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A research on characterization of GaN-related compounds and blue lasers

Research Project

Project/Area Number 07455009
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionThe University of Tokushima

Principal Investigator

SAKAI Shiro  The University of Tokushima, Faculty of Engineering Professor, 工学部, 教授 (20135411)

Project Period (FY) 1995 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥5,300,000 (Direct Cost: ¥5,300,000)
Fiscal Year 1996: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1995: ¥3,400,000 (Direct Cost: ¥3,400,000)
KeywordsGaN / InGaN / Bulk GaN / Homoepitaxy / Sublimation / GaPN / Semiconductor lasers / ワイドギャップ半導体 / 半金属 / 秩序混晶 / 青色発光素子 / 窒化物半導体 / 混晶
Research Abstract

Although a blue-to UV nitride lasers were realized, many unknown problems such as the effects of very high density of dislocation, problems associated with cladding layrs and p-type layrs were still remain unsolved. The purpose of this research is to solve these problems and to establish a basis for homoepitaxial lasers utilizing III-nitrides. For these purposes, the following research topics were performed.
1.Growth and characterization of GaPN alloy : An alloy of GaPN with bandgap energy in the range of 2.5-3 eV were obtained for the first time. A blue emission was obtained, but the composition control was found to depend strongly on the growth condition.
2.Growth of thick GaN and bulk GaN by sublimation method : A GaN with a thickness of several tens of mum to several hundred of mum on sapphire and a bulk GaN with the size of several hundreds of mum to several mm were obtained. A technique to grow bulk GaN in the selective area on the substrate was developed, and the devices processing of the bulk GaN became possible.
3.Growth of InGaN on sapphire : GaN and InGaN films were grown on sapphire by MOCVD,and the layrs were characterized. Especially, the formation mechanism of the inhomogeneity in InGaN was investigated in detail.
4.Homoepitaxial growth : GaN and GaN/InGaN double-heterostructure were grown on bulk GaN by MOCVD and the grown layrs were characterized. It was found that the growth mode on the bulk substrate was very different of that on the sapphire substrate.
Above research results provided the basis for fabricating nitride lasers on a bulk GaN substrate.

Report

(3 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • Research Products

    (46 results)

All Other

All Publications (46 results)

  • [Publications] S.Nakajima,T.Yang and S.Sakai: "Valence-Band-Edge Energy of Group-III,Nitride Alloy Semiconductors" Jpn.J.Appl.Phys.34-No.5. 2213-2215 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Yang.S.Nakajima and S.Sakai: "Electronic Structures of Wurtzite GaN,InN and their Alloy Ga_<l-x>ln_xN Calculated by the Tight-Binding Method" Jpn.J.Appl.Phys.34-NO.11. 5912-5921 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Nakajima,T.Yang and S.Sakai: "Electronic Structure of Ga_<l-x>ln_xN by the Tight-Binding Method with Nearest-Neighbor s,p and d and Second-Neighbor s and p Interactions" International Conference on Silicon Carbide and Rerated Materials : 1995,Institute of Physics Conference Series Number 142. 947-950 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Kurai,Y.Naoi,T.Abe,S.Ohmi and S.Sakai: "Photopumped Stimulated Emission from Homoepitaxial GaN Grown on Bulk GaN Prepared by Sublimation Method" Jpn.J.Appl.Phys.35-No.1B. L77-79 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Kurai,T.Abe,Y.Naoi and S.Sakai: "Growth and Characterization of Thick GaN by Sublimation Method and Homoepitaxial Growth by MOCVD" Jpn.J.Appl.Phys.35-No.3. 1637-1640 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Okada,S.Kurai,Y.Naoi,K.Nishino,F.Inoko and S.Sakai: "Tarnsmission Elictron Microscopy of Sublimation-Grown GaN Single Crystal and GaN Homoepitaxial Film" Jpn.J.Appl.Phys. 35-No.11B. 1318-1320 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Sato,Y.Naoi and S.Sakai: "Structural Analysis of GaN and GaN/InGaN/GaN DH Structures on Sapphire(0001)Substrate grown by MOCVD" Proceeding of MRS Symp.,1996. (in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Sakai,S.Kurai,K.Nishino.K.Wada,H.Sato and Y.Naoi: "Growth of GaN by Sublimation Technique and Homoepitaxial growth by MOCVD" Proceeding of MRS Symp.,1996. (in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Sato,M.R.Sarkar,Y.Naoi and S.Sakai: "XPS Measurement of Valence Band Discontinuity at GaP/GaN Heterointerfaces" Solid State Electronics. (in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Naoi,Y.Naoi and S.Sakai: "MOCVD Growth of InAsN for Infrared Applications" Solid State Electronics. (in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Kurai,K.Nishino and S.Sakai: "Nucleation Control in the Growth of Bulk Gan by Sublimation method" Jpn.J.Appl.Phys. (in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Sato,Y.Naoi and S.Sakai: "X-ray Diffraction Analysis of GaN and GaN/InGaN/GaN Double-Hetero Structures Grown on Sapphire Substrate by MOCVD" Jpn.J.Appl.Phys.(in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Nakajima, T.Yang and S.Sakai: "Valence-Band-Edge Energy of Group-III,Nitride Alloy Semiconductors" Jpn.J.Appl.Phys.Vol.34, No.5. 2213-2215 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Yang, S.Nakajima and S.Sakai: "Electronic Structures of Wurtzite GaN,InN and their Alloy Ga_<1-X>In_XN Calculated by the Tight-Binding Method" Jpn.J.Appl.Phys.Vol.34, No.11. 5912-5921 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Nakajima, T.Yang and S.Sakai: "Electronic Structures of Ga_<1-X>In_XN by the Tight-Binding Method with Nearest-Neighbor s, p and d and Second-Neighbor s and p Interactions" International Conference on Silicon Carbide and Rerated Materials-1995, Institute of Physics Conference Series. No.142. 947-950

