Project/Area Number |
07680600
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
環境保全
|
Research Institution | Kanazawa University |
Principal Investigator |
SAWADA Tatsuro Kanazawa University, Faculty of Engineering, Professor, 工学部, 教授 (80019728)
|
Co-Investigator(Kenkyū-buntansha) |
NAKAMURA Yoshitoshi Kanazawa University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (20172455)
石川 英律 金沢大学, 工学部, 助手 (70232262)
|
Project Period (FY) |
1995 – 1996
|
Project Status |
Completed (Fiscal Year 1996)
|
Budget Amount *help |
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 1996: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1995: ¥1,500,000 (Direct Cost: ¥1,500,000)
|
Keywords | biowaste / steam explosion / enzymatic saccharification / alcohol fermentation / epoxy resin |
Research Abstract |
Effective systems of steam explosion, enzymatic hydrolysis, alcohol fermentation, and resinification were developed for solublization and resource conversion of biowaste. Rice straw as a biowaste was exploded under various operational conditions such as steam pressure of 2.55-4.02 MPa and steaming time of 0.5-10 min. The exploded rice straw was separated into water soluble material, methanol soluble lignin, Klason lignin, and mixture of cellulose and low molecular substance. The effects of steam explosion on the characteristics of the exploded rice straw were studied from the point of view of pH,pore size distribution, amounts of extractive components, and enzymatic saccharification. The enzymatic saccharification was expressed as a function of steam pressure and steaming time. It was estimated from the equation that maximum saccharification was obtained at a steam pressure of 3.3-3.8 MPa and a steaming time of 1.8-2.2 min. Glucose and xylose in the enzymatic hydrolyzate were converted into ethanol rapidly and efficiently. The amount of ethanol produced reached the maximum value at a flow rate of 0.2 vvm. A bioreactor coupled with pervaporation using a polytetrafluoroethylene membrane was developed for the produdction of a higher ethanol concentration from the enzymatic hydrolyzate. The methanol soluble lignin in the rice straw exploded at a steam pressure of 3.53 MPa and a steaming time of 2 min was converted into an excellent thermosetting resin by the epoxy reaction.
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