This anomalous field dependence of gamma can be understood by assuming the presence of a gapless region on the Fermi surface. Considering the presence of significant spin fluctuations in the compound, we therefore suggest-d-wave superconductivity in this compound. Less

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (27 results)

All Other

All Publications (27 results)

  • [Publications] S.Shin et al.: "Soft x-ray emission studies of YNi_2B_2C and LaNi_2B_2C : Observation of B2p and C2p partial density of states" Physical Review. B52. 15082-15085 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Takagi: "Physical properties of the new borocarbide superconductors" Advances in Superconductivity. VII. 9-14 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Tokunaga et al.: "de Haas-van Alphen oscillations of LuNi_2B_2C in pulsed high magnetic fields" Journal of the Physical Society of Japan. 64. 1458-1461 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Takagi: "Borocarbide superconductors-materials and physical properties" Proceedings of US-JAPAN workshop on high-Tc superconductors. 343-346 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Kobayashi et al.: "Photoemission study of Ni borocarbides : superconducting YNi_2B_2C and nonsuperconducting LaNi_2B_2C" Physical Review. B53. 8733-8742 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Takagi et al.: "Borocarbide superconductors-materials and physical properties" Physica. B (accepted). (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Ikushima et al.: "Magnetic properties in the normal state of LuNi_2B_2C observed by ^<61>Ni and ^<11>B NMR" Journal of the Physical Society of Japan. (accepted). (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 高木 英典: "ホウ素・炭素を含む新しい四元化合物超伝導体の展開" 応用物理. 64. 310-317 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 高木 英典: "新しい高温超伝導物質-物質開発の進展" 科学. 65. 546-555 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 高木 英典(分担執筆): "超伝導技術とその応用" 丸善, 407 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Shin, A.Agui, M.Watanabe, M.Fujisawa, Y.Tezuka, T.Ishii, M.Hinomaru and H.Takagi: "Soft-xray-emission studies of YNi_2B_2C and LaNi_2B_2C : Observation of B2p and C 2p partial density of states" Phys. Rev.B52. 15082-15085 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Takagi: "Physical properties of the new borocarbide superconductors" Advances in superconductivity VII Springer-Verlag 9-14. (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Tokunaga, N.Miura, H.Takagi and R.J.Cava: "de Haas-van Alphen oscillations of LuNi_2B_2C in pulsed high magnetic fields" J.Phys. Soc. Jpn. 64. 1458-1461 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Takagi: "Borocarbide superconductors-materials and physical properties" Proc. US-Japan workshop on high-Tc superconductors, eds. T.tachikawa, K.Kitazawa, K.Togano and E.Muromachi. 343-346 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Kobayashi, T.Mizokawa, K.Mamiya, A.Sekiyama, A.Fujimori, H.Takagi, H.Eisaki, S.Uchida: "Photoemission study of Ni borocarbides : superconducting YNi_2B_2C and nonsuperconducting LaNi_2B_2C" PHYS.Rev.B53. 8733-8742 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Takagi and M.Nohara: "Borocarbidesuperconductors-materials and physical properties" Physica B. (accepted for publication).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Ikushima, H.Yasuoka, A.Ohno, H.Takagi, R.J.Cava, J.J.Krajewski, W.F.Peck, jr.: "Magnetic properties in the normal state of LuNi_2B_2C observed by ^<61>Ni and ^<11>B NMR" J.Phys. Soc. Jpn.(accepted for publication).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Kobayashi et al.: "Photoemission study of Ni borocarbides:Superconducting YN_<12>B_2C and nonsuperconducting LaNi_2B_2C" Physical Review. B53. 8733-8742 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.TAKAGI et al.: "Borocarbide superconductors-materials and physical properties" Physica. B. (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Ikushima et al.: "Magnetic properties in the normal state of LuNi_2B_2C obserred by ^<61>Ni and ^<11>B NMR" Journal of Physical Society of Japan. (4月号予定). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] 高木英典、野原実(分担執筆): "超伝導技術とその応用" 丸善, 407 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S. Shin,M.Hinomaru,H.Takagi et al.: "Soft-xray-emission studies of YNi_2B_2C and LaNi_2B_2:Observation of B2p and C 2p partial density of states" Physical Review. B52. 15082-15085 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Takagi: "Borocarbide superconductors-Materials and physical properties" Advances in superconductivity VII. 9-14 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M. Tokunaga ,N .Miura ,H .Takagi and R .J .Cava: "de Haas van Alphen oscillations of LuNi_2B_2C in Pulsed high magnetic fields" Journal of the Physical Society of Japan. 64. 1458-1461 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Kimura, S. Miyasaka, H. Takagi et al.: "In-plane and out-of plane magnetoresistance in La_<2-x>Sr_xCuO_4 single crystals" Physical Review B. April 1. (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] H. Takagi, H. Eisaki, S. Uchida and R. J. Cava: "Charge transport properties of strongly correlated matals near charge transfer insulator to metal transtion" Spectroscopy of Mott Insulators and Correlated metals. 185-193 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 高木英典: "ホウ素・炭素を含む新しい四次元化合物超伝導体の展開" 応用物理. 64. 310-317 (1995)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2020-05-15  

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