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Kurai, Y.Naoi, T.Abe, S.Ohmi and S.Sakai: "Photopumped Stimulated Emission from Homoepitaxial GaN Grown on Bulk GaN Prepared by Sublimation Method" Jpn.J.Appl.Phys.Vol.35, No.1B. L77-79 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Kurai, T.Abe, Y.Naoi and S.Sakai: "Growth and Characterization of Thick GaN by Sublimation Method and Homoepitaxial Growth by MOCVD" Jpn.J.Appl.Phys.Vol.35, No.3. 1637-1640 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Okada, S.Kurai, Y.Naoi, K.Nishino, F.Inoko and S.Sakai: "Tarnsmission Electron Microscopy of Sublimation-Grown GaN Single Crystal and GaN Homoepitaxial Film" Jpn.J.Appl.Phys.Vol.35, No.10B. 1318-1320 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Sato, Y.Naoi and S.Sakai: "Structural Analysis of GaN and GaN/InGaN/GaN DH Structures on Sapphire (0001) Substrate Grown by MOCVD" Proceeding of MRS Symp.(in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Sakai, S.Kurai, K.Nishino, K.Wada, H.Sato and Y.Naoi: "Growth of GaN by sublimation Technique and Homoepitaxial growth by MOCVD" Proceeding of MRS Symp.(in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Sato, M.R.Sarkar, Y.Naoi and S.Sakai: "XPS Measurement of Valence Band Discontinuity at GaP/GaN Heterointerfaces" Solid State Electronics. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Naoi, Y.Naoi and S.Sakai: "MOCVD Growth of InAsN for infrared Applications" Solid State Electronics. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Kurai, K.Nishino and S.Sakai: "Nucleation Control in the Growth of Bulk Gan by Sublimation method" Jpn.J.Appl.Phys.(in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Sato, Y.Naoi and S.Sakai: "X-ray Diffraction Analysis of GaN and GaN/InGaN/GaN Double-Hetero Structures Grown on Sapphire Substrate by MOCVD" Jpn.J.Appl.Phys.(in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Nakajima,T.Yang and S.Sakai: "Valence-Band-Edge Energy of Group-III,Nitride Alloy Semiconductors" Jpn.J.Appl.Phys.34-No.5. 2213-2215 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Yang.S.Nakajima and S.Sakai: "Electronic Structures of Wurtzite GaN,InN and their Alloy Ga_<1-x>In_xN Calculated by the Tight-Binding Method" Jpn.J.Appl.Phys.34-No.11. 5912-5921 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] Nakajima,T.Yang and S.Sakai: "Electronic Structure of Ga_<1-x>In_xN by the Tight-Binding Method with Nearest-Neighbor s.p and d and Second-Neighbor s and p Interactions" International Conference on Silicon Carbide and Rerated Materials-1995,Institute of Physics Conference Series Number 142. 947-950 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Kurai,Y.Naoi,T.Abe,S.Ohmi and S.Sakai: "Photopumped Stimulated Emission from Homoepitaxial GaN Grown on Bulk GaN Prepared by Sublimation Method" Jpn.J.Appl.Phys.35-No.1B. L77-79 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Kurai,T.Abe,Y.Naoi and S.Sakai: "Growth and Characterization of Thick GaN by Sublimation Method and Homoepitaxial Growth by MOCVD" Jpn.J.Appl.Phys.35-No.3. 1637-1640 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Okada,S.Kurai,Y.Naoi,K.Nishino,F.Inoko and S.Sakai: "Transmission Electron Microscopy of Sublimation-Grown GaN Single Crystal and GaN Homoepitaxial Film" Jpn.J.Appl.Phys.35-No.11B. 1318-1320 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Sato,Y.Naoi,and S.Sakai: "Structural Analysis of GaN and GaN/InGaN/GaN DH Structures on Sapphire(0001)Substrate grown by MOCVD" Proceeding of MRS Symp.1996. (in press). (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Sakai,S.Kurai,K.Nishino,K.Wada,H.Sato and Y.Naoi: "Growth of GaN by Sublimation Technique and Homoepitaxial growth by MOCVD" Proceeding of MRS Symp..1996. (in press). (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Sato,M.R.Sarkar,Y.Naoi and S.Sakai: "XPS Measurement of Valence Band Discontinuity at GaP/GaN Heterointerfaces" Solid State Electronics. (in press). (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Naoi,Y.Naoi and S.Sakai: "MOCVD Growth of InAsN for Infrared Applications" Solid State Electronics. (in press). (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Kurai,K.Nishino and S.Sakai: "Nucleation Control in the Growth of Bulk Gan by Sublimation method" Jpn.J.Appl.Phys.(in press). (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Sato,Y.Naoi and S.Sakai: "X-ray Diffraction Analysis of GaN and GaN/InGaN/GaN Double-Hetero Structures Grown on Sapphire Substrate by MOCVD" Jpn.J.Appl.Phys.(in press). (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Shiro Sakai: "Electronic structure of Ga_<1X>In_XN by the tight-binding method with nearest-neighbor s,p and d and second-neighbor s and p interactions" International Conference on Silicon Carbide and Related Materials-1995. 423-424 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Shiro Sakai: "Growth of Bulk and Thick GaN by Sublimation Method" 1995 Fall Meeting of the MRS, Symposium AAA. (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Shiro Sakai: "Homoepitaxial Growth of GaN on Thick GaN Substrates Prepared by Sublimation Method" Topical Workshop on III-V Nitrides. B6- (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Shiro Sakai: "XPS Measurement of Valance Band Discontinuity at GaP/GaN Heterointerfaces" Topical Workshop on III-V Nitrides. F8- (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Shiro Sakai: "Electronic Structures of Group III Nitride Alloys calculated by the Tight-Binding Method" Topical Workshop on III-V Nitrides. P2- (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Shiro Sakai: "Valence-Band-Edge Energy of Group-III Nitride Alloy Semiconductors" Jpn. J. Appl. Phys.34-No.5A. 2213-2215 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Shiro Sakai: "Electronic Structures of Wurtzite GaN, InN and Their Alloy Ga_<1-X> In_XN Calculated by the Tight-Binding Method" Jpn. J. Appl. Phys.34-No.11. 5912-5921 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Shiro Sakai: "Stimulated Emission from a Photopumped homoepitaxial GaN Grown by MOCVD on Bulk GaN Prepared by Sublimation Method" Proc. of the Topical Workshop on III-V Nitrides. SP-6 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Shiro Sakai: "MOCVD Growth of InAsN for Infrared Application" Proc. of the Topical Workshop on II-V Nitrides. P-29 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Shiro Sakai: "Photopumped Stimulated Emission from Homoepitaxial GaN Grown on Bulk GaN Prepared by Sublimation Method" Jpn. J. Appl. Phys., Vol. 35, No.1B. Part2. L77-79 (1996)

    • Related Report
      1995 Annual Research Report

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Published: 1995-04-01   Modified: 2016-04-21  

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